CA2035681C - Detergent composition - Google Patents

Detergent composition

Info

Publication number: CA2035681C
Authority: CA; Canada
Prior art keywords: sulfosuccinate; isethionate; composition according; weight; acyl
Prior art date: 1990-02-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002035681A

Other languages

English (en)

French (fr)

Other versions

CA2035681A1 (en

Inventor

Karla Jean Rys

Alan Paul Greene

Frederick Sylvio Osmer

Joseph James Podgorsky

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-02-09

Filing date

1991-02-05

Publication date

1998-12-08

1991-02-05 Application filed by Unilever PLC filed Critical Unilever PLC

1991-08-10 Publication of CA2035681A1 publication Critical patent/CA2035681A1/en

1998-12-08 Application granted granted Critical

1998-12-08 Publication of CA2035681C publication Critical patent/CA2035681C/en

2011-02-05 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 52
239000003599 detergent Substances 0.000 title description 6
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 42
-1 acyl isethionate ester salts Chemical class 0.000 claims abstract description 24
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
125000002252 acyl group Chemical group 0.000 claims description 11
239000000344 soap Substances 0.000 claims description 11
150000002148 esters Chemical class 0.000 claims description 9
238000009826 distribution Methods 0.000 claims description 7
229940045998 sodium isethionate Drugs 0.000 claims description 6
LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 claims description 6
235000021588 free fatty acids Nutrition 0.000 claims description 4
239000000463 material Substances 0.000 claims 1
238000009472 formulation Methods 0.000 description 15
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 14
238000012360 testing method Methods 0.000 description 14
206010015150 Erythema Diseases 0.000 description 13
231100000321 erythema Toxicity 0.000 description 13
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
235000014113 dietary fatty acids Nutrition 0.000 description 12
229930195729 fatty acid Natural products 0.000 description 12
239000000194 fatty acid Substances 0.000 description 12
150000004665 fatty acids Chemical class 0.000 description 12
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 9
238000011156 evaluation Methods 0.000 description 7
239000002304 perfume Substances 0.000 description 7
239000004408 titanium dioxide Substances 0.000 description 7
235000021355 Stearic acid Nutrition 0.000 description 6
238000000034 method Methods 0.000 description 6
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 6
239000011780 sodium chloride Substances 0.000 description 6
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 6
239000008117 stearic acid Substances 0.000 description 6
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 5
229920001223 polyethylene glycol Polymers 0.000 description 5
238000007619 statistical method Methods 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
229940079776 sodium cocoyl isethionate Drugs 0.000 description 4
238000005406 washing Methods 0.000 description 4
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
235000013162 Cocos nucifera Nutrition 0.000 description 3
244000060011 Cocos nucifera Species 0.000 description 3
206010030113 Oedema Diseases 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
235000010265 sodium sulphite Nutrition 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
238000010998 test method Methods 0.000 description 3
238000011282 treatment Methods 0.000 description 3
239000004606 Fillers/Extenders Substances 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
229940079840 cocoyl isethionate Drugs 0.000 description 2
238000006482 condensation reaction Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000003623 enhancer Substances 0.000 description 2
230000007794 irritation Effects 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000006277 sulfonation reaction Methods 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
239000000271 synthetic detergent Substances 0.000 description 2
FUFLCEKSBBHCMO-UHFFFAOYSA-N 11-dehydrocorticosterone Natural products O=C1CCC2(C)C3C(=O)CC(C)(C(CC4)C(=O)CO)C4C3CCC2=C1 FUFLCEKSBBHCMO-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
MFYSYFVPBJMHGN-ZPOLXVRWSA-N Cortisone Chemical compound O=C1CC[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 MFYSYFVPBJMHGN-ZPOLXVRWSA-N 0.000 description 1
MFYSYFVPBJMHGN-UHFFFAOYSA-N Cortisone Natural products O=C1CCC2(C)C3C(=O)CC(C)(C(CC4)(O)C(=O)CO)C4C3CCC2=C1 MFYSYFVPBJMHGN-UHFFFAOYSA-N 0.000 description 1
201000004624 Dermatitis Diseases 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
239000004909 Moisturizer Substances 0.000 description 1
206010040880 Skin irritation Diseases 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
229940124599 anti-inflammatory drug Drugs 0.000 description 1
229940125715 antihistaminic agent Drugs 0.000 description 1
239000000739 antihistaminic agent Substances 0.000 description 1
208000010668 atopic eczema Diseases 0.000 description 1
239000002585 base Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003749 cleanliness Effects 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229960004544 cortisone Drugs 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
229940031098 ethanolamine Drugs 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
150000002193 fatty amides Chemical class 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
239000003906 humectant Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000003607 modifier Substances 0.000 description 1
230000001333 moisturizer Effects 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
231100000475 skin irritation Toxicity 0.000 description 1
230000036556 skin irritation Effects 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
230000000699 topical effect Effects 0.000 description 1
238000007039 two-step reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/126—Acylisethionates

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

CA002035681A 1990-02-09 1991-02-05 Detergent composition Expired - Lifetime CA2035681C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US47768290A	1990-02-09	1990-02-09
US07/477,682		1990-02-09

Publications (2)

Publication Number	Publication Date
CA2035681A1 CA2035681A1 (en)	1991-08-10
CA2035681C true CA2035681C (en)	1998-12-08

Family

ID=23896912

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002035681A Expired - Lifetime CA2035681C (en)	1990-02-09	1991-02-05	Detergent composition

Country Status (8)

