CA2026152C - Melanges de polycarbonate ignifuge - Google Patents

Melanges de polycarbonate ignifuge Download PDF

Info

Publication number: CA2026152C
Authority: CA; Canada
Prior art keywords: weight; poly; molding composition; percent; thermoplastic molding
Prior art date: 1989-10-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002026152A

Other languages

English (en)

Other versions

CA2026152A1 (fr

Inventor

Winfried G. Paul

Sivaram Krishnan

Roger J. White

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer Corp

Original Assignee

Bayer Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-10-30

Filing date

1990-09-25

Publication date

2003-04-15

1990-09-25 Application filed by Bayer Corp filed Critical Bayer Corp

1991-05-01 Publication of CA2026152A1 publication Critical patent/CA2026152A1/fr

2003-04-15 Application granted granted Critical

2003-04-15 Publication of CA2026152C publication Critical patent/CA2026152C/fr

2010-09-25 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 43
229920000515 polycarbonate Polymers 0.000 title claims description 9
239000004417 polycarbonate Substances 0.000 title claims description 7
239000003063 flame retardant Substances 0.000 title description 4
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title description 3
229920000098 polyolefin Polymers 0.000 claims abstract description 21
238000009757 thermoplastic moulding Methods 0.000 claims abstract description 9
-1 poly(vinylidene fluoride) Polymers 0.000 claims description 19
150000001875 compounds Chemical class 0.000 claims description 10
229920002981 polyvinylidene fluoride Polymers 0.000 claims description 7
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
125000003118 aryl group Chemical group 0.000 claims description 4
125000005843 halogen group Chemical group 0.000 claims description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 claims description 2
125000005915 C6-C14 aryl group Chemical group 0.000 claims description 2
229910052783 alkali metal Inorganic materials 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims description 2
238000005227 gel permeation chromatography Methods 0.000 claims description 2
125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
238000000465 moulding Methods 0.000 claims description 2
229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 claims description 2
229920002620 polyvinyl fluoride Polymers 0.000 claims description 2
229920006395 saturated elastomer Polymers 0.000 claims description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
239000003340 retarding agent Substances 0.000 claims 1
239000000654 additive Substances 0.000 abstract description 4
230000000996 additive effect Effects 0.000 abstract description 3
238000000034 method Methods 0.000 description 7
238000002360 preparation method Methods 0.000 description 6
239000006085 branching agent Substances 0.000 description 5
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
229910052731 fluorine Inorganic materials 0.000 description 3
150000002989 phenols Chemical class 0.000 description 3
239000004431 polycarbonate resin Substances 0.000 description 3
229920005668 polycarbonate resin Polymers 0.000 description 3
150000003254 radicals Chemical class 0.000 description 3
239000011347 resin Substances 0.000 description 3
229920005989 resin Polymers 0.000 description 3
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
239000004425 Makrolon Substances 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
239000000178 monomer Substances 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
VPVTXVHUJHGOCM-UHFFFAOYSA-N 2,4-bis[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 VPVTXVHUJHGOCM-UHFFFAOYSA-N 0.000 description 1
MAQOZOILPAMFSW-UHFFFAOYSA-N 2,6-bis[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=C(CC=3C(=CC=C(C)C=3)O)C=C(C)C=2)O)=C1 MAQOZOILPAMFSW-UHFFFAOYSA-N 0.000 description 1
KAIRTVANLJFYQS-UHFFFAOYSA-N 2-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=CC=C1O KAIRTVANLJFYQS-UHFFFAOYSA-N 0.000 description 1
ZEKCYPANSOJWDH-UHFFFAOYSA-N 3,3-bis(4-hydroxy-3-methylphenyl)-1H-indol-2-one Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3NC2=O)C=2C=C(C)C(O)=CC=2)=C1 ZEKCYPANSOJWDH-UHFFFAOYSA-N 0.000 description 1
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
CUAUDSWILJWDOD-UHFFFAOYSA-N 4-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=C(O)C=C1 CUAUDSWILJWDOD-UHFFFAOYSA-N 0.000 description 1
AZZWZMUXHALBCQ-UHFFFAOYSA-N 4-[(4-hydroxy-3,5-dimethylphenyl)methyl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(CC=2C=C(C)C(O)=C(C)C=2)=C1 AZZWZMUXHALBCQ-UHFFFAOYSA-N 0.000 description 1
WZDLEYNMGWZAEJ-UHFFFAOYSA-N 4-[1-(4-hydroxy-3,5-dimethylphenyl)ethyl]-2,6-dimethylphenol Chemical compound C=1C(C)=C(O)C(C)=CC=1C(C)C1=CC(C)=C(O)C(C)=C1 WZDLEYNMGWZAEJ-UHFFFAOYSA-N 0.000 description 1
ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
XJGTVJRTDRARGO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]benzene-1,3-diol Chemical compound C=1C=C(O)C=C(O)C=1C(C)(C)C1=CC=C(O)C=C1 XJGTVJRTDRARGO-UHFFFAOYSA-N 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
ISAVYTVYFVQUDY-UHFFFAOYSA-N 4-tert-Octylphenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 ISAVYTVYFVQUDY-UHFFFAOYSA-N 0.000 description 1
QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
229930185605 Bisphenol Natural products 0.000 description 1
SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
229920006370 Kynar Polymers 0.000 description 1
239000002033 PVDF binder Substances 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
229940114055 beta-resorcylic acid Drugs 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
125000000068 chlorophenyl group Chemical group 0.000 description 1
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
239000000975 dye Substances 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000012456 homogeneous solution Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000006082 mold release agent Substances 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
SJDACOMXKWHBOW-UHFFFAOYSA-N oxyphenisatine Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2NC1=O SJDACOMXKWHBOW-UHFFFAOYSA-N 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
239000003017 thermal stabilizer Substances 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA002026152A 1989-10-30 1990-09-25 Melanges de polycarbonate ignifuge Expired - Lifetime CA2026152C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US42856189A	1989-10-30	1989-10-30
US07,428,561		1989-10-30

