CA2101514C - Extraction hydrometallurgique du cuivre, amelioree par des chlorures - Google Patents

Extraction hydrometallurgique du cuivre, amelioree par des chlorures Download PDF

Info

Publication number: CA2101514C
Authority: CA; Canada
Prior art keywords: copper; sulphate; solution; ions; raffinate
Prior art date: 1993-07-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 2101514

Other languages

English (en)

Other versions

CA2101514A1 (fr

Inventor

David L. Jones

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

CESL Ltd

Original Assignee

CESL Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-07-28

Filing date

1993-07-28

Publication date

2004-06-29

1993-07-28 Application filed by CESL Ltd filed Critical CESL Ltd

1993-07-28 Priority to CA 2101514 priority Critical patent/CA2101514C/fr

1995-01-29 Publication of CA2101514A1 publication Critical patent/CA2101514A1/fr

2004-06-29 Application granted granted Critical

2004-06-29 Publication of CA2101514C publication Critical patent/CA2101514C/fr

2013-07-28 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000010949 copper Substances 0.000 title claims abstract description 124
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 117
229910052802 copper Inorganic materials 0.000 title claims abstract description 117
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title claims abstract description 44
238000000605 extraction Methods 0.000 title claims abstract description 34
239000000243 solution Substances 0.000 claims abstract description 97
239000012141 concentrate Substances 0.000 claims abstract description 95
238000000034 method Methods 0.000 claims abstract description 74
230000008569 process Effects 0.000 claims abstract description 70
229910021653 sulphate ion Inorganic materials 0.000 claims abstract description 66
238000002386 leaching Methods 0.000 claims abstract description 62
238000000638 solvent extraction Methods 0.000 claims abstract description 53
238000000909 electrodialysis Methods 0.000 claims abstract description 49
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 40
-1 sulphate ions Chemical class 0.000 claims abstract description 40
235000011149 sulphuric acid Nutrition 0.000 claims abstract description 40
239000001117 sulphuric acid Substances 0.000 claims abstract description 40
QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims abstract description 33
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 30
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 27
150000001879 copper Chemical class 0.000 claims abstract description 21
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 13
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
239000001301 oxygen Substances 0.000 claims abstract description 13
230000002378 acidificating effect Effects 0.000 claims abstract description 11
239000003929 acidic solution Substances 0.000 claims abstract description 8
239000002184 metal Substances 0.000 claims abstract description 4
229910052751 metal Inorganic materials 0.000 claims abstract description 4
239000002253 acid Substances 0.000 claims description 82
230000003647 oxidation Effects 0.000 claims description 37
238000007254 oxidation reaction Methods 0.000 claims description 37
238000005363 electrowinning Methods 0.000 claims description 18
238000004064 recycling Methods 0.000 claims description 12
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 10
229910001431 copper ion Inorganic materials 0.000 claims description 9
230000000694 effects Effects 0.000 claims description 8
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 43
239000005864 Sulphur Substances 0.000 description 43
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 42
239000012528 membrane Substances 0.000 description 25
238000006243 chemical reaction Methods 0.000 description 23
229910052742 iron Inorganic materials 0.000 description 18
238000012360 testing method Methods 0.000 description 15
239000000706 filtrate Substances 0.000 description 14
239000007787 solid Substances 0.000 description 13
238000011084 recovery Methods 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
150000002500 ions Chemical class 0.000 description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
229910052708 sodium Inorganic materials 0.000 description 7
239000011734 sodium Substances 0.000 description 7
238000010977 unit operation Methods 0.000 description 7
125000002091 cationic group Chemical group 0.000 description 6
229910052595 hematite Inorganic materials 0.000 description 6
239000011019 hematite Substances 0.000 description 6
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 6
239000002002 slurry Substances 0.000 description 6
150000001450 anions Chemical class 0.000 description 5
230000008901 benefit Effects 0.000 description 5
150000001768 cations Chemical class 0.000 description 5
BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 4
229910000366 copper(II) sulfate Inorganic materials 0.000 description 4
239000003792 electrolyte Substances 0.000 description 4
238000001914 filtration Methods 0.000 description 4
239000012535 impurity Substances 0.000 description 4
238000006386 neutralization reaction Methods 0.000 description 4
239000002904 solvent Substances 0.000 description 4
125000000129 anionic group Chemical group 0.000 description 3
229910052951 chalcopyrite Inorganic materials 0.000 description 3
DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 3
239000012065 filter cake Substances 0.000 description 3
230000006872 improvement Effects 0.000 description 3
RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 2
UWGTVLYQSJNUFP-CAPFRKAQSA-N 4-dodecyl-2-[(E)-hydroxyiminomethyl]phenol Chemical compound [H]\C(=N/O)C1=CC(CCCCCCCCCCCC)=CC=C1O UWGTVLYQSJNUFP-CAPFRKAQSA-N 0.000 description 2
229910017489 Cu I Inorganic materials 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
238000003556 assay Methods 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
229910052948 bornite Inorganic materials 0.000 description 2
238000010586 diagram Methods 0.000 description 2
229910052971 enargite Inorganic materials 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
239000010931 gold Substances 0.000 description 2
239000003350 kerosene Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
230000003190 augmentative effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229910052947 chalcocite Inorganic materials 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
BUGICWZUDIWQRQ-UHFFFAOYSA-N copper iron sulfane Chemical compound S.[Fe].[Cu] BUGICWZUDIWQRQ-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012527 feed solution Substances 0.000 description 1
238000005188 flotation Methods 0.000 description 1
239000003292 glue Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052935 jarosite Inorganic materials 0.000 description 1
239000012633 leachable Substances 0.000 description 1
239000004571 lime Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000005065 mining Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000013110 organic ligand Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000009877 rendering Methods 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
238000012216 screening Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000011343 solid material Substances 0.000 description 1
229910052969 tetrahedrite Inorganic materials 0.000 description 1
230000008719 thickening Effects 0.000 description 1
238000012546 transfer Methods 0.000 description 1
238000013022 venting Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
239000011686 zinc sulphate Substances 0.000 description 1
235000009529 zinc sulphate Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0069—Leaching or slurrying with acids or salts thereof containing halogen
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Manufacture And Refinement Of Metals (AREA)

CA 2101514 1993-07-28 1993-07-28 Extraction hydrometallurgique du cuivre, amelioree par des chlorures Expired - Fee Related CA2101514C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA 2101514 CA2101514C (fr)	1993-07-28	1993-07-28	Extraction hydrometallurgique du cuivre, amelioree par des chlorures

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA 2101514 CA2101514C (fr)	1993-07-28	1993-07-28	Extraction hydrometallurgique du cuivre, amelioree par des chlorures

Publications (2)

Publication Number	Publication Date
CA2101514A1 CA2101514A1 (fr)	1995-01-29
CA2101514C true CA2101514C (fr)	2004-06-29

Family

ID=4152003

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2101514 Expired - Fee Related CA2101514C (fr)	1993-07-28	1993-07-28	Extraction hydrometallurgique du cuivre, amelioree par des chlorures

Country Status (1)

Country	Link
CA (1)	CA2101514C (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AUPP484498A0 (en)	1998-07-24	1998-08-20	Aberfoyle Resources Limited	Processing minerals
JP4468999B2 (ja)	2008-03-27	2010-05-26	日鉱金属株式会社	鉱物からの金属の回収方法
JP4717908B2 (ja)	2008-08-11	2011-07-06	Ｊｘ日鉱日石金属株式会社	銅を含有する塩化物浴からの銅の回収方法
CN110563021B (zh) *	2019-10-16	2023-04-07	大冶有色金属有限责任公司	一种无害化处理回收碱式氯化铜的方法及装置

1993
- 1993-07-28 CA CA 2101514 patent/CA2101514C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2101514A1 (fr)	1995-01-29

Legal Events

Date	Code	Title	Description
1999-09-01	EEER	Examination request
2010-07-28	MKLA	Lapsed

Publication	Publication Date	Title
US5431788A (en)	1995-07-11	Chloride assisted hydrometallurgical copper extraction
US7666371B2 (en)	2010-02-23	Method for recovering metal values from metal-containing materials using high temperature pressure leaching
EP0524782B1 (fr)	1997-10-29	Traitement des concentrés de sulfure de cuivre
US5919674A (en)	1999-07-06	Copper recovery
EP0924307B1 (fr)	2003-01-29	Extraction liquide-liquide du cobalt et du nickel d'une solution contenant du magnésium
US5487819A (en)	1996-01-30	Production of metals from minerals
AU700850B2 (en)	1999-01-14	Atmospheric mineral leaching process
US4004991A (en)	1977-01-25	Two-stage pressure leaching process for zinc and iron bearing mineral sulphides
US3776826A (en)	1973-12-04	Electrolytic recovery of metal values from ore concentrates
EP0177290B1 (fr)	1992-03-04	Procédé de récupération de l'or à partir de concentrés réfractaires sulfurés contenant de l'or et du fer
US4023964A (en)	1977-05-17	Method of obtaining copper from copper-bearing ores
EP0177292B1 (fr)	1991-05-02	Procédé pour récupérer l'argent à partir d'un résidu pratiquement exempt de soufre élémentaire
AU2001277182A1 (en)	2002-05-02	Method for Recovering Copper from Sulfide Ore Materials Using High Temperature Pressure Leaching, Solvent Extraction and Electrowinning
PL178355B1 (pl)	2000-04-28	Sposób hydrometalurgicznego ciągłego wytwarzania osadów zawierających miedź i/lub cynk do otrzymywania tych metali
US4594132A (en)	1986-06-10	Chloride hydrometallurgical process for production of copper
US3891522A (en)	1975-06-24	Hydrometallurgical process for treating copper-iron sulphides
US3816105A (en)	1974-06-11	Hydrometallurgical process for extraction of copper and sulphur from copper iron sulphides
AU3772497A (en)	1998-03-06	Method for leaching zinc concentrate in atmospheric conditions
DE60106269T2 (de)	2006-02-16	Behandlung von elementarschwefel enthaltenden materialien durch druck-laugung bei hoher temperatur zur erzeugung von schwefelsäure und zur metallgewinnung
US4157912A (en)	1979-06-12	Process for recovery of copper and zinc from complex sulphides
US3901776A (en)	1975-08-26	Process for the recovery of copper from its sulfide ores
US4443253A (en)	1984-04-17	Recovery of zinc from zinc containing sulphidic materials
CA2101514C (fr)	2004-06-29	Extraction hydrometallurgique du cuivre, amelioree par des chlorures
CA1110076A (fr)	1981-10-06	Lessivage de metaux a partir de concentres a l'aide de bioxyde d'azote dans des acides
EP1507878B1 (fr)	2006-06-21	Extraction hydrometallurgique de metaux effectuee au moyen de chlorure