CA2023585A1 - Adhesif thermofusible resistant a l'alteration engendree par la lumiere ultraviolette et a la migration de plastifiants - Google Patents

Adhesif thermofusible resistant a l'alteration engendree par la lumiere ultraviolette et a la migration de plastifiants

Info

Publication number: CA2023585A1
Authority: CA; Canada
Prior art keywords: adhesive; plasticizer; polymer; block copolymer; antioxidant
Prior art date: 1989-09-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2023585

Other languages

English (en)

Inventor

James Paul Szymanski

Eugene Richard Simmons

Jeffrey Scott Lindquist

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

HB Fuller Licensing and Financing Inc

Original Assignee

HB Fuller Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-09-08

Filing date

1990-08-20

Publication date

1991-03-09

1990-08-20 Application filed by HB Fuller Co filed Critical HB Fuller Co

1991-03-09 Publication of CA2023585A1 publication Critical patent/CA2023585A1/fr

Status Abandoned legal-status Critical Current

Links

239000004014 plasticizer Substances 0.000 title claims description 49
230000005012 migration Effects 0.000 title claims description 13
238000013508 migration Methods 0.000 title claims description 13
239000004831 Hot glue Substances 0.000 title description 12
230000015556 catabolic process Effects 0.000 title description 9
238000006731 degradation reaction Methods 0.000 title description 9
230000001070 adhesive effect Effects 0.000 claims abstract description 90
239000000853 adhesive Substances 0.000 claims abstract description 85
239000000203 mixture Substances 0.000 claims abstract description 42
239000012943 hotmelt Substances 0.000 claims abstract description 7
229920000642 polymer Polymers 0.000 claims description 36
229920001083 polybutene Polymers 0.000 claims description 35
239000011347 resin Substances 0.000 claims description 29
229920005989 resin Polymers 0.000 claims description 29
239000000178 monomer Substances 0.000 claims description 22
239000006096 absorbing agent Substances 0.000 claims description 20
239000003963 antioxidant agent Substances 0.000 claims description 18
-1 ethylene butylene Chemical group 0.000 claims description 15
230000003078 antioxidant effect Effects 0.000 claims description 14
229920001400 block copolymer Polymers 0.000 claims description 14
229920006395 saturated elastomer Polymers 0.000 claims description 14
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 10
229920006270 hydrocarbon resin Polymers 0.000 claims description 10
239000003381 stabilizer Substances 0.000 claims description 9
239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 7
229930195733 hydrocarbon Natural products 0.000 claims description 7
239000003017 thermal stabilizer Substances 0.000 claims description 7
229920001169 thermoplastic Polymers 0.000 claims description 7
239000004215 Carbon black (E152) Substances 0.000 claims description 6
239000013032 Hydrocarbon resin Substances 0.000 claims description 6
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 6
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
229920002367 Polyisobutene Polymers 0.000 claims description 6
229920001577 copolymer Polymers 0.000 claims description 6
150000002430 hydrocarbons Chemical class 0.000 claims description 6
230000005855 radiation Effects 0.000 claims description 6
230000001464 adherent effect Effects 0.000 claims description 5
239000012964 benzotriazole Substances 0.000 claims description 5
239000003795 chemical substances by application Substances 0.000 claims description 5
229920005992 thermoplastic resin Polymers 0.000 claims description 5
239000004793 Polystyrene Substances 0.000 claims description 4
150000001875 compounds Chemical class 0.000 claims description 4
125000000466 oxiranyl group Chemical group 0.000 claims description 4
229920002223 polystyrene Polymers 0.000 claims description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
239000005977 Ethylene Substances 0.000 claims description 2
238000007254 oxidation reaction Methods 0.000 claims description 2
150000004965 peroxy acids Chemical class 0.000 claims description 2
239000004416 thermosoftening plastic Substances 0.000 claims description 2
239000007795 chemical reaction product Substances 0.000 claims 3
125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims 2
239000005062 Polybutadiene Substances 0.000 claims 1
239000013036 UV Light Stabilizer Substances 0.000 claims 1
239000012963 UV stabilizer Substances 0.000 claims 1
238000005984 hydrogenation reaction Methods 0.000 claims 1
150000002978 peroxides Chemical class 0.000 claims 1
229920002857 polybutadiene Polymers 0.000 claims 1
230000000087 stabilizing effect Effects 0.000 claims 1
239000000463 material Substances 0.000 description 29
239000000758 substrate Substances 0.000 description 15
239000003153 chemical reaction reagent Substances 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 11
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
125000001931 aliphatic group Chemical group 0.000 description 10
235000007586 terpenes Nutrition 0.000 description 9
229920002554 vinyl polymer Polymers 0.000 description 8
150000001412 amines Chemical class 0.000 description 7
125000003118 aryl group Chemical group 0.000 description 7
150000003505 terpenes Chemical class 0.000 description 7
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 5
XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 5
238000000034 method Methods 0.000 description 5
239000002904 solvent Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 4
229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 4
IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
238000011109 contamination Methods 0.000 description 4
230000009477 glass transition Effects 0.000 description 4
239000003209 petroleum derivative Substances 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
150000003097 polyterpenes Chemical class 0.000 description 4
239000007787 solid Substances 0.000 description 4
229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 3
229920002633 Kraton (polymer) Polymers 0.000 description 3
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
238000002156 mixing Methods 0.000 description 3
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
229920000915 polyvinyl chloride Polymers 0.000 description 3
229920006132 styrene block copolymer Polymers 0.000 description 3
125000001424 substituent group Chemical group 0.000 description 3
HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 2
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
239000002313 adhesive film Substances 0.000 description 2
239000012790 adhesive layer Substances 0.000 description 2
239000002671 adjuvant Substances 0.000 description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
230000008859 change Effects 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 2
230000005670 electromagnetic radiation Effects 0.000 description 2
238000006735 epoxidation reaction Methods 0.000 description 2
238000009472 formulation Methods 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
239000010410 layer Substances 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
150000002989 phenols Chemical class 0.000 description 2
ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
229930195734 saturated hydrocarbon Natural products 0.000 description 2
JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
PIEXCQIOSMOEOU-UHFFFAOYSA-N 1-bromo-3-chloro-5,5-dimethylimidazolidine-2,4-dione Chemical class CC1(C)N(Br)C(=O)N(Cl)C1=O PIEXCQIOSMOEOU-UHFFFAOYSA-N 0.000 description 1
LRTOHSLOFCWHRF-UHFFFAOYSA-N 1-methyl-1h-indene Chemical compound C1=CC=C2C(C)C=CC2=C1 LRTOHSLOFCWHRF-UHFFFAOYSA-N 0.000 description 1
HQTRGFZLVRBFPT-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)-3-octadecylhenicosane-1,3-diol Chemical compound CCCCCCCCCCCCCCCCCCC(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC HQTRGFZLVRBFPT-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical compound OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 description 1
ULQQGOGMQRGFFR-UHFFFAOYSA-N 2-chlorobenzenecarboperoxoic acid Chemical compound OOC(=O)C1=CC=CC=C1Cl ULQQGOGMQRGFFR-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
GFJUOMJGSXRJJY-UHFFFAOYSA-N 2-methylprop-1-ene Chemical compound CC(C)=C.CC(C)=C GFJUOMJGSXRJJY-UHFFFAOYSA-N 0.000 description 1
YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
SHLIDWXKIUAKJY-UHFFFAOYSA-N 3-hydroxyprop-2-enoyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(=O)C=CO SHLIDWXKIUAKJY-UHFFFAOYSA-N 0.000 description 1
KUFNEMCYFOJAGR-UHFFFAOYSA-N 4-benzyl-2h-triazole Chemical class C=1C=CC=CC=1CC1=CNN=N1 KUFNEMCYFOJAGR-UHFFFAOYSA-N 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
238000005727 Friedel-Crafts reaction Methods 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
230000006750 UV protection Effects 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
238000002835 absorbance Methods 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000002998 adhesive polymer Substances 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
239000002168 alkylating agent Substances 0.000 description 1
229940100198 alkylating agent Drugs 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
229920005601 base polymer Polymers 0.000 description 1
230000008901 benefit Effects 0.000 description 1
KQNZLOUWXSAZGD-UHFFFAOYSA-N benzylperoxymethylbenzene Chemical compound C=1C=CC=CC=1COOCC1=CC=CC=C1 KQNZLOUWXSAZGD-UHFFFAOYSA-N 0.000 description 1
229930003642 bicyclic monoterpene Natural products 0.000 description 1
150000001604 bicyclic monoterpene derivatives Chemical class 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
229920006248 expandable polystyrene Polymers 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
239000011888 foil Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000011140 metalized polyester Substances 0.000 description 1
239000003863 metallic catalyst Substances 0.000 description 1
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
229960000969 phenyl salicylate Drugs 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
239000012815 thermoplastic material Substances 0.000 description 1
239000010409 thin film Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Adhesives Or Adhesive Processes (AREA)

CA 2023585 1989-09-08 1990-08-20 Adhesif thermofusible resistant a l'alteration engendree par la lumiere ultraviolette et a la migration de plastifiants Abandoned CA2023585A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US40465689A	1989-09-08	1989-09-08
US07/404,656		1989-09-08

Publications (1)

Publication Number	Publication Date
CA2023585A1 true CA2023585A1 (fr)	1991-03-09

Family

ID=23600498

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2023585 Abandoned CA2023585A1 (fr)	1989-09-08	1990-08-20	Adhesif thermofusible resistant a l'alteration engendree par la lumiere ultraviolette et a la migration de plastifiants

Country Status (2)

Country	Link
JP (1)	JPH03179075A (fr)
CA (1)	CA2023585A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1326939B1 (fr) *	2000-10-20	2006-02-15	3M Innovative Properties Company	Additif thermoplastique pour adhesifs thermofusibles a base d'elastomeres hydrocarbure thermoplastiques
TWI630253B (zh) *	2014-01-06	2018-07-21	科騰聚合物美國有限責任公司	包含具有高乙烯基及高二嵌段之苯乙烯－丁二烯聚合物之熱熔壓敏性黏著劑及熱固物

1990
- 1990-08-20 CA CA 2023585 patent/CA2023585A1/fr not_active Abandoned
- 1990-08-24 JP JP22142090A patent/JPH03179075A/ja active Pending

Also Published As

Publication number	Publication date
JPH03179075A (ja)	1991-08-05

Legal Events

Date	Code	Title	Description
1997-08-06	EEER	Examination request
2002-01-11	FZDE	Dead

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US5013785A (en)	1991-05-07	Pressure-sensitive adhesive composition comprising poly-4-methyl-1-pentene as tackifier
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EP3630906B1 (fr)	2022-10-26	Composition adhésive thermofusible sensible à la pression présentant des propriétés rhéologiques améliorées
AU2004253641A1 (en)	2005-01-13	Pressure-sensitive adhesive composition
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