CA2017715A1 - Procede d'adhesion amorce par la lumiere - Google Patents

Procede d'adhesion amorce par la lumiere

Info

Publication number: CA2017715A1
Authority: CA; Canada
Prior art keywords: composition; epoxide; epoxide resin; photoinitiator; adhesive
Prior art date: 1989-06-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2017715

Other languages

English (en)

Inventor

Stefan Weigl

Kam C. Wu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

3M Co

Original Assignee

Minnesota Mining and Manufacturing Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-06-28

Filing date

1990-05-29

Publication date

1990-12-28

1990-05-29 Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co

1990-12-28 Publication of CA2017715A1 publication Critical patent/CA2017715A1/fr

Status Abandoned legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 24
230000008569 process Effects 0.000 title claims description 21
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims abstract description 20
125000002560 nitrile group Chemical group 0.000 claims abstract description 5
229920000642 polymer Polymers 0.000 claims abstract description 5
239000000203 mixture Substances 0.000 claims description 56
229920000647 polyepoxide Polymers 0.000 claims description 25
239000000463 material Substances 0.000 claims description 24
239000003822 epoxy resin Substances 0.000 claims description 20
239000011368 organic material Substances 0.000 claims description 8
230000001678 irradiating effect Effects 0.000 claims description 5
239000002841 Lewis acid Substances 0.000 claims description 4
150000007517 lewis acids Chemical class 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 4
239000002131 composite material Substances 0.000 claims description 3
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 3
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims description 3
150000002118 epoxides Chemical class 0.000 claims 2
230000000977 initiatory effect Effects 0.000 claims 2
230000001737 promoting effect Effects 0.000 claims 2
MGFYSGNNHQQTJW-UHFFFAOYSA-N iodonium Chemical compound [IH2+] MGFYSGNNHQQTJW-UHFFFAOYSA-N 0.000 claims 1
230000001070 adhesive effect Effects 0.000 abstract description 51
239000000853 adhesive Substances 0.000 abstract description 50
239000000654 additive Substances 0.000 abstract description 3
239000004593 Epoxy Substances 0.000 abstract description 2
238000006116 polymerization reaction Methods 0.000 abstract 1
150000002924 oxiranes Chemical class 0.000 description 45
239000000758 substrate Substances 0.000 description 19
230000005855 radiation Effects 0.000 description 15
239000008199 coating composition Substances 0.000 description 14
238000000576 coating method Methods 0.000 description 14
239000011248 coating agent Substances 0.000 description 12
229910052751 metal Inorganic materials 0.000 description 12
239000002184 metal Substances 0.000 description 12
238000001723 curing Methods 0.000 description 10
229960000834 vinyl ether Drugs 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 9
-1 glycidyl epoxides Chemical class 0.000 description 9
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
125000003118 aryl group Chemical group 0.000 description 8
150000003839 salts Chemical class 0.000 description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
229920005989 resin Polymers 0.000 description 7
239000011347 resin Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 6
239000011888 foil Substances 0.000 description 6
238000009472 formulation Methods 0.000 description 6
238000012546 transfer Methods 0.000 description 6
239000002879 Lewis base Substances 0.000 description 5
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
239000010408 film Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
150000007527 lewis bases Chemical class 0.000 description 5
239000000126 substance Substances 0.000 description 5
230000001052 transient effect Effects 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
150000007942 carboxylates Chemical class 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000000016 photochemical curing Methods 0.000 description 4
239000000049 pigment Substances 0.000 description 4
125000001424 substituent group Chemical group 0.000 description 4
125000005409 triarylsulfonium group Chemical group 0.000 description 4
LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000010894 electron beam technology Methods 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
238000010030 laminating Methods 0.000 description 3
238000003475 lamination Methods 0.000 description 3
150000002825 nitriles Chemical group 0.000 description 3
229920003986 novolac Polymers 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000002023 wood Substances 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
229920013646 Hycar Polymers 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
230000004913 activation Effects 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000000151 deposition Methods 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
229920001971 elastomer Polymers 0.000 description 2
238000007646 gravure printing Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
125000000623 heterocyclic group Chemical group 0.000 description 2
WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 2
229940091173 hydantoin Drugs 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
239000011104 metalized film Substances 0.000 description 2
AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
ILBBNQMSDGAAPF-UHFFFAOYSA-N 1-(6-hydroxy-6-methylcyclohexa-2,4-dien-1-yl)propan-1-one Chemical compound CCC(=O)C1C=CC=CC1(C)O ILBBNQMSDGAAPF-UHFFFAOYSA-N 0.000 description 1
SAMJGBVVQUEMGC-UHFFFAOYSA-N 1-ethenoxy-2-(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOC=C SAMJGBVVQUEMGC-UHFFFAOYSA-N 0.000 description 1
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
FAUAZXVRLVIARB-UHFFFAOYSA-N 4-[[4-[bis(oxiran-2-ylmethyl)amino]phenyl]methyl]-n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC(CC=2C=CC(=CC=2)N(CC2OC2)CC2OC2)=CC=1)CC1CO1 FAUAZXVRLVIARB-UHFFFAOYSA-N 0.000 description 1
CXXSQMDHHYTRKY-UHFFFAOYSA-N 4-amino-2,3,5-tris(oxiran-2-ylmethyl)phenol Chemical compound C1=C(O)C(CC2OC2)=C(CC2OC2)C(N)=C1CC1CO1 CXXSQMDHHYTRKY-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
244000137852 Petrea volubilis Species 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
JRPRCOLKIYRSNH-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC2OC2)C=1C(=O)OCC1CO1 JRPRCOLKIYRSNH-UHFFFAOYSA-N 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000011951 cationic catalyst Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
239000013043 chemical agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229930003836 cresol Natural products 0.000 description 1
QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical class OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
239000011928 denatured alcohol Substances 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
238000009826 distribution Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000012854 evaluation process Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000000976 ink Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
230000031700 light absorption Effects 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000001465 metallisation Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
239000011185 multilayer composite material Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
125000001477 organic nitrogen group Chemical group 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
150000003022 phthalic acids Chemical class 0.000 description 1
239000011120 plywood Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
238000011417 postcuring Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
238000003847 radiation curing Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
230000003595 spectral effect Effects 0.000 description 1
238000012360 testing method Methods 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
230000001960 triggered effect Effects 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Landscapes

Adhesives Or Adhesive Processes (AREA)
Epoxy Resins (AREA)

CA 2017715 1989-06-28 1990-05-29 Procede d'adhesion amorce par la lumiere Abandoned CA2017715A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US37267689A	1989-06-28	1989-06-28
US372,676		1989-06-28

Publications (1)

Publication Number	Publication Date
CA2017715A1 true CA2017715A1 (fr)	1990-12-28

Family

ID=23469192

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2017715 Abandoned CA2017715A1 (fr)	1989-06-28	1990-05-29	Procede d'adhesion amorce par la lumiere

Country Status (1)

Country	Link
CA (1)	CA2017715A1 (fr)

1990
- 1990-05-29 CA CA 2017715 patent/CA2017715A1/fr not_active Abandoned

Legal Events

Date	Code	Title	Description
1998-05-29	FZDE	Dead

Publication	Publication Date	Title
JP3834594B2 (ja)	2006-10-18	安定化された硬化性接着剤
CA2028259A1 (fr)	1991-05-21	Compositions d'adhesif photopolymerisable
JP3347142B2 (ja)	2002-11-20	感圧接着剤組成物およびそれを光重合するための多重光開始方法
KR100263959B1 (ko)	2000-08-16	에너지-중합성 접착제, 코팅, 필름 및 이들의 제조 방법
AU607318B2 (en)	1991-02-28	Process for preparing photocured coatings
JPS6142954B2 (fr)	1986-09-25
JPS60158441A (ja)	1985-08-19	画像形成方法
GB1565671A (en)	1980-04-23	Photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials
JPH06507664A (ja)	1994-09-01	エポキシド　ベースの接着剤
US4287228A (en)	1981-09-01	Photopolymerizable epoxide coating compositions containing titanium dioxide pigment and method of polymerization using same
JPS6039707B2 (ja)	1985-09-07	無溶剤型光重合性被覆組成物
US4219377A (en)	1980-08-26	Photocurable epoxy composition having improved flexibility comprising vinyl terminated acrylonitrile-butadiene polymer
JPH08231938A (ja)	1996-09-10	ラミネート用活性エネルギー線硬化型接着剤組成物
JPH0284461A (ja)	1990-03-26	紫外線硬化性組成物処理体
JP2003096184A (ja)	2003-04-03	光硬化型樹脂組成物
US5057551A (en)	1991-10-15	Adhesives that continue to harden in darkness after photoinitiation
JPH0330616B2 (fr)	1991-05-01
JPS639529B2 (fr)	1988-02-29
EP0234470B1 (fr)	1991-12-18	Composition de résine durcissable par un rayonnement d'énergie active
JPS62265321A (ja)	1987-11-18	樹脂組成物
US5536621A (en)	1996-07-16	Ray-curing butadiene and substituted liquid polybutadiene composition
JP2527166B2 (ja)	1996-08-21	接着剤層を有するポリエ−テルイミドフイルム
JPS61283645A (ja)	1986-12-13	活性エネルギ−線硬化型樹脂組成物
CA1045880A (fr)	1979-01-09	Substrat pour resine liquide photosensible
JP2549421B2 (ja)	1996-10-30	活性エネルギー線硬化型樹脂組成物