CA2041870C - Procede d'electrodeposition d'un alliage de nickel et de cobalt et solution d'electrolyte utilisee a cette fin - Google Patents

Procede d'electrodeposition d'un alliage de nickel et de cobalt et solution d'electrolyte utilisee a cette fin Download PDF

Info

Publication number: CA2041870C
Authority: CA; Canada
Prior art keywords: electrolyte solution; process according; nickel; cobalt; cathode
Prior art date: 1990-05-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002041870A

Other languages

English (en)

Other versions

CA2041870A1 (fr

Inventor

Roger Van Brusselt

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

TI Group Automotive Systems Ltd

Original Assignee

TI Group Automotive Systems Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-05-08

Filing date

1991-05-06

Publication date

2001-04-24

1991-05-06 Application filed by TI Group Automotive Systems Ltd filed Critical TI Group Automotive Systems Ltd

1991-11-09 Publication of CA2041870A1 publication Critical patent/CA2041870A1/fr

2001-04-24 Application granted granted Critical

2001-04-24 Publication of CA2041870C publication Critical patent/CA2041870C/fr

2011-05-06 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000008151 electrolyte solution Substances 0.000 title claims abstract description 42
238000000034 method Methods 0.000 title claims abstract description 40
238000000576 coating method Methods 0.000 title claims abstract description 18
QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 title claims abstract description 17
239000011248 coating agent Substances 0.000 title claims abstract description 17
229910000531 Co alloy Inorganic materials 0.000 title claims abstract description 15
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 22
238000005868 electrolysis reaction Methods 0.000 claims abstract description 16
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 15
229910052742 iron Inorganic materials 0.000 claims abstract description 14
239000004327 boric acid Substances 0.000 claims abstract description 13
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims abstract description 13
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 12
KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims abstract description 10
239000000243 solution Substances 0.000 claims description 10
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 8
229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
235000011152 sodium sulphate Nutrition 0.000 claims description 7
239000003792 electrolyte Substances 0.000 claims description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
LWUVWAREOOAHDW-UHFFFAOYSA-N lead silver Chemical compound [Ag].[Pb] LWUVWAREOOAHDW-UHFFFAOYSA-N 0.000 claims description 2
229910000510 noble metal Inorganic materials 0.000 claims description 2
239000010936 titanium Substances 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
239000001117 sulphuric acid Substances 0.000 claims 4
235000011149 sulphuric acid Nutrition 0.000 claims 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 2
229910000361 cobalt sulfate Inorganic materials 0.000 abstract description 8
229940044175 cobalt sulfate Drugs 0.000 abstract description 8
229910000363 nickel(II) sulfate Inorganic materials 0.000 abstract description 8
229910017052 cobalt Inorganic materials 0.000 description 24
239000010941 cobalt Substances 0.000 description 24
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 24
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 18
229910052759 nickel Inorganic materials 0.000 description 9
230000000694 effects Effects 0.000 description 7
238000000151 deposition Methods 0.000 description 6
239000000463 material Substances 0.000 description 5
238000005260 corrosion Methods 0.000 description 4
230000007797 corrosion Effects 0.000 description 3
230000008021 deposition Effects 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
PQMFVUNERGGBPG-UHFFFAOYSA-N (6-bromopyridin-2-yl)hydrazine Chemical compound NNC1=CC=CC(Br)=N1 PQMFVUNERGGBPG-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000004020 conductor Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005137 deposition process Methods 0.000 description 1
-1 for example Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
239000000155 melt Substances 0.000 description 1
KSEORDDPLGPXCR-UHFFFAOYSA-N potassium;sulfurocyanidic acid Chemical compound [K].OS(=O)(=O)C#N KSEORDDPLGPXCR-UHFFFAOYSA-N 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000005496 tempering Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electroplating And Plating Baths Therefor (AREA)
Electroplating Methods And Accessories (AREA)
Electrolytic Production Of Metals (AREA)

CA002041870A 1990-05-08 1991-05-06 Procede d'electrodeposition d'un alliage de nickel et de cobalt et solution d'electrolyte utilisee a cette fin Expired - Lifetime CA2041870C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
BE9000486A BE1004124A3 (fr)	1990-05-08	1990-05-08	Procede pour appliquer par electrolyse une couche d'un alliage nickel-cobalt sur un objet et solution d'electrolyte utilisee a cet effet.
BE09000486		1990-05-08

Publications (2)

Publication Number	Publication Date
CA2041870A1 CA2041870A1 (fr)	1991-11-09
CA2041870C true CA2041870C (fr)	2001-04-24

Family

ID=3884783

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002041870A Expired - Lifetime CA2041870C (fr)	1990-05-08	1991-05-06	Procede d'electrodeposition d'un alliage de nickel et de cobalt et solution d'electrolyte utilisee a cette fin

