CA2020882A1 - Verre opale photosensible a reaction rapide - Google Patents

Verre opale photosensible a reaction rapide

Info

Publication number: CA2020882A1
Authority: CA; Canada
Prior art keywords: glass; exposed; temperature; making; ultraviolet radiation
Prior art date: 1989-08-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2020882

Other languages

English (en)

Inventor

Nicholas F. Borrelli

James E. Dickinson, Jr.

Joseph E. Pierson

Stanley D. Stookey

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Corning Inc

Original Assignee

Corning Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-08-07

Filing date

1990-07-11

Publication date

1991-02-08

1990-07-11 Application filed by Corning Inc filed Critical Corning Inc

1990-07-11 Priority to CA 2020882 priority Critical patent/CA2020882A1/fr

1991-02-08 Publication of CA2020882A1 publication Critical patent/CA2020882A1/fr

Status Abandoned legal-status Critical Current

Links

239000011521 glass Substances 0.000 title claims abstract description 123
239000011022 opal Substances 0.000 title description 9
230000004044 response Effects 0.000 title description 2
230000005855 radiation Effects 0.000 claims abstract description 35
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
239000000203 mixture Substances 0.000 claims abstract description 26
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 14
229910052681 coesite Inorganic materials 0.000 claims abstract description 13
229910052906 cristobalite Inorganic materials 0.000 claims abstract description 13
239000000377 silicon dioxide Substances 0.000 claims abstract description 13
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 13
229910052709 silver Inorganic materials 0.000 claims abstract description 13
229910052682 stishovite Inorganic materials 0.000 claims abstract description 13
229910052905 tridymite Inorganic materials 0.000 claims abstract description 13
238000010438 heat treatment Methods 0.000 claims abstract description 10
229910011255 B2O3 Inorganic materials 0.000 claims abstract description 8
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052794 bromium Inorganic materials 0.000 claims abstract description 8
229910052593 corundum Inorganic materials 0.000 claims abstract description 8
229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 8
238000011161 development Methods 0.000 claims abstract description 7
229910052731 fluorine Inorganic materials 0.000 claims abstract description 7
GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims abstract description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 19
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 13
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
238000000034 method Methods 0.000 claims description 12
238000001816 cooling Methods 0.000 claims description 11
239000012535 impurity Substances 0.000 claims description 5
FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 3
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 3
229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 3
229910052801 chlorine Inorganic materials 0.000 claims description 3
XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 3
238000002844 melting Methods 0.000 claims description 3
230000008018 melting Effects 0.000 claims description 3
238000003303 reheating Methods 0.000 claims description 3
230000009466 transformation Effects 0.000 claims description 2
230000001747 exhibiting effect Effects 0.000 claims 1
230000000694 effects Effects 0.000 abstract description 4
206010034972 Photosensitivity reaction Diseases 0.000 abstract description 3
230000036211 photosensitivity Effects 0.000 abstract description 3
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 13
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 8
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 7
239000000306 component Substances 0.000 description 7
239000004576 sand Substances 0.000 description 6
230000035945 sensitivity Effects 0.000 description 6
239000004332 silver Substances 0.000 description 6
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 6
238000013459 approach Methods 0.000 description 5
230000006872 improvement Effects 0.000 description 5
238000006124 Pilkington process Methods 0.000 description 4
239000002585 base Substances 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
229910052742 iron Inorganic materials 0.000 description 4
239000000463 material Substances 0.000 description 4
238000000862 absorption spectrum Methods 0.000 description 3
238000007792 addition Methods 0.000 description 3
239000006121 base glass Substances 0.000 description 3
239000003086 colorant Substances 0.000 description 3
230000003287 optical effect Effects 0.000 description 3
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 3
101100172886 Caenorhabditis elegans sec-6 gene Proteins 0.000 description 2
101100172892 Caenorhabditis elegans sec-8 gene Proteins 0.000 description 2
229910052684 Cerium Inorganic materials 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
229910000272 alkali metal oxide Inorganic materials 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
230000008859 change Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000000470 constituent Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
-1 silver ions Chemical class 0.000 description 2
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
101100065878 Caenorhabditis elegans sec-10 gene Proteins 0.000 description 1
101100148780 Caenorhabditis elegans sec-16A.1 gene Proteins 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
229910004883 Na2SiF6 Inorganic materials 0.000 description 1
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
239000011358 absorbing material Substances 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
230000009471 action Effects 0.000 description 1
229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
229910000420 cerium oxide Inorganic materials 0.000 description 1
WTVAYLQYAWAHAX-UHFFFAOYSA-J cerium(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Ce+4] WTVAYLQYAWAHAX-UHFFFAOYSA-J 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 description 1
238000004040 coloring Methods 0.000 description 1
238000010961 commercial manufacture process Methods 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
230000001276 controlling effect Effects 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
230000005670 electromagnetic radiation Effects 0.000 description 1
238000000295 emission spectrum Methods 0.000 description 1
239000005357 flat glass Substances 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000007689 inspection Methods 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
238000009533 lab test Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
239000000155 melt Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
230000035515 penetration Effects 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
239000011669 selenium Substances 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
238000004383 yellowing Methods 0.000 description 1

Landscapes

Glass Compositions (AREA)

CA 2020882 1989-08-07 1990-07-11 Verre opale photosensible a reaction rapide Abandoned CA2020882A1 (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA 2020882 CA2020882A1 (fr)	1989-08-07	1990-07-11	Verre opale photosensible a reaction rapide

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US390,064		1989-08-07
CA 2020882 CA2020882A1 (fr)	1989-08-07	1990-07-11	Verre opale photosensible a reaction rapide

Publications (1)

Publication Number	Publication Date
CA2020882A1 true CA2020882A1 (fr)	1991-02-08

Family

ID=4145452

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2020882 Abandoned CA2020882A1 (fr)	1989-08-07	1990-07-11	Verre opale photosensible a reaction rapide

Country Status (1)

Country	Link
CA (1)	CA2020882A1 (fr)

1990
- 1990-07-11 CA CA 2020882 patent/CA2020882A1/fr not_active Abandoned

Legal Events

Date	Code	Title	Description
1995-01-11	FZDE	Dead

Publication	Publication Date	Title
US4979975A (en)	1990-12-25	Fast response photosensitive opal glasses
US4549894A (en)	1985-10-29	Ultraviolet absorbing photochromic glass of low silver content
US4251278A (en)	1981-02-17	Photochromic glasses which darken to a brown hue
US4980318A (en)	1990-12-25	High refractive index photochromic glasses
US4134747A (en)	1979-01-16	Method of forming transparent and opaque portions in a reducing atmosphere glass
JP2645288B2 (ja)	1997-08-25	急速退色、高屈折率光互変性ガラス
US4118214A (en)	1978-10-03	Treating polychromatic glass in reducing atmospheres
US4092139A (en)	1978-05-30	Process for making colored photosensitive glass
JP2024164110A (ja)	2024-11-26	Ｌｉ２Ｏ－Ａｌ２Ｏ３－ＳｉＯ２系結晶化ガラス
US5019538A (en)	1991-05-28	Colored photosensitive opal glasses
DE1496091A1 (de)	1969-03-06	Phototropische Glaskoerper
JPH10101369A (ja)	1998-04-21	紫外線赤外線吸収ガラス
EP0595002B1 (fr)	1997-06-18	Verres colorés et procédé
US3703388A (en)	1972-11-21	High refractive index photochromic glasses
US4022628A (en)	1977-05-10	Ion exchange-strengthened silicate glass filter for ultraviolet light
US2651146A (en)	1953-09-08	Method of opacifying the surface of glass articles
US3328182A (en)	1967-06-27	Phototropic glass article and method
CN1113219A (zh)	1995-12-13	高折光率光致变色棕色玻璃
EP0592864B1 (fr)	1998-01-07	Verres polarisants
US2515275A (en)	1950-07-18	Photosensitive glass
US3449103A (en)	1969-06-10	Photochromic glass making
JP2001510431A (ja)	2001-07-31	改良されたフォトクロミックガラス
US2515939A (en)	1950-07-18	Opacifiable photosensitive glasses
US2515942A (en)	1950-07-18	Photosensitive glass containing palladium
GB1009152A (en)	1965-11-10	Phototropic glass article and method of making it