CA2134387A1 - Composition de catalyseur et procede servant a la preparation de polymeres - Google Patents

Composition de catalyseur et procede servant a la preparation de polymeres

Info

Publication number: CA2134387A1
Authority: CA; Canada
Prior art keywords: composition; anion; group; group viii; ethylenically unsaturated
Prior art date: 1993-10-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002134387A

Other languages

English (en)

Inventor

Arleen M. Bradford

Andre Buys

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Internationale Research Maatschappij BV

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-10-28

Filing date

1994-10-26

Publication date

1995-04-29

1994-10-26 Application filed by Individual filed Critical Individual

1995-04-29 Publication of CA2134387A1 publication Critical patent/CA2134387A1/fr

Status Abandoned legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 41
239000000203 mixture Substances 0.000 title claims abstract description 35
238000000034 method Methods 0.000 title claims abstract description 21
238000002360 preparation method Methods 0.000 title claims abstract description 12
229920000642 polymer Polymers 0.000 title abstract description 6
229910052751 metal Inorganic materials 0.000 claims abstract description 30
239000002184 metal Substances 0.000 claims abstract description 30
150000001450 anions Chemical class 0.000 claims abstract description 29
229920001577 copolymer Polymers 0.000 claims abstract description 29
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 23
229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 22
150000001875 compounds Chemical class 0.000 claims abstract description 22
239000007800 oxidant agent Substances 0.000 claims abstract description 14
230000001590 oxidative effect Effects 0.000 claims abstract description 12
230000000737 periodic effect Effects 0.000 claims abstract 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 15
125000004429 atom Chemical group 0.000 claims description 15
239000003446 ligand Substances 0.000 claims description 15
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 10
239000002253 acid Substances 0.000 claims description 10
239000007789 gas Substances 0.000 claims description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 7
239000012876 carrier material Substances 0.000 claims description 7
229910052799 carbon Inorganic materials 0.000 claims description 6
229910052698 phosphorus Inorganic materials 0.000 claims description 6
PZTGRDMCBZUJDL-UHFFFAOYSA-N 1,2-naphthoquinone-4-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC(=O)C(=O)C2=C1 PZTGRDMCBZUJDL-UHFFFAOYSA-N 0.000 claims description 5
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
125000001183 hydrocarbyl group Chemical group 0.000 claims description 5
239000011574 phosphorus Substances 0.000 claims description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
239000005864 Sulphur Substances 0.000 claims description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 4
230000000536 complexating effect Effects 0.000 claims description 3
125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
MMNWSHJJPDXKCH-UHFFFAOYSA-N 9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 MMNWSHJJPDXKCH-UHFFFAOYSA-N 0.000 claims description 2
125000003545 alkoxy group Chemical group 0.000 claims description 2
229910052787 antimony Inorganic materials 0.000 claims description 2
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
229910052785 arsenic Inorganic materials 0.000 claims description 2
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
230000021615 conjugation Effects 0.000 claims description 2
238000007334 copolymerization reaction Methods 0.000 claims description 2
MSSUFHMGCXOVBZ-UHFFFAOYSA-N anthraquinone-2,6-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 MSSUFHMGCXOVBZ-UHFFFAOYSA-N 0.000 claims 1
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
125000004437 phosphorous atom Chemical group 0.000 claims 1
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 14
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 8
229910017052 cobalt Inorganic materials 0.000 description 8
239000010941 cobalt Substances 0.000 description 8
-1 hydroxy-substituted nitrobenzene Chemical class 0.000 description 8
239000012071 phase Substances 0.000 description 8
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
239000007788 liquid Substances 0.000 description 7
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 7
FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
239000007791 liquid phase Substances 0.000 description 5
229910052763 palladium Inorganic materials 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
125000000129 anionic group Chemical group 0.000 description 4
239000003085 diluting agent Substances 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
239000000178 monomer Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
229910052759 nickel Inorganic materials 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000000463 material Substances 0.000 description 2
150000002828 nitro derivatives Chemical class 0.000 description 2
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
239000001294 propane Substances 0.000 description 2
238000000746 purification Methods 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
229910052703 rhodium Inorganic materials 0.000 description 2
239000010948 rhodium Substances 0.000 description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
WOAHJDHKFWSLKE-UHFFFAOYSA-N 1,2-benzoquinone Chemical compound O=C1C=CC=CC1=O WOAHJDHKFWSLKE-UHFFFAOYSA-N 0.000 description 1
DCXDVGKTBDNYRX-UHFFFAOYSA-N 1,2-bis(ethylsulfanyl)ethane Chemical compound CCSCCSCC DCXDVGKTBDNYRX-UHFFFAOYSA-N 0.000 description 1
150000005184 1,3-dinitrobenzenes Chemical group 0.000 description 1
229940005561 1,4-benzoquinone Drugs 0.000 description 1
JXMYUMNAEKRMIP-UHFFFAOYSA-N 1-nitro-4-propan-2-ylbenzene Chemical group CC(C)C1=CC=C([N+]([O-])=O)C=C1 JXMYUMNAEKRMIP-UHFFFAOYSA-N 0.000 description 1
JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical group CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
125000004204 2-methoxyphenyl group Chemical group [H]C1=C([H])C(*)=C(OC([H])([H])[H])C([H])=C1[H] 0.000 description 1
SXXPTCXIFIOPQF-UHFFFAOYSA-N 3-bis(2-methoxyphenyl)phosphanylpropyl-bis(2-methoxyphenyl)phosphane Chemical compound COC1=CC=CC=C1P(C=1C(=CC=CC=1)OC)CCCP(C=1C(=CC=CC=1)OC)C1=CC=CC=C1OC SXXPTCXIFIOPQF-UHFFFAOYSA-N 0.000 description 1
BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical group C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
229940076442 9,10-anthraquinone Drugs 0.000 description 1
ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
229930040373 Paraformaldehyde Natural products 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
230000018199 S phase Effects 0.000 description 1
229920005654 Sephadex Polymers 0.000 description 1
DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
229920005603 alternating copolymer Polymers 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
230000002844 continuous effect Effects 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
239000008121 dextrose Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000001914 filtration Methods 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229920005684 linear copolymer Polymers 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
125000006501 nitrophenyl group Chemical group 0.000 description 1
125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
125000004043 oxo group Chemical group O=* 0.000 description 1
239000005022 packaging material Substances 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
FVZVCSNXTFCBQU-UHFFFAOYSA-N phosphanyl Chemical group [PH2] FVZVCSNXTFCBQU-UHFFFAOYSA-N 0.000 description 1
150000003009 phosphonic acids Chemical class 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
238000002459 porosimetry Methods 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000011027 product recovery Methods 0.000 description 1
150000004053 quinones Chemical class 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Polyethers (AREA)

CA002134387A 1993-10-28 1994-10-26 Composition de catalyseur et procede servant a la preparation de polymeres Abandoned CA2134387A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP93203031		1993-10-28
EP93203031.5		1993-10-28

Publications (1)

Publication Number	Publication Date
CA2134387A1 true CA2134387A1 (fr)	1995-04-29

Family

ID=8214149

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002134387A Abandoned CA2134387A1 (fr)	1993-10-28	1994-10-26	Composition de catalyseur et procede servant a la preparation de polymeres

Country Status (6)

Country	Link
JP (1)	JPH07179598A (fr)
CN (1)	CN1107483A (fr)
AU (1)	AU673107B2 (fr)
CA (1)	CA2134387A1 (fr)
DE (1)	DE69415919T2 (fr)
ZA (1)	ZA948414B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10313887A1 (de) *	2003-03-27	2004-10-28	Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.	Verfahren zum selektiven Gewinnen von Gold aus goldhaltigen Materialien

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IN168306B (fr) *	1986-03-05	1991-03-09	Shell Int Research
US4806630A (en) *	1986-12-01	1989-02-21	Shell Oil Company	Catalytic polymerization of carbon monoxide and olefin, with organo nitro or organo nitrite compound additive
US5066778A (en) *	1989-03-02	1991-11-19	Shell Oil Company	Carbon monoxide/cyclopenten copolymer and preparation with aromatic dinitro compound

1994
- 1994-10-26 CA CA002134387A patent/CA2134387A1/fr not_active Abandoned
- 1994-10-26 ZA ZA948414A patent/ZA948414B/xx unknown
- 1994-10-26 AU AU77495/94A patent/AU673107B2/en not_active Expired - Fee Related
- 1994-10-26 JP JP6262916A patent/JPH07179598A/ja active Pending
- 1994-10-27 CN CN94119345A patent/CN1107483A/zh active Pending
- 1994-10-27 DE DE69415919T patent/DE69415919T2/de not_active Expired - Fee Related

Also Published As

Publication number	Publication date
AU673107B2 (en)	1996-10-24
JPH07179598A (ja)	1995-07-18
ZA948414B (en)	1995-06-29
AU7749594A (en)	1995-05-18
DE69415919D1 (de)	1999-02-25
DE69415919T2 (de)	1999-06-17
CN1107483A (zh)	1995-08-30

Legal Events

Date	Code	Title	Description
2001-10-26	FZDE	Dead

Publication	Publication Date	Title
CA1333619C (fr)	1994-12-20	Compositions de catalyseurs
AU646544B2 (en)	1994-02-24	Polymer preparation
AU612462B2 (en)	1991-07-11	Polyketone polymer preparation
EP0650761B1 (fr)	1999-01-13	Composition de catalyseur et procédé pour la préparation de polymères
AU646585B2 (en)	1994-02-24	Catalyst compositions suitable for the preparation of polymers of carbon monoxide and alpha-olefins
CA2003917A1 (fr)	1990-05-28	Polymeres de monoxyde de carbone avec une ou plusieurs alpha-olefines
CA1338582C (fr)	1996-09-03	Methode de preparation de polymeres
AU646545B2 (en)	1994-02-24	Catalyst compositions
CA2069992A1 (fr)	1992-12-01	Compositions a proprietes de catalyseur et procede qui se prete a l'obtention de polymeres d'oxyde de carbone et de composes a insaturation olefinique
JPH09241375A (ja)	1997-09-16	コポリマーの製造方法
JPH04227928A (ja)	1992-08-18	一酸化炭素とオレフィン性不飽和化合物との重合体の製造方法
CA2014627A1 (fr)	1990-10-19	Preparation de copolymeres de monoxyde de carbone
US5352765A (en)	1994-10-04	Preparation of copolymers of carbon monoxide and olefinically unsaturated compounds
CA2063481A1 (fr)	1992-09-22	Compositions de catalyseur
EP0443687A2 (fr)	1991-08-28	Procédé de préparation de polymères à base d'oxyde de carbone et d'un ou de plusieurs composés oléfiniquement non-saturés
EP0490452B1 (fr)	1996-09-11	Compositions de catalyseur et procédé de préparation de polymères
AU673107B2 (en)	1996-10-24	Catalyst composition and process for the preparation of polymers
CA2136636C (fr)	1999-05-11	Procede de preparation de co-polymeres de monoxyde de carbone et de composes a groupement ethylene insatures
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