Country Status (7)

Country	Link
EP (1)	EP0456628B1 (fr)
JP (1)	JP3224401B2 (fr)
KR (1)	KR100229165B1 (fr)
AT (1)	ATE141961T1 (fr)
BE (1)	BE1004124A3 (fr)
CA (1)	CA2041870C (fr)
DE (1)	DE69121630T2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR100793840B1 (ko)	2007-01-10	2008-01-10	김기형	코발트 혼합 전해도금액 및 이를 이용한 코발트 혼합도금액 코팅제품

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE715415A (fr) *	1967-06-30	1968-10-16
JP5843469B2 (ja)	2011-04-26	2016-01-13	キヤノン株式会社	振動波モータ
JP5622958B2 (ja)	2014-06-06	2014-11-12	京セラドキュメントソリューションズ株式会社	画像形成装置

1990
- 1990-05-08 BE BE9000486A patent/BE1004124A3/fr not_active IP Right Cessation
1991
- 1991-05-06 CA CA002041870A patent/CA2041870C/fr not_active Expired - Lifetime
- 1991-05-07 EP EP91870074A patent/EP0456628B1/fr not_active Expired - Lifetime
- 1991-05-07 AT AT91870074T patent/ATE141961T1/de not_active IP Right Cessation
- 1991-05-07 DE DE69121630T patent/DE69121630T2/de not_active Expired - Lifetime
- 1991-05-08 KR KR1019910007441A patent/KR100229165B1/ko not_active Expired - Lifetime
- 1991-05-08 JP JP10275391A patent/JP3224401B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE69121630D1 (de)	1996-10-02
EP0456628A1 (fr)	1991-11-13
EP0456628B1 (fr)	1996-08-28
DE69121630T2 (de)	1997-02-06
ATE141961T1 (de)	1996-09-15
BE1004124A3 (fr)	1992-09-29
JPH04228594A (ja)	1992-08-18
CA2041870A1 (fr)	1991-11-09
JP3224401B2 (ja)	2001-10-29
KR100229165B1 (ko)	1999-11-01
KR920005739A (ko)	1992-04-03

Legal Events

Date	Code	Title	Description
1998-04-27	EEER	Examination request
2011-05-06	MKEX	Expiry

Publication	Publication Date	Title
CA1254168A (fr)	1989-05-16	Electrodeposition d'un revetement en alliage de fer et de zinc
US4652348A (en)	1987-03-24	Method for the production of alloys possessing high elastic modulus and improved magnetic properties by electrodeposition
CA1118710A (fr)	1982-02-23	Nickelages durs, resistants a la chaleur
US3901771A (en)	1975-08-26	One-side electrocoating
Wilcox et al.	1996	Zinc manganese alloy electrodeposition
US3970537A (en)	1976-07-20	Electrolytic treating apparatus
US6365031B1 (en)	2002-04-02	High current density zinc sulfate electrogalvanizing process and composition
US4249999A (en)	1981-02-10	Electrolytic zinc-nickel alloy plating
CA2236933A1 (fr)	1998-12-18	Electrodeposition de nickel a faible contrainte
US4767509A (en)	1988-08-30	Nickel-phosphorus electroplating and bath therefor
US1920964A (en)	1933-08-08	Electrodeposition of alloys
CA2041870C (fr)	2001-04-24	Procede d'electrodeposition d'un alliage de nickel et de cobalt et solution d'electrolyte utilisee a cette fin
US4167459A (en)	1979-09-11	Electroplating with Ni-Cu alloy
US1960029A (en)	1934-05-22	Electrodeposition of alloys
GB2133040A (en)	1984-07-18	Copper plating bath process and anode therefore
US4804444A (en)	1989-02-14	Method of producing a both-side electrogalvanized steel strip in a chloride bath
Chitharanjan Hegde et al.	2009	Electrodeposition and characterization Zn-Co alloy
KRISIINAN et al.	1996	Effect of organic acids in nickel plating
US3247083A (en)	1966-04-19	Method of chromium electrodeposition
Walker et al.	1970	Stress in copper electrodeposits from the sulphate bath
Savel'ev et al.	1988	Effect of Composition of Sulphate Electrolyte and Copper Plating Regime on the Uniformity and Properties of Coatings
Dennis	1972	Decorative electrodeposited metallic coatings
KR890012023A (ko)	1989-08-24	강화된 인산염화능을 갖는 일측 전기도금강 스트립의 제조 장치 및 방법
KR100276314B1 (ko)	2000-12-15	표면 광택, 균일성 및 내식성이 우수한 전기 주석도금 강판의 제조방법
Mpoyo et al.	1993	High speed electro-deposition of alloys. II. Manganese-nickel alloys