CA2018943A1 - Couplage d'alcenes - Google Patents
Couplage d'alcenesInfo
- Publication number
- CA2018943A1 CA2018943A1 CA2018943A CA2018943A CA2018943A1 CA 2018943 A1 CA2018943 A1 CA 2018943A1 CA 2018943 A CA2018943 A CA 2018943A CA 2018943 A CA2018943 A CA 2018943A CA 2018943 A1 CA2018943 A1 CA 2018943A1
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- alkali metal
- alkene
- potassium
- ethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 230000008878 coupling Effects 0.000 title 1
- 238000010168 coupling process Methods 0.000 title 1
- 238000005859 coupling reaction Methods 0.000 title 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical group CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 229910052783 alkali metal Inorganic materials 0.000 abstract 3
- 150000001340 alkali metals Chemical class 0.000 abstract 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003426 co-catalyst Substances 0.000 abstract 2
- 239000001294 propane Substances 0.000 abstract 2
- 229910000799 K alloy Inorganic materials 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/24—Catalytic processes with metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US374,057 | 1989-06-30 | ||
| US07/374,057 US4982044A (en) | 1989-06-30 | 1989-06-30 | Alkene coupling |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2018943A1 true CA2018943A1 (fr) | 1990-12-31 |
| CA2018943C CA2018943C (fr) | 1999-11-02 |
Family
ID=23475090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002018943A Expired - Fee Related CA2018943C (fr) | 1989-06-30 | 1990-06-13 | Couplage d'alcenes |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4982044A (fr) |
| EP (1) | EP0405366B1 (fr) |
| JP (1) | JP2833712B2 (fr) |
| AU (1) | AU626697B2 (fr) |
| CA (1) | CA2018943C (fr) |
| DE (1) | DE69008778T2 (fr) |
| ES (1) | ES2054157T3 (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2546905C (fr) * | 2003-11-24 | 2014-08-05 | Michael Lefenfeld | Compositions de gel de silice contenant des metaux alcalins et des alliages de metaux alcalins |
| CA2570295C (fr) * | 2004-06-14 | 2014-02-18 | Signa Chemistry Llc | Compositions de siliciure contenant des metaux alcalins et leurs methodes de fabrication |
| CA2580930C (fr) * | 2004-09-22 | 2013-07-09 | Signa Chemistry Llc | Compositions de metal alcalin d'alumine et d'oxyde de titane |
| US9102528B2 (en) | 2009-03-30 | 2015-08-11 | Intelligent Energy Limited | Hydrogen generation systems and methods utilizing sodium silicide and sodium silica gel materials |
| EP2414096B1 (fr) | 2009-03-30 | 2016-11-09 | Intelligent Energy Limited | Systèmes et procédés de production d'hydrogène utilisant des matières à base de siliciure de sodium |
| US8895204B2 (en) | 2010-11-08 | 2014-11-25 | Intelligent Energy Limited | Water reactive hydrogen fuel cell power system |
| CN103477487A (zh) | 2010-11-08 | 2013-12-25 | 西格纳化学有限责任公司 | 水反应性氢燃料电池功率系统 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1443063A1 (de) * | 1959-03-02 | 1968-10-31 | Shell Int Research | Verfahren zur Herstellung von 4-Methylpenten-1 |
| US3255272A (en) * | 1961-08-30 | 1966-06-07 | Ethyl Corp | Olefin dimerization |
| JPS55145534A (en) * | 1979-04-27 | 1980-11-13 | Mitsui Petrochem Ind Ltd | Dimerization catalyst of alpha-olefin |
| JPS57126426A (en) * | 1981-01-27 | 1982-08-06 | Nippon Oil Co Ltd | Preparation of 4-methyl-1-pentene |
| CA1304416C (fr) * | 1987-12-21 | 1992-06-30 | R. Scott Smith | Procede de combinaison |
| US4914250A (en) * | 1988-06-17 | 1990-04-03 | Ethyl Corporation | Coupling process |
-
1989
- 1989-06-30 US US07/374,057 patent/US4982044A/en not_active Expired - Fee Related
-
1990
- 1990-06-13 CA CA002018943A patent/CA2018943C/fr not_active Expired - Fee Related
- 1990-06-22 DE DE69008778T patent/DE69008778T2/de not_active Expired - Fee Related
- 1990-06-22 EP EP90111906A patent/EP0405366B1/fr not_active Expired - Lifetime
- 1990-06-22 ES ES90111906T patent/ES2054157T3/es not_active Expired - Lifetime
- 1990-06-28 AU AU57998/90A patent/AU626697B2/en not_active Ceased
- 1990-06-28 JP JP2168593A patent/JP2833712B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU626697B2 (en) | 1992-08-06 |
| EP0405366B1 (fr) | 1994-05-11 |
| ES2054157T3 (es) | 1994-08-01 |
| JP2833712B2 (ja) | 1998-12-09 |
| CA2018943C (fr) | 1999-11-02 |
| DE69008778T2 (de) | 1994-08-25 |
| US4982044A (en) | 1991-01-01 |
| DE69008778D1 (de) | 1994-06-16 |
| JPH0363234A (ja) | 1991-03-19 |
| AU5799890A (en) | 1991-01-03 |
| EP0405366A3 (en) | 1992-03-04 |
| EP0405366A2 (fr) | 1991-01-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |