CA2060712C - Pile electrochimique rechargeable au lithium a haute tension - Google Patents

Pile electrochimique rechargeable au lithium a haute tension

Info

Publication number: CA2060712C
Authority: CA; Canada
Prior art keywords: cell; electrolyte; electrochemical cell; cathode; polymer
Prior art date: 1991-05-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002060712A

Other languages

English (en)

Other versions

CA2060712A1 (fr

Inventor

Steven M. Slane

Charles W. Walker, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

United States Department of the Army

Original Assignee

United States Department of the Army

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-05-20

Filing date

1992-02-05

Publication date

1998-12-01

1992-02-05 Application filed by United States Department of the Army filed Critical United States Department of the Army

1992-11-21 Publication of CA2060712A1 publication Critical patent/CA2060712A1/fr

1998-12-01 Application granted granted Critical

1998-12-01 Publication of CA2060712C publication Critical patent/CA2060712C/fr

2012-02-05 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229910052744 lithium Inorganic materials 0.000 title claims abstract description 28
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 27
239000003792 electrolyte Substances 0.000 claims abstract description 26
229920000642 polymer Polymers 0.000 claims abstract description 17
QENGPZGAWFQWCZ-UHFFFAOYSA-N 3-Methylthiophene Chemical compound CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims abstract description 11
150000003839 salts Chemical class 0.000 claims abstract description 8
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 claims 4
230000001351 cycling effect Effects 0.000 abstract description 13
229910015013 LiAsF Inorganic materials 0.000 abstract description 8
210000004027 cell Anatomy 0.000 description 57
239000002904 solvent Substances 0.000 description 10
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 9
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
238000007600 charging Methods 0.000 description 6
230000003647 oxidation Effects 0.000 description 6
238000007254 oxidation reaction Methods 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 4
239000010408 film Substances 0.000 description 4
238000009830 intercalation Methods 0.000 description 4
229910052697 platinum Inorganic materials 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
150000001450 anions Chemical class 0.000 description 3
229920001940 conductive polymer Polymers 0.000 description 3
238000000034 method Methods 0.000 description 3
239000000758 substrate Substances 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000002939 deleterious effect Effects 0.000 description 2
210000001787 dendrite Anatomy 0.000 description 2
238000005755 formation reaction Methods 0.000 description 2
239000007789 gas Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
229910002804 graphite Inorganic materials 0.000 description 2
239000010439 graphite Substances 0.000 description 2
231100001261 hazardous Toxicity 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
-1 metal oxide compounds Chemical class 0.000 description 2
229910052976 metal sulfide Inorganic materials 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
230000036647 reaction Effects 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
239000010936 titanium Substances 0.000 description 2
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
241000212342 Sium Species 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000005910 alkyl carbonate group Chemical group 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
239000010405 anode material Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
229940075397 calomel Drugs 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000002322 conducting polymer Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
230000003467 diminishing effect Effects 0.000 description 1
238000004880 explosion Methods 0.000 description 1
239000011888 foil Substances 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000001457 metallic cations Chemical class 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
239000012046 mixed solvent Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229920006254 polymer film Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
239000010409 thin film Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
230000003245 working effect Effects 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Secondary Cells (AREA)
Battery Electrode And Active Subsutance (AREA)

CA002060712A 1991-05-20 1992-02-05 Pile electrochimique rechargeable au lithium a haute tension Expired - Fee Related CA2060712C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/703,319		1991-05-20
US07/703,319 USH1422H (en)	1991-05-20	1991-05-20	High voltage lithium rechargeable electrochemical cell

Publications (2)

Publication Number	Publication Date
CA2060712A1 CA2060712A1 (fr)	1992-11-21
CA2060712C true CA2060712C (fr)	1998-12-01

Family

ID=24824924

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002060712A Expired - Fee Related CA2060712C (fr)	1991-05-20	1992-02-05	Pile electrochimique rechargeable au lithium a haute tension

Country Status (2)

Country	Link
US (1)	USH1422H (fr)
CA (1)	CA2060712C (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7767335B2 (en) *	2003-05-16	2010-08-03	The United States Of America As Represented By The Secretary Of The Navy	High-voltage battery switch

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4728589A (en) *	1980-03-11	1988-03-01	University Patents, Inc.	Reversible electrochemical doping of conjugated polymers and secondary batteries based thereon
DE3843412A1 (de) *	1988-04-22	1990-06-28	Bayer Ag	Neue polythiophene, verfahren zu ihrer herstellung und ihre verwendung

1991
- 1991-05-20 US US07/703,319 patent/USH1422H/en not_active Abandoned
1992
- 1992-02-05 CA CA002060712A patent/CA2060712C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2060712A1 (fr)	1992-11-21
USH1422H (en)	1995-03-07

Legal Events

Date	Code	Title	Description
1996-02-08	EEER	Examination request
2001-02-05	MKLA	Lapsed

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CA3139843C (fr)	2023-08-29	Pile rechargeable
CA2156800C (fr)	2003-04-29	Additifs aromatiques polymerisables pour proteger les batteries rechargeables non aqueuses au lithium contre les surcharges
EP0776058B1 (fr)	2001-08-29	Monomères aromatiques agents de développement de gaz pour la protection de piles au lithium non-aqueuses contre la surcharge
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US6203947B1 (en)	2001-03-20	Long cycle-life alkali metal battery
US6387571B1 (en)	2002-05-14	Electrolyte for a rechargeable cell
US6291107B1 (en)	2001-09-18	Non-aqueous electrolyte battery
US6074776A (en)	2000-06-13	Polymerizable additives for making non-aqueous rechargeable lithium batteries safe after overcharge
CA1306283C (fr)	1992-08-11	Accumulateur a electrolyte non aqueux muni d'un separateur special
AU2020264696B2 (en)	2023-02-02	Rechargeable battery cell
JP4050251B2 (ja)	2008-02-20	有機電解液及びこれを採用したリチウム電池
EP0122381B1 (fr)	1987-11-25	Batterie secondaire contenant de l'organoborate électrolyte
US6489061B1 (en)	2002-12-03	Secondary non-aquenous electrochemical cell configured to improve overcharge and overdischarge acceptance ability
GB2083273A (en)	1982-03-17	Method for increasing recycling life of non-aqueous cells
US6511769B1 (en)	2003-01-28	Electrolyte for rechargeable lithium battery
US4499161A (en)	1985-02-12	Electrochemical cell using dimethoxymethane and/or trimethoxymethane as solvent for electrolyte
KR920009805B1 (ko)	1992-10-22	라튬 이차전지
KR20180124722A (ko)	2018-11-21	리튬금속 이차전지용 전해질 및 이를 포함하는 리튬금속 이차전지
US4751160A (en)	1988-06-14	Organic electrolyte for use in a lithium rechargeable electrochemical cell and lithium rechargeable electrochemical cell including said organic electrolyte
Shirota et al.	1991	Electrochemically doped poly (N-vinylcarbazole) as an electrode material for rechargeable batteries
CA2060712C (fr)	1998-12-01	Pile electrochimique rechargeable au lithium a haute tension
JPH08185851A (ja)	1996-07-16	電池用電極および該電極を使用した二次電池
EP0239976A2 (fr)	1987-10-07	Batterie secondaire à électrolyte fondu
USH1462H (en)	1995-07-04	Solid state electrochemical lithium/polymer cell
USH1721H (en)	1998-04-07	Aqueous rechargeable battery