CA2029484A1 - Separation de gaz a l'aide de membranes absorbantes - Google Patents

Separation de gaz a l'aide de membranes absorbantes

Info

Publication number
CA2029484A1
CA2029484A1 CA2029484A CA2029484A CA2029484A1 CA 2029484 A1 CA2029484 A1 CA 2029484A1 CA 2029484 A CA2029484 A CA 2029484A CA 2029484 A CA2029484 A CA 2029484A CA 2029484 A1 CA2029484 A1 CA 2029484A1
Authority
CA
Canada
Prior art keywords
gas separation
membranes
separation
primary components
adsorptive material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2029484A
Other languages
English (en)
Other versions
CA2029484C (fr
Inventor
Madhukar Bhaskara Rao
Shivaji Sircar
Timothy Christopher Golden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MID-AMERICA COMMERCIALIZATION Corp ("MACC")
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23732930&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2029484(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Publication of CA2029484A1 publication Critical patent/CA2029484A1/fr
Application granted granted Critical
Publication of CA2029484C publication Critical patent/CA2029484C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09B—EDUCATIONAL OR DEMONSTRATION APPLIANCES; APPLIANCES FOR TEACHING, OR COMMUNICATING WITH, THE BLIND, DEAF OR MUTE; MODELS; PLANETARIA; GLOBES; MAPS; DIAGRAMS
    • G09B9/00—Simulators for teaching or training purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/108—Inorganic support material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1213—Laminated layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/147—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing embedded adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/028—Molecular sieves
    • B01D71/0281—Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/045—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes using membranes, e.g. selective permeation
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09B—EDUCATIONAL OR DEMONSTRATION APPLIANCES; APPLIANCES FOR TEACHING, OR COMMUNICATING WITH, THE BLIND, DEAF OR MUTE; MODELS; PLANETARIA; GLOBES; MAPS; DIAGRAMS
    • G09B9/00—Simulators for teaching or training purposes
    • G09B9/003—Simulators for teaching or training purposes for military purposes and tactics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/081—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/082—Cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/15—Use of additives
    • B01D2323/218—Additive materials
    • B01D2323/2181—Inorganic additives
    • B01D2323/21813—Metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02833—Pore size more than 10 and up to 100 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/04—Characteristic thickness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Theoretical Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Educational Technology (AREA)
  • General Physics & Mathematics (AREA)
  • Educational Administration (AREA)
  • Physics & Mathematics (AREA)
  • Business, Economics & Management (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Cette invention concerne des membranes composites semi-perméables renfermant un matériau adsorbant poreux déposé sur un substrat poreux et servant à la séparation de mélanges gazeux. Le procédé de séparation repose sur l'adsorption d'un ou de plusieurs constituants primaires par les pores du matériau adsorbant et la diffusion par écoulement de surface à travers la membrane pour la production d'un perméat enrichi d'un ou de plusieurs de constituants primaires. Cette invention concerne également des méthodes de fabrication desdites membranes composites.
CA002029484A 1989-11-14 1990-11-07 Separation de gaz a l'aide de membranes absorbantes Expired - Fee Related CA2029484C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43656689A 1989-11-14 1989-11-14
US07/436566 1989-11-14

Publications (2)

Publication Number Publication Date
CA2029484A1 true CA2029484A1 (fr) 1991-05-15
CA2029484C CA2029484C (fr) 1999-04-27

Family

ID=23732930

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002029484A Expired - Fee Related CA2029484C (fr) 1989-11-14 1990-11-07 Separation de gaz a l'aide de membranes absorbantes

Country Status (6)

Country Link
EP (1) EP0428052B1 (fr)
KR (1) KR930001603B1 (fr)
CA (1) CA2029484C (fr)
DE (1) DE69031973T2 (fr)
ES (1) ES2110958T3 (fr)
MY (1) MY104776A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114956057A (zh) * 2022-06-24 2022-08-30 闪速优科(深圳)新材料有限公司 一种柔性石墨烯薄膜的制备方法

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DE4107089A1 (de) * 1991-03-06 1992-09-10 Deutsche Forsch Luft Raumfahrt Verfahren und vorrichtung zum trennen und transportieren von gasen und/oder von durch dissoziation an oberflaechen entstandenen gasmolekuel-bruchstuecken durch oberflaechendiffusion
JPH05105420A (ja) * 1991-03-29 1993-04-27 Ngk Insulators Ltd ゼオライト結晶体の合成膜およびその製造方法
DE4117284A1 (de) * 1991-05-27 1992-12-03 Studiengesellschaft Kohle Mbh Verfahren zur herstellung von mikroporoesen keramikmembranen fuer die trennung von gas- und fluessigkeitsgemischen
TW242120B (fr) * 1992-06-24 1995-03-01 Air Prod & Chem
IL105442A (en) * 1993-04-19 1996-01-19 Carbon Membranes Ltd Method for the separation of gases at low temperatures
EP0711202B1 (fr) * 1993-07-27 1999-12-22 The University Of Arizona Membrane reactive concue pour filtrer et purifier des gaz contenant des impuretes, et son procede d'utilisation
US5332424A (en) * 1993-07-28 1994-07-26 Air Products And Chemicals, Inc. Hydrocarbon fractionation by adsorbent membranes
WO1996034677A1 (fr) * 1995-05-03 1996-11-07 Pall Corporation Dispositifs et procedes relatifs a la filtration et/ou la purification de fluides
US5634354A (en) * 1996-05-08 1997-06-03 Air Products And Chemicals, Inc. Olefin recovery from olefin-hydrogen mixtures
US5897915A (en) * 1996-10-28 1999-04-27 Corning Incorporated Coated substrates, method for producing same, and use therefor
ES2151781B1 (es) * 1997-05-14 2001-08-16 Consejo Superior Investigacion Procedimiento para la preparacion de membranas de carbono.
ES2151815B1 (es) * 1998-05-18 2001-08-16 Consejo Superior Investigacion Procedimiento para la preparacion de membranas de carbono para la separacion de gases permanentes.
DE19849216A1 (de) 1998-10-26 2000-04-27 Andreas Noack Verfahren und Vorrichtung zur Trennung von Fluidgemischen (Thermomembranverfahren)
ES2155381B1 (es) * 1999-04-15 2001-12-01 Consejo Superior Investigacion Procedimiento para la preparacion de membranas de carbono para la separacion de gases.
US7465692B1 (en) 2000-03-16 2008-12-16 Pall Corporation Reactive media, methods of use and assemblies for purifying
EP1292380B1 (fr) 2000-06-22 2005-12-28 E.I. Dupont De Nemours And Company Membranes de carbone nanoporeuses a matrice melangee
DE10051910A1 (de) 2000-10-19 2002-05-02 Membrana Mundi Gmbh Flexible, poröse Membranen und Adsorbentien, und Verfahren zu deren Herstellung
KR100466250B1 (ko) * 2002-09-30 2005-01-14 한국과학기술원 다양한 형태의 콜로이드 결정 및 다공성 구조체의 제조방법
DE102006034601B3 (de) 2006-07-26 2008-02-07 Schmidt, Klaus, Prof. Dr. Rückhaltung von Edelgasen im Atemgas bei beatmeten Patienten mit Hilfe von Membranseparation
US8118914B2 (en) * 2008-09-05 2012-02-21 Alstom Technology Ltd. Solid materials and method for CO2 removal from gas stream
WO2014094139A1 (fr) 2012-12-22 2014-06-26 Dmf Medical Incorporated Circuit anesthésique ayant une membrane à fibres creuses
KR101634653B1 (ko) * 2014-03-26 2016-06-29 국방과학연구소 분석대상가스 농축용 흡착제 및 제조방법, 분석대상가스의 검출방법
US10086337B2 (en) 2014-11-30 2018-10-02 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Composite carbon molecular sieve membranes having anti-substructure collapse particles loaded in a core thereof
RU2596257C1 (ru) * 2015-04-29 2016-09-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ фракционирования смесей низкомолекулярных углеводородов с использованием капиллярной конденсации на микропористых мембранах
TWI746476B (zh) * 2015-11-13 2021-11-21 美商艾克頌美孚硏究工程公司 混合之二甲苯的分離
JP7074679B2 (ja) * 2016-03-16 2022-05-24 ダウ グローバル テクノロジーズ エルエルシー 炭化塩化ビニリデンコポリマーガス分離膜を介するガスの分離及び膜の調製のためのプロセス
US12036518B2 (en) * 2019-01-25 2024-07-16 Dow Global Technologies Llc Carbon molecular sieve membrane produced from a carbon forming polymer-polyvinylidene chloride copolymer blend
CN114370596B (zh) * 2021-12-08 2023-07-14 中国航空工业集团公司北京长城计量测试技术研究所 一种提升碱金属纯度的气室及实现方法

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JPS6028826A (ja) * 1983-07-26 1985-02-14 Hiroshi Suzuki かご型ゼオライト薄膜表層を有する複合膜及びその製造法
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JPH0628706B2 (ja) * 1984-10-30 1994-04-20 宏志 鈴木 ゼオライト，層間利用化合物又は結晶格子間利用化合物を多孔質支持体の細孔内に保有する複合体及びその製造法
JPH0824815B2 (ja) * 1987-08-21 1996-03-13 住友精化株式会社 ガスの分離方法
FR2625690B1 (fr) * 1988-01-11 1993-04-23 Inst Francais Du Petrole Procede de separation des constituants d'un melange en phase gazeuse au moyen d'une membrane composite

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114956057A (zh) * 2022-06-24 2022-08-30 闪速优科(深圳)新材料有限公司 一种柔性石墨烯薄膜的制备方法
CN114956057B (zh) * 2022-06-24 2023-07-04 闪速优科(深圳)新材料有限公司 一种柔性石墨烯薄膜的制备方法

Also Published As

Publication number Publication date
DE69031973T2 (de) 1998-04-30
CA2029484C (fr) 1999-04-27
KR930001603B1 (ko) 1993-03-06
ES2110958T3 (es) 1998-03-01
EP0428052A3 (en) 1991-09-11
MY104776A (en) 1994-05-31
KR910009328A (ko) 1991-06-28
EP0428052A2 (fr) 1991-05-22
DE69031973D1 (de) 1998-02-26
EP0428052B1 (fr) 1998-01-21

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Effective date: 20071107