CA2016993A1 - Derives synthetiques de la saponite, methode de preparation de ces saponites et leur utilisation dans la conversion catalytique (des hydrocarbures) - Google Patents

Derives synthetiques de la saponite, methode de preparation de ces saponites et leur utilisation dans la conversion catalytique (des hydrocarbures)

Info

Publication number: CA2016993A1
Authority: CA; Canada
Prior art keywords: saponite; process according; source; derivatives; nickel
Prior art date: 1989-05-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002016993A

Other languages

English (en)

Inventor

Johan Breukelaar

Rutger Anthony Van Santen

Andreas Wilhelmus De Winter

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-05-19

Filing date

1990-05-17

Publication date

1990-11-19

1990-05-17 Application filed by Individual filed Critical Individual

1990-11-19 Publication of CA2016993A1 publication Critical patent/CA2016993A1/fr

Status Abandoned legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 57
238000006243 chemical reaction Methods 0.000 title abstract description 9
230000003197 catalytic effect Effects 0.000 title abstract description 6
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 title abstract description 5
229910021645 metal ion Inorganic materials 0.000 claims abstract description 16
229910000275 saponite Inorganic materials 0.000 claims abstract description 16
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 11
229910052751 metal Inorganic materials 0.000 claims abstract description 10
239000002184 metal Substances 0.000 claims abstract description 10
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 56
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
238000011282 treatment Methods 0.000 claims description 26
229910052759 nickel Inorganic materials 0.000 claims description 25
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 23
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 22
239000003054 catalyst Substances 0.000 claims description 15
239000011777 magnesium Substances 0.000 claims description 13
239000000463 material Substances 0.000 claims description 13
239000000377 silicon dioxide Substances 0.000 claims description 13
229910052697 platinum Inorganic materials 0.000 claims description 12
239000005977 Ethylene Substances 0.000 claims description 11
239000004411 aluminium Substances 0.000 claims description 11
229910052782 aluminium Inorganic materials 0.000 claims description 11
229910052763 palladium Inorganic materials 0.000 claims description 11
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
229910052749 magnesium Inorganic materials 0.000 claims description 10
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
238000004517 catalytic hydrocracking Methods 0.000 claims description 9
150000002736 metal compounds Chemical class 0.000 claims description 9
229910052710 silicon Inorganic materials 0.000 claims description 9
239000010703 silicon Substances 0.000 claims description 9
239000011149 active material Substances 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 8
-1 ammonium ions Chemical class 0.000 claims description 7
239000010941 cobalt Substances 0.000 claims description 7
229910017052 cobalt Inorganic materials 0.000 claims description 7
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
150000001335 aliphatic alkanes Chemical class 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 6
229910052681 coesite Inorganic materials 0.000 claims description 6
229910052906 cristobalite Inorganic materials 0.000 claims description 6
235000012239 silicon dioxide Nutrition 0.000 claims description 6
229910052682 stishovite Inorganic materials 0.000 claims description 6
229910052905 tridymite Inorganic materials 0.000 claims description 6
229910052593 corundum Inorganic materials 0.000 claims description 5
229910001845 yogo sapphire Inorganic materials 0.000 claims description 5
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 4
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 4
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
229910052721 tungsten Inorganic materials 0.000 claims description 4
239000010937 tungsten Substances 0.000 claims description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
239000011575 calcium Substances 0.000 claims description 3
229910052791 calcium Inorganic materials 0.000 claims description 3
229910052744 lithium Inorganic materials 0.000 claims description 3
150000007524 organic acids Chemical class 0.000 claims description 3
239000011734 sodium Substances 0.000 claims description 3
229910052708 sodium Inorganic materials 0.000 claims description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
150000001336 alkenes Chemical class 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
239000010949 copper Substances 0.000 claims description 2
229910052802 copper Inorganic materials 0.000 claims description 2
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 2
229910052742 iron Inorganic materials 0.000 claims description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
150000003377 silicon compounds Chemical class 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims 2
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims 1
229910001593 boehmite Inorganic materials 0.000 claims 1
229910001429 cobalt ion Inorganic materials 0.000 claims 1
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims 1
229910001453 nickel ion Inorganic materials 0.000 claims 1
239000002243 precursor Substances 0.000 claims 1
239000004215 Carbon black (E152) Substances 0.000 abstract 1
229930195733 hydrocarbon Natural products 0.000 abstract 1
150000002430 hydrocarbons Chemical class 0.000 abstract 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
239000000203 mixture Substances 0.000 description 13
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
239000001257 hydrogen Substances 0.000 description 9
229910052739 hydrogen Inorganic materials 0.000 description 9
238000010438 heat treatment Methods 0.000 description 8
238000002474 experimental method Methods 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
238000001354 calcination Methods 0.000 description 5
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
238000006317 isomerization reaction Methods 0.000 description 4
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000007789 gas Substances 0.000 description 3
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
239000000243 solution Substances 0.000 description 3
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
239000004990 Smectic liquid crystal Substances 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
239000011959 amorphous silica alumina Substances 0.000 description 2
239000001273 butane Substances 0.000 description 2
238000005341 cation exchange Methods 0.000 description 2
239000011737 fluorine Substances 0.000 description 2
229910052731 fluorine Inorganic materials 0.000 description 2
239000001307 helium Substances 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 2
239000011654 magnesium acetate Substances 0.000 description 2
235000011285 magnesium acetate Nutrition 0.000 description 2
229940069446 magnesium acetate Drugs 0.000 description 2
159000000003 magnesium salts Chemical class 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
235000005985 organic acids Nutrition 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
239000005695 Ammonium acetate Substances 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001399 aluminium compounds Chemical class 0.000 description 1
229910001579 aluminosilicate mineral Inorganic materials 0.000 description 1
229940043376 ammonium acetate Drugs 0.000 description 1
235000019257 ammonium acetate Nutrition 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
229940077746 antacid containing aluminium compound Drugs 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
CQQJGTPWCKCEOQ-UHFFFAOYSA-L magnesium dipropionate Chemical compound [Mg+2].CCC([O-])=O.CCC([O-])=O CQQJGTPWCKCEOQ-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
235000016768 molybdenum Nutrition 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
150000002941 palladium compounds Chemical class 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
150000003376 silicon Chemical class 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000004230 steam cracking Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
150000003658 tungsten compounds Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/049—Pillared clays
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
- C07C5/226—Catalytic processes not covered by C07C5/23 - C07C5/31 with metals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2791—Catalytic processes with metals
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/16—Clays or other mineral silicates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
General Chemical & Material Sciences (AREA)
Geology (AREA)
Dispersion Chemistry (AREA)
Materials Engineering (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CA002016993A 1989-05-19 1990-05-17 Derives synthetiques de la saponite, methode de preparation de ces saponites et leur utilisation dans la conversion catalytique (des hydrocarbures) Abandoned CA2016993A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB8911610.7		1989-05-19
GB898911610A GB8911610D0 (en)	1989-05-19	1989-05-19	Synthetic saponite-derivatives,a method for preparing such saponites and their use in catalytic(hydro)conversions

Publications (1)

Publication Number	Publication Date
CA2016993A1 true CA2016993A1 (fr)	1990-11-19

Family

ID=10657070

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002016993A Abandoned CA2016993A1 (fr)	1989-05-19	1990-05-17	Derives synthetiques de la saponite, methode de preparation de ces saponites et leur utilisation dans la conversion catalytique (des hydrocarbures)

Country Status (9)

Country	Link
US (1)	US5089458A (fr)
EP (1)	EP0398429B1 (fr)
JP (1)	JP2936491B2 (fr)
KR (1)	KR0143992B1 (fr)
AU (1)	AU620249B2 (fr)
CA (1)	CA2016993A1 (fr)
DE (1)	DE69005189T2 (fr)
ES (1)	ES2062297T3 (fr)
GB (1)	GB8911610D0 (fr)

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FR2673930B1 (fr) *	1991-03-14	1993-08-27	Inst Francais Du Petrole	Nouveaux phyllosilicates 2:1 dioctraedriques et leur procede de preparation.
FR2682371B1 (fr) *	1991-10-09	1993-11-26	Institut Francais Petrole	Phyllosilicates 2:1 trioctaedriques et leur procede de preparation.
US5296427A (en) *	1992-11-09	1994-03-22	Uop	Fluorided beidellite clay and process for preparing the clay
US5393411A (en) *	1992-11-09	1995-02-28	Uop	Hydrocarbon conversion process using a fluorided beidellite clay
US5744113A (en) *	1993-05-27	1998-04-28	Siemens Aktiengesellschaft	Process and catalyst for decomposing oxides of nitrogen
US5503819A (en) *	1994-03-18	1996-04-02	Uop	Substituted fluoride smectite clays, process for preparing the clay and uses thereof
US5733439A (en) *	1994-03-18	1998-03-31	Uop	Hydrocarbon conversion processes using substituted fluoride smectite clays
JP2636178B2 (ja) *	1994-08-23	1997-07-30	工業技術院長	合成混合層ケイ酸塩及びその製造方法
NL1003833C2 (nl) *	1995-08-22	1998-12-08	Nippon Oil Co Ltd	Katalysator voor het hydrokraken van een zware koolwaterstofolie en een werkwijze voor het hydrokraken.
FR2745728B1 (fr) *	1996-03-08	1998-04-10	Inst Francais Du Petrole	Catalyseur comprenant un phyllosilicate 2:1 trioctaedrique prepare en milieu fluorure et procede d'hydroconversion de charges petrolieres
US6541409B1 (en) *	1999-01-29	2003-04-01	Akzo Nobel N.V.	Process for producing anionic clay using non-peptized boemite and compositions produced therefrom
WO2001046071A2 (fr) *	1999-12-22	2001-06-28	Akzo Nobel N.V.	Procede de preparation de mineraux argileux synthetiques
FR2802913B1 (fr) *	1999-12-23	2002-02-08	Inst Francais Du Petrole	Phyllosilicates 2:1 trioctaedriques de type stevensite ou kerolite, procede de preparation et utilisation en catalyse
FR2802914B1 (fr) *	1999-12-23	2002-02-08	Inst Francais Du Petrole	Phyllosilicates 2:1 trioctaedriques de type stevensite ou kerolite modifies post-synthese, procede de preparation, utilisation en catalyse
DE102019106698B4 (de) *	2019-03-15	2025-01-09	Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.	Katalytische Herstellung von Butadien

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US3855147A (en) *	1972-05-26	1974-12-17	Nl Industries Inc	Synthetic smectite compositions, their preparation, and their use as thickeners in aqueous systems
US3959118A (en) *	1972-05-26	1976-05-25	N L Industries, Inc.	Hydrocarbon cracking with synthetic smectite compositions
US3852405A (en) *	1972-09-22	1974-12-03	Nl Industries Inc	Laminar heavy metal aluminosilicates
US3844979A (en) *	1972-12-01	1974-10-29	Chevron Res	Layered clay minerals, catalysts, and processes for using
US4666877A (en) *	1985-07-19	1987-05-19	Exxon Research And Engineering Company	Multimetallic pillared interlayered clay products and processes of making them
DE3541666A1 (de) *	1985-11-26	1987-05-27	Hoechst Ag	Verfahren zur herstellung eines kristallinen, quellfaehigen schichtsilikats vom saponit-typ
GB8726661D0 (en) *	1987-11-13	1987-12-16	Shell Int Research	Manufacture of synthetic saponites

1989
- 1989-05-19 GB GB898911610A patent/GB8911610D0/en active Pending
1990
- 1990-05-07 US US07/520,484 patent/US5089458A/en not_active Expired - Lifetime
- 1990-05-11 EP EP90201199A patent/EP0398429B1/fr not_active Expired - Lifetime
- 1990-05-11 ES ES90201199T patent/ES2062297T3/es not_active Expired - Lifetime
- 1990-05-11 DE DE90201199T patent/DE69005189T2/de not_active Expired - Fee Related
- 1990-05-16 KR KR1019900006996A patent/KR0143992B1/ko not_active Expired - Fee Related
- 1990-05-17 CA CA002016993A patent/CA2016993A1/fr not_active Abandoned
- 1990-05-17 JP JP2125601A patent/JP2936491B2/ja not_active Expired - Lifetime
- 1990-05-17 AU AU55161/90A patent/AU620249B2/en not_active Ceased

Also Published As

Publication number	Publication date
US5089458A (en)	1992-02-18
GB8911610D0 (en)	1989-07-05
JPH035315A (ja)	1991-01-11
EP0398429A3 (fr)	1991-07-03
EP0398429A2 (fr)	1990-11-22
DE69005189T2 (de)	1994-05-11
EP0398429B1 (fr)	1993-12-15
AU620249B2 (en)	1992-02-13
KR900017911A (ko)	1990-12-20
DE69005189D1 (de)	1994-01-27
JP2936491B2 (ja)	1999-08-23
AU5516190A (en)	1990-11-22
ES2062297T3 (es)	1994-12-16
KR0143992B1 (ko)	1998-07-15

Legal Events

Date	Code	Title	Description
1997-05-16	EEER	Examination request
2001-08-24	FZDE	Discontinued

Publication	Publication Date	Title
US4248739A (en)	1981-02-03	Stabilized pillared interlayered clays
EP0398429B1 (fr)	1993-12-15	Dérivés synthétiques de type saponite, méthode pour préparer de telles saponites, et leur utilisation pour l'(hydro)conversion catalytique
EP0550120A1 (fr)	1993-07-07	Catalyseur zéolite bêta activé et procédé d'isomérisation
CA1098104A (fr)	1981-03-24	Substance contenant de la silice et production industrielle d'hydrocarbures catalysee par ladite substance
JPH10101327A (ja)	1998-04-21	ゼオライトｎｕ−８８、その調製方法およびその触媒としての使用
US9120090B2 (en)	2015-09-01	Modified zeolite catalyst
JPS6241573B2 (fr)	1987-09-03
US6969692B2 (en)	2005-11-29	Process for the preparation of doped pentasil-type zeolites using a doped reactant
US4410751A (en)	1983-10-18	Production of olefins from a lower alcohol or dimethyl ether
NZ200154A (en)	1985-07-12	Synthetic zeolite,and use as catalyst
CA1329583C (fr)	1994-05-17	Procede pour la fabrication de saponites synthetiques
CA2496898C (fr)	2011-10-18	Processus de preparation de zeolites de type pensatile dopes au moyen d'un reactif dope
US5192726A (en)	1993-03-09	Beidellite clay and process for preparing the clay
US5389593A (en)	1995-02-14	Pillared clay containing fluorided pillars
JPH04504857A (ja)	1992-08-27	イソパラフィン―オレフィンアルキル化プロセス
CA2075166A1 (fr)	1993-02-02	Materiau zeolitique
US5192725A (en)	1993-03-09	Gallium/germanium dioctahedral smectite clay and process for preparing the clay
EP0016495B1 (fr)	1982-07-21	Procédé de préparation de méthane et d'éthane et méthane et/ou éthane ainsi préparés
US5409597A (en)	1995-04-25	Hydrocarbon conversion process using a pillared clay containing fluorided pillars
US5286367A (en)	1994-02-15	Hydrocarbon conversion process using a gallium/germanium dioctahedral smectite clay
US5296427A (en)	1994-03-22	Fluorided beidellite clay and process for preparing the clay
US5393411A (en)	1995-02-28	Hydrocarbon conversion process using a fluorided beidellite clay
EP0256065B1 (fr)	1991-10-23	Aluminosilicate cristallin en couche et son procede de preparation
US5503819A (en)	1996-04-02	Substituted fluoride smectite clays, process for preparing the clay and uses thereof
US5733439A (en)	1998-03-31	Hydrocarbon conversion processes using substituted fluoride smectite clays