Publications (2)

Publication Number	Publication Date
CA2026152A1 CA2026152A1 (fr)	1991-05-01
CA2026152C true CA2026152C (fr)	2003-04-15

Family

ID=23699429

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002026152A Expired - Lifetime CA2026152C (fr)	1989-10-30	1990-09-25	Melanges de polycarbonate ignifuge

Country Status (5)

Country	Link
US (1)	US6323280B1 (fr)
EP (1)	EP0425894B1 (fr)
JP (1)	JPH03167253A (fr)
CA (1)	CA2026152C (fr)
DE (1)	DE69008110T2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0708149A1 (fr) *	1994-10-21	1996-04-24	Hoechst Aktiengesellschaft	Matériau de couche d'alignement pour dispositifs d'affichage à cristal liquide
EP1611176B1 (fr)	2003-02-21	2015-09-09	SABIC Global Technologies B.V.	Procédé de préparation de copolymères de polycarbonate-polysiloxane transparents hautes températures
US9127155B2 (en)	2012-04-11	2015-09-08	Sabic Global Technologies B.V.	Phosphorus free flame retardant composition
US10487208B2 (en)	2015-01-20	2019-11-26	Covestro Deutschland Ag	Flame-retardant molding compounds containing siloxane-containing polycarbonate block co-condensate
KR102480605B1 (ko)	2015-01-20	2022-12-26	코베스트로 도이칠란트 아게	실록산-함유 폴리카르보네이트 블록 공축합물을 함유하며 유리 섬유를 함유하는 난연성 성형 배합물
JP7761500B2 (ja) *	2022-01-28	2025-10-28	帝人株式会社	ポリカーボネート樹脂組成物および成形品

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3821326A (en) *	1972-05-03	1974-06-28	Uniroyal Inc	Polycarbonate-vinylidene fluoride hexafluoropropylene copolymer blend
US4391935A (en) *	1974-08-09	1983-07-05	General Electric Company	Flame retardant polycarbonate composition
US4252916A (en)	1978-12-06	1981-02-24	General Electric Company	Thermally stable translucent polycarbonate compositions
US4220583A (en) *	1978-12-06	1980-09-02	General Electric Company	Translucent, flame-retardant polycarbonate compositions
DE3414116A1 (de) *	1984-04-14	1985-10-24	Bayer Ag, 5090 Leverkusen	Uv-stabilisierte polycarbonatformkoerper
US4663391A (en)	1986-03-06	1987-05-05	General Electric Company	Polycarbonate composition exhibiting improved wear resistance
US4749738A (en) *	1986-12-19	1988-06-07	General Electric Company	Polycarbonate compositions exhibiting improved wear resistance
US4767818A (en) *	1987-03-23	1988-08-30	General Electric Company	Low gloss, flame retardant polycarbonate compositions
DE3903547A1 (de) *	1989-02-07	1990-08-09	Bayer Ag	Mischungen aus thermoplastischen polydiorganosiloxan-polycarbonat-blockcopolymeren mit polytetrafluorethylenen

1990
- 1990-09-25 CA CA002026152A patent/CA2026152C/fr not_active Expired - Lifetime
- 1990-10-17 DE DE69008110T patent/DE69008110T2/de not_active Expired - Fee Related
- 1990-10-17 EP EP90119899A patent/EP0425894B1/fr not_active Expired - Lifetime
- 1990-10-25 JP JP2286011A patent/JPH03167253A/ja active Pending
1995
- 1995-03-31 US US08/414,702 patent/US6323280B1/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
EP0425894B1 (fr)	1994-04-13
EP0425894A2 (fr)	1991-05-08
CA2026152A1 (fr)	1991-05-01
JPH03167253A (ja)	1991-07-19
US6323280B1 (en)	2001-11-27
EP0425894A3 (en)	1992-01-02
DE69008110T2 (de)	1994-07-28
DE69008110D1 (de)	1994-05-19

Legal Events

Date	Code	Title	Description
1997-08-07	EEER	Examination request
2010-09-25	MKEX	Expiry

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US4880864A (en)	1989-11-14	Thermoplastic polycarbonates and blends with enhanced flame retardant properties
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