CA2026910C - Destruction de composes organiques halogenes - Google Patents

Destruction de composes organiques halogenes Download PDF

Info

Publication number: CA2026910C
Authority: CA; Canada
Prior art keywords: medium; contaminated; organic compounds; contaminated medium; halogenated organic
Prior art date: 1990-10-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002026910A

Other languages

English (en)

Other versions

CA2026910A1 (fr

Inventor

Alfred Kornel

Charles J. Rogers

Harold L. Sparks

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BCD GROUP Inc

Original Assignee

BCD GROUP Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-10-04

Filing date

1990-10-04

Publication date

2000-11-21

1990-10-04 Application filed by BCD GROUP Inc filed Critical BCD GROUP Inc

1990-10-04 Priority to CA002026910A priority Critical patent/CA2026910C/fr

1992-04-05 Publication of CA2026910A1 publication Critical patent/CA2026910A1/fr

2000-11-21 Application granted granted Critical

2000-11-21 Publication of CA2026910C publication Critical patent/CA2026910C/fr

2010-10-04 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

150000002896 organic halogen compounds Chemical class 0.000 title claims abstract description 36
230000006378 damage Effects 0.000 title claims abstract description 30
238000000034 method Methods 0.000 claims abstract description 65
150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 21
239000007864 aqueous solution Substances 0.000 claims abstract description 17
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
239000001257 hydrogen Substances 0.000 claims abstract description 13
238000010438 heat treatment Methods 0.000 claims abstract description 12
150000002894 organic compounds Chemical class 0.000 claims abstract description 12
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 11
239000002253 acid Substances 0.000 claims abstract description 8
230000000694 effects Effects 0.000 claims abstract description 6
239000000839 emulsion Substances 0.000 claims abstract 5
239000002689 soil Substances 0.000 claims description 30
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 9
150000001720 carbohydrates Chemical class 0.000 claims description 8
235000014633 carbohydrates Nutrition 0.000 claims description 8
229930195733 hydrocarbon Natural products 0.000 claims description 8
150000002430 hydrocarbons Chemical class 0.000 claims description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
125000001931 aliphatic group Chemical group 0.000 claims description 4
239000013049 sediment Substances 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
239000010802 sludge Substances 0.000 claims description 3
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
239000002250 absorbent Substances 0.000 claims description 2
230000002745 absorbent Effects 0.000 claims description 2
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
150000001412 amines Chemical class 0.000 claims description 2
235000014113 dietary fatty acids Nutrition 0.000 claims description 2
239000000194 fatty acid Substances 0.000 claims description 2
229930195729 fatty acid Natural products 0.000 claims description 2
150000004665 fatty acids Chemical class 0.000 claims description 2
239000007788 liquid Substances 0.000 claims description 2
229910017604 nitric acid Inorganic materials 0.000 claims description 2
150000003505 terpenes Chemical class 0.000 claims description 2
235000007586 terpenes Nutrition 0.000 claims description 2
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
150000001298 alcohols Chemical class 0.000 claims 1
239000001117 sulphuric acid Substances 0.000 claims 1
235000011149 sulphuric acid Nutrition 0.000 claims 1
239000003153 chemical reaction reagent Substances 0.000 description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
239000000852 hydrogen donor Substances 0.000 description 17
239000000463 material Substances 0.000 description 14
150000001875 compounds Chemical class 0.000 description 11
239000000203 mixture Substances 0.000 description 9
IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
238000004458 analytical method Methods 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 5
229930006000 Sucrose Natural products 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
239000000356 contaminant Substances 0.000 description 5
238000004821 distillation Methods 0.000 description 5
239000000047 product Substances 0.000 description 5
239000005720 sucrose Substances 0.000 description 5
150000003462 sulfoxides Chemical class 0.000 description 5
DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 description 4
229950006824 dieldrin Drugs 0.000 description 4
NGPMUTDCEIKKFM-UHFFFAOYSA-N dieldrin Natural products CC1=C(Cl)C2(Cl)C3C4CC(C5OC45)C3C1(Cl)C2(Cl)Cl NGPMUTDCEIKKFM-UHFFFAOYSA-N 0.000 description 4
238000002156 mixing Methods 0.000 description 4
239000003921 oil Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
239000000039 congener Substances 0.000 description 3
230000018044 dehydration Effects 0.000 description 3
238000006297 dehydration reaction Methods 0.000 description 3
238000009826 distribution Methods 0.000 description 3
239000012530 fluid Substances 0.000 description 3
JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 3
JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 3
238000002290 gas chromatography-mass spectrometry Methods 0.000 description 3
229960002809 lindane Drugs 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
239000008188 pellet Substances 0.000 description 3
229920000151 polyglycol Polymers 0.000 description 3
239000010695 polyglycol Substances 0.000 description 3
239000000523 sample Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
239000003990 capacitor Substances 0.000 description 2
239000000470 constituent Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
239000000080 wetting agent Substances 0.000 description 2
BTAGRXWGMYTPBY-UHFFFAOYSA-N 1,2,3-trichloro-4-(2,3,4-trichlorophenyl)benzene Chemical compound ClC1=C(Cl)C(Cl)=CC=C1C1=CC=C(Cl)C(Cl)=C1Cl BTAGRXWGMYTPBY-UHFFFAOYSA-N 0.000 description 1
PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 1
YVGGHNCTFXOJCH-UHFFFAOYSA-N DDT Chemical compound C1=CC(Cl)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(Cl)C=C1 YVGGHNCTFXOJCH-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
101100400378 Mus musculus Marveld2 gene Proteins 0.000 description 1
INPDFIMLLXXDOQ-UHFFFAOYSA-N Phycocyanobilin Natural products CCC1=C(C)C(=CC2=NC(=C/c3[nH]c(C=C/4C(C(C(N4)=O)C)=CC)c(C)c3CCC(=O)O)C(=C2C)CCC(=O)O)NC1=O INPDFIMLLXXDOQ-UHFFFAOYSA-N 0.000 description 1
241000220317 Rosa Species 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001339 alkali metal compounds Chemical class 0.000 description 1
229910000102 alkali metal hydride Inorganic materials 0.000 description 1
150000008046 alkali metal hydrides Chemical class 0.000 description 1
150000001346 alkyl aryl ethers Chemical class 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 1
230000001186 cumulative effect Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000005202 decontamination Methods 0.000 description 1
230000003588 decontaminative effect Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
239000000383 hazardous chemical Substances 0.000 description 1
231100000086 high toxicity Toxicity 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000002352 nonmutagenic effect Effects 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
CEOCDNVZRAIOQZ-UHFFFAOYSA-N pentachlorobenzene Chemical compound ClC1=CC(Cl)=C(Cl)C(Cl)=C1Cl CEOCDNVZRAIOQZ-UHFFFAOYSA-N 0.000 description 1
230000002085 persistent effect Effects 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
150000003071 polychlorinated biphenyls Chemical class 0.000 description 1
OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical class O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 1
230000005180 public health Effects 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
231100000378 teratogenic Toxicity 0.000 description 1
230000003390 teratogenic effect Effects 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

Fire-Extinguishing Compositions (AREA)
Processing Of Solid Wastes (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA002026910A 1990-10-04 1990-10-04 Destruction de composes organiques halogenes Expired - Fee Related CA2026910C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA002026910A CA2026910C (fr)	1990-10-04	1990-10-04	Destruction de composes organiques halogenes

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA002026910A CA2026910C (fr)	1990-10-04	1990-10-04	Destruction de composes organiques halogenes

Publications (2)

Publication Number	Publication Date
CA2026910A1 CA2026910A1 (fr)	1992-04-05
CA2026910C true CA2026910C (fr)	2000-11-21

Family

ID=4146109

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002026910A Expired - Fee Related CA2026910C (fr)	1990-10-04	1990-10-04	Destruction de composes organiques halogenes

Country Status (1)

Country	Link
CA (1)	CA2026910C (fr)

1990
- 1990-10-04 CA CA002026910A patent/CA2026910C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2026910A1 (fr)	1992-04-05

Legal Events

Date	Code	Title	Description
1997-10-03	EEER	Examination request
2004-10-04	MKLA	Lapsed

Publication	Publication Date	Title
US5064526A (en)	1991-11-12	Method for the base-catalyzed decomposition of halogenated and non-halogenated organic compounds in a contaminated medium
US5019175A (en)	1991-05-28	Method for the destruction of halogenated organic compounds in a contaminated medium
US4337368A (en)	1982-06-29	Reagent and method for decomposing halogenated organic compounds
US4632742A (en)	1986-12-30	Process for the decomposition and decontamination of organic substances and halogenated toxic materials
CA1337902C (fr)	1996-01-09	Procedes de decontamination pour materiaux, supports ou produits pollues
WO1986006010A1 (fr)	1986-10-23	Procede de decontamination du sol
US4602994A (en)	1986-07-29	Removal of PCBs and other halogenated organic compounds from organic fluids
US4417977A (en)	1983-11-29	Removal of PCBS and other halogenated organic compounds from organic fluids
US5149444A (en)	1992-09-22	Process for the decontamination of soils, sediments, and sludges
US5039350A (en)	1991-08-13	Method for the decomposition of halogenated organic compounds in a contaminated medium
CA2128013A1 (fr)	1993-07-22	Methode d'hydrodeshalogenation de composes organiques halogenes dans des milieux aqueux
US5043054A (en)	1991-08-27	Process for dehalogenation of contaminated waste materials
EP0118858A1 (fr)	1984-09-19	Procédé de décomposition et décontamination de composés organiques et d'agents toxiques halogénés
CA2026910C (fr)	2000-11-21	Destruction de composes organiques halogenes
US5152844A (en)	1992-10-06	Degradation of polychlorinated biphenyls
US5174893A (en)	1992-12-29	Process for dehalogenation of contaminated waste materials
NZ245624A (en)	1995-04-27	Destruction of halogenated organic compounds and reduction of non-halogenated organic compounds contained in a contaminated medium by adding an aqueous hydrogen donor, alkali metal hydroxide, heating to dehydrate and then to destroy the halogen compounds
RU2090272C1 (ru)	1997-09-20	Способ восстановительного разложения галоидированных или негалоидированных органических загрязняющих соединений, содержащихся в загрязненной среде
EP0850666B1 (fr)	2002-04-03	Méthode pour la décomposition des polychlorobiphényles
JP4159165B2 (ja)	2008-10-01	有機ハロゲン化合物で汚染された固形物の浄化方法とその装置
WO1991009808A1 (fr)	1991-07-11	Compositions reactives contenant un ion superoxyde, permettant la degradation de composes organiques halogenes
NZ251522A (en)	1996-07-26	Reductive decomposition of chemical contaminants by reaction with at least one compound of an alkaline earth metal or alkali metal, h-donor compound, catalyst and heat
JP3342197B2 (ja)	2002-11-05	ダイオキシン類の処理方法
Sawyer et al.	1994	Reactive compositions containing superoxide ion for the degradation of halogenated organic compounds
WO1996009092A1 (fr)	1996-03-28	Procede de decomposition de composes organiques halogenes