Country	Link
EP (1)	EP0441652B1 (de)
JP (1)	JP2975450B2 (de)
AU (1)	AU637668B2 (de)
BR (1)	BR9100525A (de)
CA (1)	CA2035681C (de)
DE (1)	DE69111259T2 (de)
ES (1)	ES2076462T3 (de)
ZA (1)	ZA91953B (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2146117A1 (en) *	1992-10-05	1994-04-14	Dennis L. Fost	Synthetic detergent bars and the method of making the same
WO1994017167A1 (en) *	1993-01-19	1994-08-04	Unilever Plc	Low soap bar composition
DE4409321A1 (de) *	1994-03-18	1995-09-21	Henkel Kgaa	Detergensgemische
DE69531303T2 (de) *	1994-05-10	2004-04-22	The Procter & Gamble Company, Cincinnati	Syndetseifenriegel zur körperpflege mit geringem gehalt an nichtionischen polyethylen-/polypropylenglycolpolymeren für verbesserte zartheit
US5683973A (en) *	1996-02-15	1997-11-04	Lever Brothers Company, Division Of Conopco, Inc.	Mild bar compositions comprising blends of higher melting point polyalkylene glycol(s) and lower melting point polyalkylene glycol(s) as processing aids
GB9623935D0 (en) *	1996-11-18	1997-01-08	Unilever Plc	Aqueous cleansing composition
FR3007641B1 (fr) *	2013-06-27	2016-11-18	Oreal	Composition nettoyante stable sous forme de solide souple

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1402265A (en) *	1971-08-24	1975-08-06	Colgate Palmolive Co	Soap-synthetic detergent combination bars
IT1165608B (it) *	1978-01-19	1987-04-22	Unilever Nv	Barra detergente, particolarmente per lavaggio personale
US4335025A (en) *	1980-02-19	1982-06-15	Witco Chemical Corporation	Process for the preparation of synthetic detergent bars, and products produced thereby
DE3335705A1 (de) *	1983-10-01	1985-04-11	Chemische Werke Hüls AG, 4370 Marl	Fluessiger teppichreiniger
ES2061668T3 (es) *	1987-09-17	1994-12-16	Procter & Gamble	Barra de tocador para limpieza de la piel con bajo contenido de humedad.
US4954282A (en) *	1989-04-19	1990-09-04	Lever Brothers Company	Acyl isethionate skin cleansing compositions

1991
- 1991-02-04 AU AU70206/91A patent/AU637668B2/en not_active Expired
- 1991-02-05 CA CA002035681A patent/CA2035681C/en not_active Expired - Lifetime
- 1991-02-07 BR BR919100525A patent/BR9100525A/pt not_active IP Right Cessation
- 1991-02-08 ES ES91301046T patent/ES2076462T3/es not_active Expired - Lifetime
- 1991-02-08 EP EP91301046A patent/EP0441652B1/de not_active Expired - Lifetime
- 1991-02-08 ZA ZA91953A patent/ZA91953B/xx unknown
- 1991-02-08 JP JP3103994A patent/JP2975450B2/ja not_active Expired - Lifetime
- 1991-02-08 DE DE69111259T patent/DE69111259T2/de not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE69111259D1 (de)	1995-08-24
CA2035681A1 (en)	1991-08-10
ES2076462T3 (es)	1995-11-01
JP2975450B2 (ja)	1999-11-10
JPH04234810A (ja)	1992-08-24
AU637668B2 (en)	1993-06-03
AU7020691A (en)	1991-08-15
EP0441652B1 (de)	1995-07-19
EP0441652A1 (de)	1991-08-14
ZA91953B (en)	1992-10-28
DE69111259T2 (de)	1995-12-21
BR9100525A (pt)	1991-10-29

Legal Events

Date	Code	Title	Description
1994-11-18	EEER	Examination request
2011-02-05	MKEX	Expiry

Publication	Publication Date	Title
US5372751A (en)	1994-12-13	Acyl isethionate skin cleaning compositions containing betaines, amido sulfosuccinates or combinations of the two
US4954282A (en)	1990-09-04	Acyl isethionate skin cleansing compositions
US4695395A (en)	1987-09-22	Cleaning compositions with skin protection agents
EP0203750B2 (de)	1997-11-19	Besonders milde Hautreinigungszusammensetzung
US4812253A (en)	1989-03-14	Ultra mild skin cleansing composition
AU671434B2 (en)	1996-08-29	Hair shampoo containing acyl lactylate and alkyl polyglycoside
AU768304B2 (en)	2003-12-04	Bar and process thereof
US5096608A (en)	1992-03-17	Ultra mild skin cleansing composition
US5310508A (en)	1994-05-10	Mild personal cleansing compositions containing sodium alcohol ethoxy glyceryl sulfonate
AU625494B2 (en)	1992-07-16	Skin cleansing toilet bar with low moisture content
US5296159A (en)	1994-03-22	Mild soap-synbar
NZ226220A (en)	1992-01-29	Toilet bar soap comprising synthetic surfactant, moisturiser, soap and two or more polymeric skin-feel and mildness aids
EP0748367B1 (de)	1998-05-27	Hautreinigungsmittel
EP0542526B1 (de)	1997-04-23	Hautreinigungsmittel
AU637668B2 (en)	1993-06-03	Detergent composition
CA2048408C (en)	1996-01-02	Acyl isethionate skin cleansing compositions containing selected betaines
US5108640A (en)	1992-04-28	Personal cleansing synbar with improved rinsing
WO1996036313A1 (en)	1996-11-21	Aqueous liquid cleansing composition containing fatty acid soaps