CA2085501C - Compositions thermoscellables a base de polyolefine - Google Patents

Compositions thermoscellables a base de polyolefine Download PDF

Info

Publication number: CA2085501C
Authority: CA; Canada
Prior art keywords: copolymer; propylene; weight; ethylene; content
Prior art date: 1992-02-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 2085501

Other languages

English (en)

Other versions

CA2085501A1 (fr

Inventor

Emanuele Burgin

Massimo Covezzi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Basell North America Inc

Original Assignee

Montell North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-02-18

Filing date

1993-02-17

Publication date

2000-08-15

1992-02-18 Priority claimed from ITMI920347A external-priority patent/IT1254468B/it

1992-10-08 Priority claimed from IT000347 external-priority patent/IT1258201B/it

1993-02-17 Application filed by Montell North America Inc filed Critical Montell North America Inc

1993-08-19 Publication of CA2085501A1 publication Critical patent/CA2085501A1/fr

2000-08-15 Application granted granted Critical

2000-08-15 Publication of CA2085501C publication Critical patent/CA2085501C/fr

2013-02-17 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 61
229920000098 polyolefin Polymers 0.000 title claims abstract description 15
229920001577 copolymer Polymers 0.000 claims abstract description 27
229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 21
239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 20
229920005606 polypropylene copolymer Polymers 0.000 claims abstract description 20
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 19
239000005977 Ethylene Substances 0.000 claims abstract description 18
230000000977 initiatory effect Effects 0.000 claims abstract description 10
229920001155 polypropylene Polymers 0.000 claims abstract description 9
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 25
239000003054 catalyst Substances 0.000 claims description 21
229920000642 polymer Polymers 0.000 claims description 17
238000006116 polymerization reaction Methods 0.000 claims description 17
238000000034 method Methods 0.000 claims description 16
239000011777 magnesium Substances 0.000 claims description 12
229910052749 magnesium Inorganic materials 0.000 claims description 10
239000000178 monomer Substances 0.000 claims description 7
238000002360 preparation method Methods 0.000 claims description 7
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 6
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 6
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 6
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
230000000707 stereoselective effect Effects 0.000 claims description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 43
-1 propylene, ethylene Chemical group 0.000 description 31
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 16
150000001875 compounds Chemical class 0.000 description 14
239000007789 gas Substances 0.000 description 14
239000012071 phase Substances 0.000 description 14
239000011949 solid catalyst Substances 0.000 description 10
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 10
229910003074 TiCl4 Inorganic materials 0.000 description 9
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
239000007787 solid Substances 0.000 description 7
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
238000013019 agitation Methods 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
238000002156 mixing Methods 0.000 description 5
UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
239000004743 Polypropylene Substances 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000002245 particle Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
239000010936 titanium Substances 0.000 description 4
150000003609 titanium compounds Chemical class 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
239000004698 Polyethylene Substances 0.000 description 3
238000002083 X-ray spectrum Methods 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
125000005843 halogen group Chemical group 0.000 description 3
229910001629 magnesium chloride Inorganic materials 0.000 description 3
239000008188 pellet Substances 0.000 description 3
229920000573 polyethylene Polymers 0.000 description 3
238000001228 spectrum Methods 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
238000004566 IR spectroscopy Methods 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
229910010062 TiCl3 Inorganic materials 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
125000000753 cycloalkyl group Chemical group 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000003921 oil Substances 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
150000003377 silicon compounds Chemical class 0.000 description 2
229920002545 silicone oil Polymers 0.000 description 2
239000002904 solvent Substances 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 2
229940099259 vaseline Drugs 0.000 description 2
OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
POWUJINVZSHIGY-UHFFFAOYSA-N 2,6-di(propan-2-yl)piperidine Chemical compound CC(C)C1CCCC(C(C)C)N1 POWUJINVZSHIGY-UHFFFAOYSA-N 0.000 description 1
PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
239000004708 Very-low-density polyethylene Substances 0.000 description 1
XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
239000012190 activator Substances 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
UXXXZMDJQLPQPH-UHFFFAOYSA-N bis(2-methylpropyl) carbonate Chemical compound CC(C)COC(=O)OCC(C)C UXXXZMDJQLPQPH-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
LMHUKLLZJMVJQZ-UHFFFAOYSA-N but-1-ene;prop-1-ene Chemical compound CC=C.CCC=C LMHUKLLZJMVJQZ-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000010411 cooking Methods 0.000 description 1
239000012967 coordination catalyst Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
238000007872 degassing Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
ZVMRWPHIZSSUKP-UHFFFAOYSA-N dicyclohexyl(dimethoxy)silane Chemical compound C1CCCCC1[Si](OC)(OC)C1CCCCC1 ZVMRWPHIZSSUKP-UHFFFAOYSA-N 0.000 description 1
ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
150000003021 phthalic acid derivatives Chemical class 0.000 description 1
239000002985 plastic film Substances 0.000 description 1
229920006255 plastic film Polymers 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
150000003900 succinic acid esters Chemical class 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
239000000725 suspension Substances 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229920001866 very low density polyethylene Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA 2085501 1992-02-18 1993-02-17 Compositions thermoscellables a base de polyolefine Expired - Fee Related CA2085501C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
ITMI920347A IT1254468B (it)	1992-02-18	1992-02-18	Composizioni poliolefiniche termosaldabili
ITMI92A000347		1992-02-18
IT000347 IT1258201B (it)	1992-10-08	1992-10-08	Contenitore verticale

Publications (2)

Publication Number	Publication Date
CA2085501A1 CA2085501A1 (fr)	1993-08-19
CA2085501C true CA2085501C (fr)	2000-08-15

Family

ID=29217442

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2085501 Expired - Fee Related CA2085501C (fr)	1992-02-18	1993-02-17	Compositions thermoscellables a base de polyolefine

Country Status (1)

Country	Link
CA (1)	CA2085501C (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US11485845B2 (en) *	2019-05-29	2022-11-01	Borealis Ag	C2C3 random copolymer

1993
- 1993-02-17 CA CA 2085501 patent/CA2085501C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2085501A1 (fr)	1993-08-19

Legal Events

Date	Code	Title	Description
1995-08-15	EEER	Examination request
2003-02-17	MKLA	Lapsed

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CA2145330C (fr)	2007-02-20	Composition a base de copolymere de propylene cristallise, possedant une basse temperature de soudure et une bonne adherence pour l'encre
CA2091299C (fr)	2001-06-12	Compositions de copolymeres statistiques de propene, renfermant une .alpha.-olefine, comonomere
EP0556815B1 (fr)	1998-09-09	Compositions de polyoléfines soudables à chaud
CA2115534C (fr)	2000-09-19	Pellicules polymeriques d'olefine
RU2134274C1 (ru)	1999-08-10	Полиолефиновая композиция, полиолефиновая смесь, способ получения смеси и изделие
CA2306034C (fr)	2008-09-23	Compositions de copolymeres de propylene cristallin ayant une capacite d'adherence et des proprietes optiques amelioree et une solubilite reduite
AU2002362692B2 (en)	2008-01-31	Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility
EP0483675A2 (fr)	1992-05-06	Polymère de propylène et produits laminés
AU2002362692A1 (en)	2003-07-03	Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility
EP0592852B1 (fr)	1997-08-20	Mélanges de bitume et compositions de polymère pour la modification des bitumes
CA2085501C (fr)	2000-08-15	Compositions thermoscellables a base de polyolefine
IL99564A (en)	1996-01-19	Preparations of crystalline propylene polymers with low sealing temperature
MXPA00003862A (en)	2001-12-13	Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility