CA2096164C - Molten zinc resistant alloy and its manufactured method - Google Patents
Molten zinc resistant alloy and its manufactured methodInfo
- Publication number
- CA2096164C CA2096164C CA002096164A CA2096164A CA2096164C CA 2096164 C CA2096164 C CA 2096164C CA 002096164 A CA002096164 A CA 002096164A CA 2096164 A CA2096164 A CA 2096164A CA 2096164 C CA2096164 C CA 2096164C
- Authority
- CA
- Canada
- Prior art keywords
- alloy
- molten zinc
- zinc
- boron
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 61
- 239000011701 zinc Substances 0.000 title claims abstract description 61
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 36
- 239000000956 alloy Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims description 30
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052796 boron Inorganic materials 0.000 claims abstract description 24
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 16
- 239000011733 molybdenum Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims description 38
- 239000011248 coating agent Substances 0.000 claims description 30
- 229910017262 Mo—B Inorganic materials 0.000 claims description 13
- 239000012535 impurity Substances 0.000 claims description 9
- 238000005474 detonation Methods 0.000 claims description 5
- 238000010289 gas flame spraying Methods 0.000 claims description 5
- 229910000765 intermetallic Inorganic materials 0.000 claims description 5
- 239000003566 sealing material Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008119 colloidal silica Substances 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims 2
- 238000000151 deposition Methods 0.000 claims 1
- 238000005507 spraying Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 28
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 9
- 239000010408 film Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000011195 cermet Substances 0.000 description 5
- 238000010283 detonation spraying Methods 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- 238000007747 plating Methods 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 150000001247 metal acetylides Chemical class 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910009043 WC-Co Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000007750 plasma spraying Methods 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/04—Alloys based on tungsten or molybdenum
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0034—Details related to elements immersed in bath
- C23C2/00342—Moving elements, e.g. pumps or mixers
- C23C2/00344—Means for moving substrates, e.g. immersed rollers or immersed bearings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/937—Sprayed metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12597—Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12597—Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
- Y10T428/12604—Film [e.g., glaze, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Coating By Spraying Or Casting (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4148211A JPH0791625B2 (ja) | 1992-05-14 | 1992-05-14 | 溶融亜鉛浴浸漬部材およびその製造方法 |
| JP4-148211 | 1992-05-14 | ||
| JP4250630A JP2593426B2 (ja) | 1992-08-26 | 1992-08-26 | 耐溶融亜鉛侵食性合金およびその製法と用途 |
| JP4-250630 | 1992-08-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2096164A1 CA2096164A1 (en) | 1993-11-15 |
| CA2096164C true CA2096164C (en) | 1998-08-18 |
Family
ID=26478500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002096164A Expired - Fee Related CA2096164C (en) | 1992-05-14 | 1993-05-13 | Molten zinc resistant alloy and its manufactured method |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5360675A (2) |
| EP (1) | EP0570219B1 (2) |
| CN (1) | CN1076403C (2) |
| CA (1) | CA2096164C (2) |
| DE (1) | DE69306302T2 (2) |
| ES (1) | ES2095569T3 (2) |
| RU (1) | RU2084554C1 (2) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR9701794A (pt) * | 1997-04-14 | 1998-11-24 | Claro Ind E Comercio De Aparel | Sistema ininterrupto de energia elétrica em samáforos com lâmpadas eletrônicas |
| JP2000096204A (ja) * | 1998-09-19 | 2000-04-04 | Nippon Steel Hardfacing Co Ltd | 溶融金属耐食性に優れた皮膜を有する溶融金属浴用部材の製造方法 |
| US6534196B2 (en) | 2001-02-26 | 2003-03-18 | Cincinnati Thermal Spray | Refractory metal coated articles for use in molten metal environments |
| US6818313B2 (en) * | 2002-07-24 | 2004-11-16 | University Of Dayton | Corrosion-inhibiting coating |
| FR2938554B1 (fr) * | 2008-11-19 | 2011-05-06 | Areva Nc | Procede de revetement d'un element de creuset metallique par un melange de verre et de ceramique |
| CN102418064B (zh) * | 2011-12-09 | 2013-07-17 | 北京科技大学 | 耐液锌腐蚀超音速喷涂TiAl-Nb复合涂层的制备方法 |
| AR092945A1 (es) * | 2012-10-10 | 2015-05-06 | Oerlikon Trading Ag Trübbach | Recubrimiento para usos a altas temperaturas con solicitacion tribologica |
| CN102925892B (zh) * | 2012-11-23 | 2014-07-23 | 北京科技大学 | 耐熔锌腐蚀Ti-Al-Nb涂层的电火花沉积方法 |
| BR112015023290A2 (pt) | 2013-03-15 | 2017-07-18 | Mesocoat Inc | pó de aspersão térmica, método de fabricação de um pó de aspersão térmica, revestimento por aspersão térmica formado de um pó de aspersão térmica, e, método de formação de um revestimento por aspersão térmica em um substrato |
| CN105483543B (zh) * | 2015-12-10 | 2017-12-08 | 湘潭大学 | 一种Fe‑B‑W耐锌液腐蚀的整体材料及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2725287A (en) * | 1952-11-26 | 1955-11-29 | Raytheon Mfg Co | Molybdenum solder powder |
| US3025182A (en) * | 1957-03-05 | 1962-03-13 | Kanthal Ab | Formation of corrosion-resistant metallic coatings by so-called flame-spraying techniques |
| US3091548A (en) * | 1959-12-15 | 1963-05-28 | Union Carbide Corp | High temperature coatings |
| US3690686A (en) * | 1969-08-11 | 1972-09-12 | Ramsey Corp | Piston with seal having high strength molybdenum alloy facing |
| US3749559A (en) * | 1969-10-20 | 1973-07-31 | Ramsey Corp | Piston rings with coating impregnated with antifriction agent |
| JPS56112447A (en) * | 1980-02-07 | 1981-09-04 | Mitsubishi Metal Corp | Fe alloy with superior molten zinc erosion resistance |
| US4645715A (en) * | 1981-09-23 | 1987-02-24 | Energy Conversion Devices, Inc. | Coating composition and method |
| US4822415A (en) * | 1985-11-22 | 1989-04-18 | Perkin-Elmer Corporation | Thermal spray iron alloy powder containing molybdenum, copper and boron |
| DE3789829T2 (de) * | 1986-06-06 | 1994-09-01 | Seiko Instr Inc | Seltene Erden-Eisenmagnet und Herstellungsverfahren. |
| JP2628317B2 (ja) * | 1987-10-21 | 1997-07-09 | 日鉄ハード株式会社 | 耐食性に優れた溶融亜鉛メッキ用浴中浸漬部材 |
| JPH01225761A (ja) * | 1988-03-04 | 1989-09-08 | Tocalo Co Ltd | 溶融金属めっき浴用部材 |
| JPH02236266A (ja) * | 1989-03-09 | 1990-09-19 | Tocalo Co Ltd | 溶融金属用部材およびその製造方法 |
| JP2553937B2 (ja) * | 1989-09-06 | 1996-11-13 | 日鉄ハード株式会社 | 耐食・耐摩耗性に優れた溶融金属用浸漬部材 |
-
1993
- 1993-05-11 US US08/059,857 patent/US5360675A/en not_active Expired - Fee Related
- 1993-05-13 DE DE69306302T patent/DE69306302T2/de not_active Expired - Fee Related
- 1993-05-13 CA CA002096164A patent/CA2096164C/en not_active Expired - Fee Related
- 1993-05-13 EP EP93303701A patent/EP0570219B1/en not_active Expired - Lifetime
- 1993-05-13 ES ES93303701T patent/ES2095569T3/es not_active Expired - Lifetime
- 1993-05-13 CN CN93107223A patent/CN1076403C/zh not_active Expired - Fee Related
- 1993-05-13 RU RU9393005301A patent/RU2084554C1/ru active
-
1994
- 1994-05-25 US US08/248,784 patent/US5456950A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5456950A (en) | 1995-10-10 |
| ES2095569T3 (es) | 1997-02-16 |
| EP0570219A2 (en) | 1993-11-18 |
| RU2084554C1 (ru) | 1997-07-20 |
| EP0570219B1 (en) | 1996-12-04 |
| CA2096164A1 (en) | 1993-11-15 |
| DE69306302D1 (de) | 1997-01-16 |
| EP0570219A3 (2) | 1994-02-23 |
| DE69306302T2 (de) | 1997-06-12 |
| CN1083122A (zh) | 1994-03-02 |
| US5360675A (en) | 1994-11-01 |
| CN1076403C (zh) | 2001-12-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |