CA2073025C - Continuous constant pressure staging of solid-vapor compound reactors - Google Patents
Continuous constant pressure staging of solid-vapor compound reactorsInfo
- Publication number
- CA2073025C CA2073025C CA002073025A CA2073025A CA2073025C CA 2073025 C CA2073025 C CA 2073025C CA 002073025 A CA002073025 A CA 002073025A CA 2073025 A CA2073025 A CA 2073025A CA 2073025 C CA2073025 C CA 2073025C
- Authority
- CA
- Canada
- Prior art keywords
- compounds
- gaseous reactant
- reactor
- pressure
- reactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 178
- 239000000376 reactant Substances 0.000 claims abstract description 158
- 238000006243 chemical reaction Methods 0.000 claims abstract description 69
- 238000000034 method Methods 0.000 claims abstract description 52
- 239000013529 heat transfer fluid Substances 0.000 claims abstract description 47
- 239000007787 solid Substances 0.000 claims abstract description 36
- 238000004891 communication Methods 0.000 claims abstract description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 22
- 239000003463 adsorbent Substances 0.000 claims description 17
- 238000003795 desorption Methods 0.000 claims description 17
- 238000001179 sorption measurement Methods 0.000 claims description 17
- 230000001174 ascending effect Effects 0.000 claims description 15
- 239000007789 gas Substances 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 9
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 8
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910001868 water Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 150000004706 metal oxides Chemical group 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 5
- 239000001569 carbon dioxide Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- 150000004678 hydrides Chemical class 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 150000003973 alkyl amines Chemical class 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052723 transition metal Inorganic materials 0.000 claims description 4
- 150000003624 transition metals Chemical class 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 150000004763 sulfides Chemical class 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 3
- 229910001510 metal chloride Inorganic materials 0.000 claims 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 230000008569 process Effects 0.000 description 14
- 239000003507 refrigerant Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 8
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- 238000005086 pumping Methods 0.000 description 3
- 238000002336 sorption--desorption measurement Methods 0.000 description 3
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 229910001623 magnesium bromide Inorganic materials 0.000 description 2
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 229910019131 CoBr2 Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001622 calcium bromide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- -1 complex compound Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000004137 mechanical activation Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000008207 working material Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
- F25B17/08—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt
- F25B17/083—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt with two or more boiler-sorbers operating alternately
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/62—Absorption based systems
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Separation Of Gases By Adsorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US436,431 | 1989-11-14 | ||
| US07/436,431 US5025635A (en) | 1989-11-14 | 1989-11-14 | Continuous constant pressure staging of solid-vapor compound reactors |
| PCT/US1990/006392 WO1991007627A1 (en) | 1989-11-14 | 1990-11-05 | Continuous constant pressure staging of solid-vapor compound reactors |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2073025A1 CA2073025A1 (en) | 1991-05-15 |
| CA2073025C true CA2073025C (en) | 2001-06-12 |
Family
ID=23732373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002073025A Expired - Fee Related CA2073025C (en) | 1989-11-14 | 1990-11-05 | Continuous constant pressure staging of solid-vapor compound reactors |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5025635A (de) |
| EP (1) | EP0500720B1 (de) |
| JP (1) | JPH05504612A (de) |
| AT (1) | ATE132612T1 (de) |
| AU (1) | AU639506B2 (de) |
| CA (1) | CA2073025C (de) |
| DE (1) | DE69024660T2 (de) |
| ES (1) | ES2082014T3 (de) |
| GR (1) | GR3019436T3 (de) |
| MX (1) | MX172855B (de) |
| NZ (1) | NZ235962A (de) |
| WO (1) | WO1991007627A1 (de) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5664427A (en) * | 1989-03-08 | 1997-09-09 | Rocky Research | Rapid sorption cooling or freezing appliance |
| US5477706A (en) * | 1991-11-19 | 1995-12-26 | Rocky Research | Heat transfer apparatus and methods for solid-vapor sorption systems |
| US5628205A (en) * | 1989-03-08 | 1997-05-13 | Rocky Research | Refrigerators/freezers incorporating solid-vapor sorption reactors capable of high reaction rates |
| US5598721A (en) * | 1989-03-08 | 1997-02-04 | Rocky Research | Heating and air conditioning systems incorporating solid-vapor sorption reactors capable of high reaction rates |
| US5241831A (en) * | 1989-11-14 | 1993-09-07 | Rocky Research | Continuous constant pressure system for staging solid-vapor compounds |
| US5263330A (en) * | 1989-07-07 | 1993-11-23 | Rocky Research | Discrete constant pressure system for staging solid-vapor compounds |
| US5335510A (en) * | 1989-11-14 | 1994-08-09 | Rocky Research | Continuous constant pressure process for staging solid-vapor compounds |
| US5354324A (en) * | 1990-10-18 | 1994-10-11 | The General Hospital Corporation | Laser induced platelet inhibition |
| FR2687462A1 (fr) * | 1992-02-14 | 1993-08-20 | Elf Aquitaine | Dispositif pour la production de froid et/ou de chaleur par reaction solide-gaz. |
| US5291942A (en) * | 1993-05-24 | 1994-03-08 | Gas Research Institute | Multiple stage sorption and desorption process and apparatus |
| US5386705A (en) * | 1993-08-27 | 1995-02-07 | California Institute Of Technology | Staged regenerative sorption heat pump |
| US5463879A (en) * | 1994-01-04 | 1995-11-07 | California Institute Of Technology | Heat cascading regenerative sorption heat pump |
| US5442931A (en) * | 1994-08-02 | 1995-08-22 | Gas Research Institute | Simplified adsorption heat pump using passive heat recuperation |
| US5842356A (en) * | 1995-09-20 | 1998-12-01 | Sun Microsystems, Inc. | Electromagnetic wave-activated sorption refrigeration system |
| KR19990045764A (ko) * | 1995-09-20 | 1999-06-25 | 핀트족 마르시아디 | 흡수쌍 냉동 장치 |
| US5855119A (en) | 1995-09-20 | 1999-01-05 | Sun Microsystems, Inc. | Method and apparatus for cooling electrical components |
| US6244056B1 (en) | 1995-09-20 | 2001-06-12 | Sun Microsystems, Inc. | Controlled production of ammonia and other gases |
| US5916259A (en) * | 1995-09-20 | 1999-06-29 | Sun Microsystems, Inc. | Coaxial waveguide applicator for an electromagnetic wave-activated sorption system |
| US5873258A (en) * | 1995-09-20 | 1999-02-23 | Sun Microsystems, Inc | Sorption refrigeration appliance |
| US6138469A (en) | 1995-09-20 | 2000-10-31 | Sun Microsystems, Inc. | Refrigeration system for electronic components having environmental isolation |
| JPH11514733A (ja) * | 1995-11-01 | 1999-12-14 | ジェイ．，ジュニア バウアー，ジョン | バランス吸着式冷蔵装置 |
| US5985309A (en) * | 1996-05-24 | 1999-11-16 | Massachusetts Institute Of Technology | Preparation of particles for inhalation |
| US6224842B1 (en) | 1999-05-04 | 2001-05-01 | Rocky Research | Heat and mass transfer apparatus and method for solid-vapor sorption systems |
| US7003979B1 (en) | 2000-03-13 | 2006-02-28 | Sun Microsystems, Inc. | Method and apparatus for making a sorber |
| US6318453B1 (en) * | 2000-04-26 | 2001-11-20 | Energy Conversion Devices, Inc. | Hydrogen cooled hydrogen storage unit having maximized cooling efficiency |
| US8037686B2 (en) * | 2002-11-01 | 2011-10-18 | George Lasker | Uncoupled, thermal-compressor, gas-turbine engine |
| US20050126171A1 (en) * | 2002-11-01 | 2005-06-16 | George Lasker | Uncoupled, thermal-compressor, gas-turbine engine |
| EP1711755A4 (de) * | 2004-01-28 | 2011-03-09 | Commw Scient Ind Res Org | Verfahren, vorrichtung und system zur wärmeübertragung |
| US20070151988A1 (en) * | 2005-12-14 | 2007-07-05 | Saucedo Victor M | Constant pressure delivery vessel and system |
| US8968515B2 (en) * | 2006-05-01 | 2015-03-03 | Board Of Trustees Of Michigan State University | Methods for pretreating biomass |
| US9206446B2 (en) | 2006-05-01 | 2015-12-08 | Board Of Trustees Of Michigan State University | Extraction of solubles from plant biomass for use as microbial growth stimulant and methods related thereto |
| WO2008155543A2 (en) * | 2007-06-18 | 2008-12-24 | Thermal Energy Systems Ltd | Heat pump |
| US20090095012A1 (en) * | 2007-10-12 | 2009-04-16 | Atsushi Akisawa | Double-effect adsorption refrigeration device |
| US8425674B2 (en) * | 2008-10-24 | 2013-04-23 | Exxonmobil Research And Engineering Company | System using unutilized heat for cooling and/or power generation |
| US8945245B2 (en) | 2009-08-24 | 2015-02-03 | The Michigan Biotechnology Institute | Methods of hydrolyzing pretreated densified biomass particulates and systems related thereto |
| US10457810B2 (en) | 2009-08-24 | 2019-10-29 | Board Of Trustees Of Michigan State University | Densified biomass products containing pretreated biomass fibers |
| CA2760840C (en) | 2009-08-24 | 2014-12-02 | Board Of Trustees Of Michigan State University | Pretreated densified biomass products and methods of making and using same |
| EP2561084A4 (de) | 2010-04-19 | 2013-10-23 | Univ Michigan State | Verzehrbare lignozellulose-biomasse sowie extrakte daraus und verfahren zu ihrer herstellung |
| US8394177B2 (en) | 2010-06-01 | 2013-03-12 | Michigan Biotechnology Institute | Method of separating components from a gas stream |
| JP5761205B2 (ja) * | 2011-01-24 | 2015-08-12 | 富士通株式会社 | 吸着器及び吸着式ヒートポンプ |
| US9982931B2 (en) * | 2015-04-28 | 2018-05-29 | Rocky Research | Systems and methods for controlling refrigeration cycles of sorption reactors based on recuperation time |
| US9951977B2 (en) * | 2015-07-30 | 2018-04-24 | International Business Machines Corporation | Adsorbing heat exchanger |
| US12480446B2 (en) * | 2023-01-16 | 2025-11-25 | Pratt & Whitney Canada Corp. | Thermal compression reheating cycle |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US668310A (en) * | 1899-07-11 | 1901-02-19 | Dry Air Refrigerator Company | Process of refrigeration. |
| GB272868A (en) * | 1926-06-17 | 1927-12-15 | Sulzer Ag | Improvements in or relating to absorption refrigerating machines |
| US1887909A (en) * | 1929-06-08 | 1932-11-15 | Siemens Ag | Absorption machine |
| US2088276A (en) * | 1931-12-08 | 1937-07-27 | Siemens Ag | System for the conversion of heat |
| US2496459A (en) * | 1942-06-06 | 1950-02-07 | Kleen Refrigerator Inc | Absorption or adsorption refrigeration |
| US4637218A (en) * | 1974-11-04 | 1987-01-20 | Tchernev Dimiter I | Heat pump energized by low-grade heat source |
| NL7601906A (nl) * | 1976-02-25 | 1977-08-29 | Philips Nv | Cyclische desorptiekoelmachine resp. - warmte- pomp. |
| GB1583491A (en) * | 1977-06-01 | 1981-01-28 | Cjb Developments Ltd | Adsorption heat pump |
| US4372376A (en) * | 1980-12-09 | 1983-02-08 | The United States Of America As Represented By The United States Department Of Energy | Heat pump apparatus |
| GB2095818B (en) * | 1981-03-27 | 1985-10-02 | Exxon Research Engineering Co | Staged adsorption/resorption heat pump |
| DE3277930D1 (en) * | 1981-07-31 | 1988-02-11 | Seikisui Chemical Co Ltd | Metal hydride heat pump system |
| US4439994A (en) * | 1982-07-06 | 1984-04-03 | Hybrid Energy Systems, Inc. | Three phase absorption systems and methods for refrigeration and heat pump cycles |
| US4610148A (en) * | 1985-05-03 | 1986-09-09 | Shelton Samuel V | Solid adsorbent heat pump system |
| DE3532093C1 (de) * | 1985-09-09 | 1987-04-09 | Schiedel Gmbh & Co | Diskontinuierlich arbeitende Sorptions-Speichervorrichtung mit Feststoffabsorber |
| FR2590356B1 (fr) * | 1985-11-19 | 1989-06-02 | Jeumont Schneider | Dispositif pour la production en continu de chaud et de froid |
-
1989
- 1989-11-14 US US07/436,431 patent/US5025635A/en not_active Expired - Lifetime
-
1990
- 1990-11-05 CA CA002073025A patent/CA2073025C/en not_active Expired - Fee Related
- 1990-11-05 AU AU67590/90A patent/AU639506B2/en not_active Ceased
- 1990-11-05 DE DE69024660T patent/DE69024660T2/de not_active Expired - Fee Related
- 1990-11-05 ES ES90917245T patent/ES2082014T3/es not_active Expired - Lifetime
- 1990-11-05 JP JP3500486A patent/JPH05504612A/ja active Pending
- 1990-11-05 AT AT90917245T patent/ATE132612T1/de not_active IP Right Cessation
- 1990-11-05 NZ NZ235962A patent/NZ235962A/en unknown
- 1990-11-05 EP EP90917245A patent/EP0500720B1/de not_active Expired - Lifetime
- 1990-11-05 WO PCT/US1990/006392 patent/WO1991007627A1/en not_active Ceased
- 1990-11-12 MX MX023288A patent/MX172855B/es unknown
-
1996
- 1996-03-27 GR GR960400822T patent/GR3019436T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU639506B2 (en) | 1993-07-29 |
| JPH05504612A (ja) | 1993-07-15 |
| DE69024660D1 (de) | 1996-02-15 |
| ES2082014T3 (es) | 1996-03-16 |
| EP0500720A4 (en) | 1993-06-23 |
| GR3019436T3 (en) | 1996-06-30 |
| ATE132612T1 (de) | 1996-01-15 |
| DE69024660T2 (de) | 1996-07-11 |
| MX172855B (es) | 1994-01-17 |
| EP0500720A1 (de) | 1992-09-02 |
| AU6759090A (en) | 1991-06-13 |
| US5025635A (en) | 1991-06-25 |
| EP0500720B1 (de) | 1996-01-03 |
| WO1991007627A1 (en) | 1991-05-30 |
| CA2073025A1 (en) | 1991-05-15 |
| NZ235962A (en) | 1992-12-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |