CA2078155C - Compositions detergentes - Google Patents

Compositions detergentes

Info

Publication number: CA2078155C
Authority: CA; Canada
Prior art keywords: composition; detergent; zeolite; detergency builder; zeolite map
Prior art date: 1991-09-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002078155A

Other languages

English (en)

Other versions

CA2078155A1 (fr

Inventor

Andrew Paul Chapple

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-09-18

Filing date

1992-09-14

Publication date

1997-06-03

1992-09-14 Application filed by Unilever PLC filed Critical Unilever PLC

1993-03-19 Publication of CA2078155A1 publication Critical patent/CA2078155A1/fr

1997-06-03 Application granted granted Critical

1997-06-03 Publication of CA2078155C publication Critical patent/CA2078155C/fr

2012-09-14 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 79
239000003599 detergent Substances 0.000 title claims abstract description 48
239000010457 zeolite Substances 0.000 claims abstract description 60
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 59
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 57
150000001875 compounds Chemical class 0.000 claims abstract description 19
239000004115 Sodium Silicate Substances 0.000 claims abstract description 17
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 17
229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 17
239000004411 aluminium Substances 0.000 claims abstract description 15
229910052782 aluminium Inorganic materials 0.000 claims abstract description 15
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
229910052710 silicon Inorganic materials 0.000 claims abstract description 13
239000010703 silicon Substances 0.000 claims abstract description 13
-1 nonionic Chemical group 0.000 claims description 14
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
229910052708 sodium Inorganic materials 0.000 claims description 8
239000011734 sodium Substances 0.000 claims description 8
125000000129 anionic group Chemical group 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 5
125000002091 cationic group Chemical group 0.000 claims description 3
239000004744 fabric Substances 0.000 abstract description 16
238000005406 washing Methods 0.000 abstract description 6
239000000463 material Substances 0.000 description 11
239000007844 bleaching agent Substances 0.000 description 10
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 9
239000004615 ingredient Substances 0.000 description 9
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
238000002474 experimental method Methods 0.000 description 8
239000002736 nonionic surfactant Substances 0.000 description 8
239000000344 soap Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
239000003795 chemical substances by application Substances 0.000 description 6
239000008187 granular material Substances 0.000 description 6
229910000323 aluminium silicate Inorganic materials 0.000 description 5
235000019589 hardness Nutrition 0.000 description 5
238000000034 method Methods 0.000 description 5
239000002243 precursor Substances 0.000 description 5
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
239000011575 calcium Substances 0.000 description 4
239000002002 slurry Substances 0.000 description 4
229910000029 sodium carbonate Inorganic materials 0.000 description 4
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 4
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 3
239000000843 powder Substances 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
229920000742 Cotton Polymers 0.000 description 2
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
108091005804 Peptidases Proteins 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
239000004365 Protease Substances 0.000 description 2
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
239000001768 carboxy methyl cellulose Substances 0.000 description 2
239000008233 hard water Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
108010020132 microbial serine proteinases Proteins 0.000 description 2
125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
150000003333 secondary alcohols Chemical class 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000000429 sodium aluminium silicate Substances 0.000 description 2
235000012217 sodium aluminium silicate Nutrition 0.000 description 2
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
230000002195 synergetic effect Effects 0.000 description 2
229920002994 synthetic fiber Polymers 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
229920006243 acrylic copolymer Polymers 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
239000005018 casein Substances 0.000 description 1
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
235000021240 caseins Nutrition 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000004851 dishwashing Methods 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
239000000976 ink Substances 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000004900 laundering Methods 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000003921 oil Substances 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000004967 organic peroxy acids Chemical class 0.000 description 1
239000002304 perfume Substances 0.000 description 1
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
239000002994 raw material Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
239000008234 soft water Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Detergent Compositions (AREA)

CA002078155A 1991-09-18 1992-09-14 Compositions detergentes Expired - Lifetime CA2078155C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB919119958A GB9119958D0 (en)	1991-09-18	1991-09-18	Detergent compositions
GB9119958.8		1991-09-18

Publications (2)

Publication Number	Publication Date
CA2078155A1 CA2078155A1 (fr)	1993-03-19
CA2078155C true CA2078155C (fr)	1997-06-03

Family

ID=10701627

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002078155A Expired - Lifetime CA2078155C (fr)	1991-09-18	1992-09-14	Compositions detergentes

Country Status (8)

Country	Link
EP (1)	EP0533392B1 (fr)
JP (1)	JPH05202384A (fr)
BR (1)	BR9203532A (fr)
CA (1)	CA2078155C (fr)
DE (1)	DE69225449T2 (fr)
ES (1)	ES2116320T3 (fr)
GB (1)	GB9119958D0 (fr)
ZA (1)	ZA927167B (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4304474A1 (de) *	1993-02-15	1994-08-18	Henkel Kgaa	Tensid- und builderhaltiges Waschmitteladditiv
EP0781320B2 (fr) †	1994-09-13	2013-10-16	Kao Corporation	Procede de lavage
GB2303858A (en) *	1995-08-02	1997-03-05	Procter & Gamble	Detergent composition
GB9519606D0 (en) *	1995-09-26	1995-11-29	Procter & Gamble	Detergent composition
KR100258495B1 (ko) *	1995-11-22	2000-07-01	가오가부시끼가이샤	의료용 분말 세제 조성물
GB9605533D0 (en)	1996-03-15	1996-05-15	Unilever Plc	Modified aluminosilicate
GB9605534D0 (en) *	1996-03-15	1996-05-15	Unilever Plc	Detergent compositions
FR2794646B1 (fr)	1999-06-09	2001-09-21	Ethypharm Lab Prod Ethiques	Microgranules de sulfate de morphine, procede de preparation et composition les contenant
MY133398A (en) *	1999-07-09	2007-11-30	Colgate Palmolive Co	Fabric cleaning composition containing zeolite
US6204239B1 (en) *	1999-11-24	2001-03-20	Colgate-Palmolive, Inc.	Fabric cleaning composition containing zeolite

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4265777A (en) *	1980-04-17	1981-05-05	The Procter & Gamble Company	Detergent compositions containing an aluminosilicate detergency builder and an unsaturated fatty acid soap
CA2001927C (fr) *	1988-11-03	1999-12-21	Graham Thomas Brown	Aluminosilicates et detergents
JPH02178399A (ja) *	1988-12-29	1990-07-11	Lion Corp	粒状洗剤組成物
DE3920704A1 (de) *	1989-06-24	1991-01-03	Hoechst Ag	Builder fuer textilwaschmittel

1991
- 1991-09-18 GB GB919119958A patent/GB9119958D0/en active Pending
1992
- 1992-09-10 ES ES92308211T patent/ES2116320T3/es not_active Expired - Lifetime
- 1992-09-10 EP EP92308211A patent/EP0533392B1/fr not_active Expired - Lifetime
- 1992-09-10 DE DE69225449T patent/DE69225449T2/de not_active Expired - Lifetime
- 1992-09-11 JP JP4243314A patent/JPH05202384A/ja active Pending
- 1992-09-11 BR BR929203532A patent/BR9203532A/pt not_active IP Right Cessation
- 1992-09-14 CA CA002078155A patent/CA2078155C/fr not_active Expired - Lifetime
- 1992-09-18 ZA ZA927167A patent/ZA927167B/xx unknown

Also Published As

Publication number	Publication date
JPH05202384A (ja)	1993-08-10
BR9203532A (pt)	1993-04-13
GB9119958D0 (en)	1991-10-30
DE69225449T2 (de)	1998-09-03
EP0533392A3 (en)	1995-04-12
ZA927167B (en)	1994-03-18
DE69225449D1 (de)	1998-06-18
ES2116320T3 (es)	1998-07-16
CA2078155A1 (fr)	1993-03-19
EP0533392B1 (fr)	1998-05-13
EP0533392A2 (fr)	1993-03-24

Legal Events

Date	Code	Title	Description
1993-04-26	EEER	Examination request
2012-09-14	MKEX	Expiry

Publication	Publication Date	Title
CA2108695C (fr)	1998-08-04	Compositions detergentes granulaires a solubilite amelioree
CA1291390C (fr)	1991-10-29	Poudres detersives contenant du succinate et un polycarboxylate polymerique
JPH0948995A (ja)	1997-02-18	イミノジスクシネート類を含有する洗剤およびクリーナー
US5300250A (en)	1994-04-05	Granular laundry compositions having improved solubility
CA2078155C (fr)	1997-06-03	Compositions detergentes
EP0448297A1 (fr)	1991-09-25	Compositions détergentes
CA1314188C (fr)	1993-03-09	Compositions detergentes
EP0705325B1 (fr)	1999-05-06	Compositions detergentes granulaires contenant des adjuvants selectionnes dans des proportions optimales
EP0419036B1 (fr)	1998-12-09	Additif renforçateur pour détergents et système le contenant
CA2062032C (fr)	1998-06-09	Detergent
CA1316790C (fr)	1993-04-27	Compositions de blanchissage sans phosphore
EP0358472B1 (fr)	1994-12-14	Compositions détergentes
CA2038491C (fr)	1998-08-25	Detersifs
US5854198A (en)	1998-12-29	Particulate aluminosilicate-built detergent compositions comprising cogranules of zeolite map and alkali metal silicate
US6448218B2 (en)	2002-09-10	Modified aluminosilicate
EP0696313A1 (fr)	1996-02-14	Poudre detergente comportant un adjuvant silicatique, une combinaison tensioactive particuliere et une lipase
EP0774505B1 (fr)	2001-11-21	Compositions détergentes
FI80068C (fi)	1990-04-10	Granulaer tvaettmedelskomposition.
JPH04277599A (ja)	1992-10-02	洗剤組成物
JPH09501977A (ja)	1997-02-25	噴霧乾燥洗浄もしくは清浄組成物またはその成分