CA2146359C - Sol/engrais synthetiques a liberation lente - Google Patents

Sol/engrais synthetiques a liberation lente Download PDF

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Publication number: CA2146359C
Authority: CA; Canada
Prior art keywords: parts; potassium; ammonium; solution; fertilizer
Prior art date: 1992-10-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002146359A

Other languages

English (en)

Other versions

CA2146359A1 (fr

Inventor

Douglas W. Ming

Donald L. Henninger

Earl R. Allen

D. C. Golden

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

LUNDEEN DANIEL N

Original Assignee

LUNDEEN DANIEL N

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-10-16

Filing date

1993-10-15

Publication date

2002-01-15

1993-10-15 Application filed by LUNDEEN DANIEL N filed Critical LUNDEEN DANIEL N

1994-04-28 Publication of CA2146359A1 publication Critical patent/CA2146359A1/fr

2002-01-15 Application granted granted Critical

2002-01-15 Publication of CA2146359C publication Critical patent/CA2146359C/fr

2013-10-15 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000002689 soil Substances 0.000 title claims abstract description 46
239000003337 fertilizer Substances 0.000 title claims abstract description 41
229910052586 apatite Inorganic materials 0.000 claims abstract description 49
VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims abstract description 49
239000010457 zeolite Substances 0.000 claims abstract description 46
229910052700 potassium Inorganic materials 0.000 claims abstract description 35
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 34
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 34
239000011591 potassium Substances 0.000 claims abstract description 34
239000011777 magnesium Substances 0.000 claims abstract description 32
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 30
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 21
229910052749 magnesium Inorganic materials 0.000 claims abstract description 21
-1 nitrogen cations Chemical class 0.000 claims abstract description 16
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 15
239000011593 sulfur Substances 0.000 claims abstract description 15
229910052717 sulfur Inorganic materials 0.000 claims abstract description 15
229920006395 saturated elastomer Polymers 0.000 claims abstract description 10
239000011159 matrix material Substances 0.000 claims abstract description 9
239000006174 pH buffer Substances 0.000 claims abstract description 9
239000000243 solution Substances 0.000 claims description 55
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 51
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 35
235000007686 potassium Nutrition 0.000 claims description 33
239000010949 copper Substances 0.000 claims description 32
125000002091 cationic group Chemical group 0.000 claims description 31
239000000203 mixture Substances 0.000 claims description 31
239000011701 zinc Substances 0.000 claims description 31
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
239000011575 calcium Substances 0.000 claims description 27
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 25
229910052791 calcium Inorganic materials 0.000 claims description 25
239000002244 precipitate Substances 0.000 claims description 25
XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical group [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 24
229910052588 hydroxylapatite Inorganic materials 0.000 claims description 23
239000000460 chlorine Substances 0.000 claims description 21
150000004677 hydrates Chemical class 0.000 claims description 20
238000000034 method Methods 0.000 claims description 20
239000011572 manganese Substances 0.000 claims description 19
229910019142 PO4 Inorganic materials 0.000 claims description 18
229910052802 copper Inorganic materials 0.000 claims description 18
229910052742 iron Inorganic materials 0.000 claims description 18
229910001868 water Inorganic materials 0.000 claims description 18
229910052725 zinc Inorganic materials 0.000 claims description 18
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 17
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
239000010452 phosphate Substances 0.000 claims description 16
239000011734 sodium Substances 0.000 claims description 14
229910052796 boron Inorganic materials 0.000 claims description 13
229910052731 fluorine Inorganic materials 0.000 claims description 13
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
239000003795 chemical substances by application Substances 0.000 claims description 12
239000011737 fluorine Substances 0.000 claims description 12
229910052750 molybdenum Inorganic materials 0.000 claims description 12
229910052708 sodium Inorganic materials 0.000 claims description 12
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 11
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 11
239000011733 molybdenum Substances 0.000 claims description 11
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 10
JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical group O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 10
150000001450 anions Chemical group 0.000 claims description 10
229910001603 clinoptilolite Inorganic materials 0.000 claims description 10
238000002156 mixing Methods 0.000 claims description 10
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 10
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 9
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
229910052801 chlorine Inorganic materials 0.000 claims description 8
239000003501 hydroponics Substances 0.000 claims description 8
229940043430 calcium compound Drugs 0.000 claims description 7
150000001674 calcium compounds Chemical class 0.000 claims description 7
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 6
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
125000000129 anionic group Chemical group 0.000 claims description 6
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 6
229910052909 inorganic silicate Inorganic materials 0.000 claims description 6
229910052748 manganese Inorganic materials 0.000 claims description 6
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 6
ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
229910002651 NO3 Inorganic materials 0.000 claims description 5
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
238000006243 chemical reaction Methods 0.000 claims description 5
150000008040 ionic compounds Chemical class 0.000 claims description 5
239000000047 product Substances 0.000 claims description 5
229910052710 silicon Inorganic materials 0.000 claims description 5
239000010703 silicon Substances 0.000 claims description 5
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical group [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
239000004115 Sodium Silicate Substances 0.000 claims description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
239000001099 ammonium carbonate Substances 0.000 claims description 4
150000001805 chlorine compounds Chemical class 0.000 claims description 4
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 4
VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 4
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
235000002639 sodium chloride Nutrition 0.000 claims description 4
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
229910052911 sodium silicate Inorganic materials 0.000 claims description 4
239000010455 vermiculite Substances 0.000 claims description 4
229910052902 vermiculite Inorganic materials 0.000 claims description 4
235000019354 vermiculite Nutrition 0.000 claims description 4
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
JEWHCPOELGJVCB-UHFFFAOYSA-N aluminum;calcium;oxido-[oxido(oxo)silyl]oxy-oxosilane;potassium;sodium;tridecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.[Na].[Al].[K].[Ca].[O-][Si](=O)O[Si]([O-])=O JEWHCPOELGJVCB-UHFFFAOYSA-N 0.000 claims description 3
235000019270 ammonium chloride Nutrition 0.000 claims description 3
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
235000011130 ammonium sulphate Nutrition 0.000 claims description 3
235000010338 boric acid Nutrition 0.000 claims description 3
229960002645 boric acid Drugs 0.000 claims description 3
UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims description 3
229910052676 chabazite Inorganic materials 0.000 claims description 3
TVZISJTYELEYPI-UHFFFAOYSA-N hypodiphosphoric acid Chemical compound OP(O)(=O)P(O)(O)=O TVZISJTYELEYPI-UHFFFAOYSA-N 0.000 claims description 3
229910001743 phillipsite Inorganic materials 0.000 claims description 3
229910052615 phyllosilicate Inorganic materials 0.000 claims description 3
239000001103 potassium chloride Substances 0.000 claims description 3
235000011164 potassium chloride Nutrition 0.000 claims description 3
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
235000011151 potassium sulphates Nutrition 0.000 claims description 3
229910021647 smectite Inorganic materials 0.000 claims description 3
229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
ONBHUPNUUMQQMW-UHFFFAOYSA-K Cl[Cu](Cl)Cl Chemical compound Cl[Cu](Cl)Cl ONBHUPNUUMQQMW-UHFFFAOYSA-K 0.000 claims description 2
239000005749 Copper compound Substances 0.000 claims description 2
229910021592 Copper(II) chloride Inorganic materials 0.000 claims description 2
229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 2
MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 claims description 2
229910021380 Manganese Chloride Inorganic materials 0.000 claims description 2
GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 claims description 2
NBRRWXAMGXVNRL-UHFFFAOYSA-N [Si](O)([O-])([O-])O[Si]([O-])([O-])[O-].[K+].[K+].[K+].[K+].[K+] Chemical compound [Si](O)([O-])([O-])O[Si]([O-])([O-])[O-].[K+].[K+].[K+].[K+].[K+] NBRRWXAMGXVNRL-UHFFFAOYSA-N 0.000 claims description 2
235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
235000012501 ammonium carbonate Nutrition 0.000 claims description 2
LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims description 2
229910021538 borax Inorganic materials 0.000 claims description 2
YALMXYPQBUJUME-UHFFFAOYSA-L calcium chlorate Chemical compound [Ca+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O YALMXYPQBUJUME-UHFFFAOYSA-L 0.000 claims description 2
239000001110 calcium chloride Substances 0.000 claims description 2
229910001628 calcium chloride Inorganic materials 0.000 claims description 2
150000001880 copper compounds Chemical class 0.000 claims description 2
XNEQAVYOCNWYNZ-UHFFFAOYSA-L copper;dinitrite Chemical compound [Cu+2].[O-]N=O.[O-]N=O XNEQAVYOCNWYNZ-UHFFFAOYSA-L 0.000 claims description 2
AUTNMGCKBXKHNV-UHFFFAOYSA-P diazanium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [NH4+].[NH4+].O1B([O-])OB2OB([O-])OB1O2 AUTNMGCKBXKHNV-UHFFFAOYSA-P 0.000 claims description 2
UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 2
229960002089 ferrous chloride Drugs 0.000 claims description 2
239000011790 ferrous sulphate Substances 0.000 claims description 2
235000003891 ferrous sulphate Nutrition 0.000 claims description 2
UFFNHUYHCDHKHK-UHFFFAOYSA-N hexapotassium trioxido(trioxidosilyloxy)silane Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] UFFNHUYHCDHKHK-UHFFFAOYSA-N 0.000 claims description 2
PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 claims description 2
150000002506 iron compounds Chemical class 0.000 claims description 2
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 2
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 claims description 2
JDBBTVFYDZWUFI-UHFFFAOYSA-K iron(3+) trinitrite Chemical compound [Fe+3].[O-]N=O.[O-]N=O.[O-]N=O JDBBTVFYDZWUFI-UHFFFAOYSA-K 0.000 claims description 2
YHGPYBQVSJBGHH-UHFFFAOYSA-H iron(3+);trisulfate;pentahydrate Chemical compound O.O.O.O.O.[Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YHGPYBQVSJBGHH-UHFFFAOYSA-H 0.000 claims description 2
229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
150000002681 magnesium compounds Chemical class 0.000 claims description 2
NNNSKJSUQWKSAM-UHFFFAOYSA-L magnesium;dichlorate Chemical compound [Mg+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O NNNSKJSUQWKSAM-UHFFFAOYSA-L 0.000 claims description 2
239000011565 manganese chloride Substances 0.000 claims description 2
235000002867 manganese chloride Nutrition 0.000 claims description 2
150000002697 manganese compounds Chemical class 0.000 claims description 2
WPXWANCYVRRWEX-UHFFFAOYSA-L manganese(2+);dinitrite Chemical compound [Mn+2].[O-]N=O.[O-]N=O WPXWANCYVRRWEX-UHFFFAOYSA-L 0.000 claims description 2
SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 2
229910000357 manganese(II) sulfate Inorganic materials 0.000 claims description 2
229910052680 mordenite Inorganic materials 0.000 claims description 2
RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 claims description 2
239000011736 potassium bicarbonate Substances 0.000 claims description 2
235000015497 potassium bicarbonate Nutrition 0.000 claims description 2
229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 2
229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
235000011181 potassium carbonates Nutrition 0.000 claims description 2
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 2
229910052913 potassium silicate Inorganic materials 0.000 claims description 2
235000019353 potassium silicate Nutrition 0.000 claims description 2
JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 claims description 2
150000003377 silicon compounds Chemical class 0.000 claims description 2
229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
235000017550 sodium carbonate Nutrition 0.000 claims description 2
239000011780 sodium chloride Substances 0.000 claims description 2
NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims description 2
235000019795 sodium metasilicate Nutrition 0.000 claims description 2
229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
235000011152 sodium sulphate Nutrition 0.000 claims description 2
239000004328 sodium tetraborate Substances 0.000 claims description 2
235000010339 sodium tetraborate Nutrition 0.000 claims description 2
POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 claims description 2
239000011592 zinc chloride Substances 0.000 claims description 2
235000005074 zinc chloride Nutrition 0.000 claims description 2
150000003752 zinc compounds Chemical class 0.000 claims description 2
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
229960001763 zinc sulfate Drugs 0.000 claims description 2
HHIMNFJHTNVXBJ-UHFFFAOYSA-L zinc;dinitrite Chemical compound [Zn+2].[O-]N=O.[O-]N=O HHIMNFJHTNVXBJ-UHFFFAOYSA-L 0.000 claims description 2
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 4
241000196324 Embryophyta Species 0.000 claims 4
229910002919 BO3 Inorganic materials 0.000 claims 3
229910015667 MoO4 Inorganic materials 0.000 claims 3
229910006130 SO4 Inorganic materials 0.000 claims 3
150000001768 cations Chemical class 0.000 claims 3
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 3
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims 2
BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 claims 2
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 claims 2
GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 claims 1
OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 claims 1
PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 claims 1
UAILCXANVPDDLP-UHFFFAOYSA-N OB(O)OO.N.N.N Chemical compound OB(O)OO.N.N.N UAILCXANVPDDLP-UHFFFAOYSA-N 0.000 claims 1
VFTOLAKHPLTCIF-UHFFFAOYSA-N aminoazanium;dihydrogen phosphate Chemical compound NN.OP(O)(O)=O VFTOLAKHPLTCIF-UHFFFAOYSA-N 0.000 claims 1
KHPLPBHMTCTCHA-UHFFFAOYSA-N ammonium chlorate Chemical compound N.OCl(=O)=O KHPLPBHMTCTCHA-UHFFFAOYSA-N 0.000 claims 1
239000000872 buffer Substances 0.000 claims 1
AAJBNRZDTJPMTJ-UHFFFAOYSA-L magnesium;dinitrite Chemical compound [Mg+2].[O-]N=O.[O-]N=O AAJBNRZDTJPMTJ-UHFFFAOYSA-L 0.000 claims 1
239000012286 potassium permanganate Substances 0.000 claims 1
235000015097 nutrients Nutrition 0.000 abstract description 38
239000011785 micronutrient Substances 0.000 abstract description 12
235000013369 micronutrients Nutrition 0.000 abstract description 12
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 abstract description 12
239000001506 calcium phosphate Substances 0.000 abstract description 11
229910000389 calcium phosphate Inorganic materials 0.000 abstract description 11
235000011010 calcium phosphates Nutrition 0.000 abstract description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 5
230000008635 plant growth Effects 0.000 abstract description 5
229910052757 nitrogen Inorganic materials 0.000 abstract description 3
238000005341 cation exchange Methods 0.000 abstract 1
239000011550 stock solution Substances 0.000 description 18
230000009418 agronomic effect Effects 0.000 description 12
150000001875 compounds Chemical class 0.000 description 12
239000008367 deionised water Substances 0.000 description 12
229910021641 deionized water Inorganic materials 0.000 description 12
239000002609 medium Substances 0.000 description 12
235000001055 magnesium Nutrition 0.000 description 11
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 10
150000002500 ions Chemical class 0.000 description 10
239000013078 crystal Substances 0.000 description 8
229910052500 inorganic mineral Inorganic materials 0.000 description 8
235000010755 mineral Nutrition 0.000 description 8
239000011707 mineral Substances 0.000 description 8
239000012736 aqueous medium Substances 0.000 description 7
235000021317 phosphate Nutrition 0.000 description 7
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
238000004090 dissolution Methods 0.000 description 5
238000001035 drying Methods 0.000 description 5
238000003898 horticulture Methods 0.000 description 5
239000011574 phosphorus Substances 0.000 description 5
229910052698 phosphorus Inorganic materials 0.000 description 5
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
229910001424 calcium ion Inorganic materials 0.000 description 4
230000007935 neutral effect Effects 0.000 description 4
239000006228 supernatant Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
241001465754 Metazoa Species 0.000 description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
229910052793 cadmium Inorganic materials 0.000 description 3
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000007788 liquid Substances 0.000 description 3
230000014759 maintenance of location Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000002245 particle Substances 0.000 description 3
241000894007 species Species 0.000 description 3
238000001228 spectrum Methods 0.000 description 3
239000013589 supplement Substances 0.000 description 3
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
230000004720 fertilization Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
230000012010 growth Effects 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
150000002484 inorganic compounds Chemical class 0.000 description 2
239000012500 ion exchange media Substances 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
238000009304 pastoral farming Methods 0.000 description 2
239000002367 phosphate rock Substances 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000758 substrate Substances 0.000 description 2
235000001508 sulfur Nutrition 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
231100000701 toxic element Toxicity 0.000 description 2
239000003053 toxin Substances 0.000 description 2
231100000765 toxin Toxicity 0.000 description 2
108700012359 toxins Proteins 0.000 description 2
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
ZHJGWYRLJUCMRT-UHFFFAOYSA-N 5-[6-[(4-methylpiperazin-1-yl)methyl]benzimidazol-1-yl]-3-[1-[2-(trifluoromethyl)phenyl]ethoxy]thiophene-2-carboxamide Chemical compound C=1C=CC=C(C(F)(F)F)C=1C(C)OC(=C(S1)C(N)=O)C=C1N(C1=C2)C=NC1=CC=C2CN1CCN(C)CC1 ZHJGWYRLJUCMRT-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
241000894006 Bacteria Species 0.000 description 1
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
FXFJWCTYDLHAJJ-UHFFFAOYSA-J O.O.O.O.O.[Ca++].[Ca++].[O-]P([O-])(=O)OP([O-])([O-])=O Chemical compound O.O.O.O.O.[Ca++].[Ca++].[O-]P([O-])(=O)OP([O-])([O-])=O FXFJWCTYDLHAJJ-UHFFFAOYSA-J 0.000 description 1
241001494479 Pecora Species 0.000 description 1
239000006004 Quartz sand Substances 0.000 description 1
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000007059 acute toxicity Effects 0.000 description 1
231100000403 acute toxicity Toxicity 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000005273 aeration Methods 0.000 description 1
XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
229920005551 calcium lignosulfonate Polymers 0.000 description 1
RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
125000005587 carbonate group Chemical group 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
CXTABWUBRGBDFL-UHFFFAOYSA-N copper;manganese(2+) Chemical compound [Mn+2].[Cu+2] CXTABWUBRGBDFL-UHFFFAOYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
229910000393 dicalcium diphosphate Inorganic materials 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004453 electron probe microanalysis Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
150000004687 hexahydrates Chemical class 0.000 description 1
239000004021 humic acid Substances 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
235000019691 monocalcium phosphate Nutrition 0.000 description 1
229910000150 monocalcium phosphate Inorganic materials 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
210000003205 muscle Anatomy 0.000 description 1
230000001546 nitrifying effect Effects 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
239000003415 peat Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
230000010363 phase shift Effects 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
150000003112 potassium compounds Chemical class 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
229910001414 potassium ion Inorganic materials 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
239000004304 potassium nitrite Substances 0.000 description 1
235000010289 potassium nitrite Nutrition 0.000 description 1
229910000160 potassium phosphate Inorganic materials 0.000 description 1
235000011009 potassium phosphates Nutrition 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000011435 rock Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
239000011669 selenium Substances 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
239000002881 soil fertilizer Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
239000011573 trace mineral Substances 0.000 description 1
235000013619 trace mineral Nutrition 0.000 description 1
229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
230000005641 tunneling Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Fertilizers (AREA)

CA002146359A 1992-10-16 1993-10-15 Sol/engrais synthetiques a liberation lente Expired - Fee Related CA2146359C (fr)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US96334892A	1992-10-16	1992-10-16
US96334992A	1992-10-16	1992-10-16
US07/963,348		1992-10-16
US07/963,349		1992-10-16
PCT/US1993/009906 WO1994008896A1 (fr)	1992-10-16	1993-10-15	Fertilisant a liberation lente et sol synthetique actif

Publications (2)

Publication Number	Publication Date
CA2146359A1 CA2146359A1 (fr)	1994-04-28
CA2146359C true CA2146359C (fr)	2002-01-15

Family

ID=27130451

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002146359A Expired - Fee Related CA2146359C (fr)	1992-10-16	1993-10-15	Sol/engrais synthetiques a liberation lente

Country Status (6)

Country	Link
KR (1)	KR950704190A (fr)
AU (1)	AU675257B2 (fr)
CA (1)	CA2146359C (fr)
GB (1)	GB2288172B (fr)
NZ (1)	NZ257289A (fr)
WO (1)	WO1994008896A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6271174B1 (en) *	1996-11-25	2001-08-07	Allor Foundation	Method of and products for promoting improved growth of plants and more water-efficient growing soilor other media and the like with antzeolite crystals treated with preferably water-based plant-derived nutrient extractions and the like
KR100353155B1 (ko) *	2001-05-31	2002-09-18	호 근 김	천연 게르마늄 광석을 함유하는 비료 조성물 및 이에의하여 재배된 곤달비를 이용하여 제조된 식품
DE10240938A1 (de) *	2002-09-02	2004-03-11	Rheinische Friedrich-Wilhelms-Universität Bonn	Gedeckeltes Düngermitteldepot
US7818916B2 (en)	2004-12-30	2010-10-26	Aerogrow International, Inc.	pH buffered plant nutrient compositions and methods for growing plants
CN102645279B (zh) *	2012-04-18	2013-12-04	中国科学院遥感应用研究所	月表矿物的干涉成像光谱仪高光谱数据模拟方法
US8945392B2 (en) *	2012-09-19	2015-02-03	Red Lion Chem Tech, Llc	Composite for phosphate and ammonium ion removal
WO2015004031A1 (fr) *	2013-07-10	2015-01-15	Again Nutrient Recovery Ab	Récupération de nutriments
DE102014100026A1 (de) *	2014-01-02	2015-07-02	Chemische Fabrik Budenheim Kg	Gemischtmetallische kristalline Orthophosphate für die zeitlich kontrollierte Freisetzung von Spurenelementen im rhizodermalen und epidermalen Bereich von Pflanzen

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4139599A (en) *	1973-01-11	1979-02-13	Colgate Palmolive Company	Process for preparing dicalcium phosphate dihydrate having a portion of the calcium displaced by divalent metal ion
DE3031893A1 (de) *	1980-08-23	1982-04-01	Bayer Ag, 5090 Leverkusen	Duengemittel
EP0205622B1 (fr) *	1984-12-18	1993-09-08	Kanto Kagaku Kabushiki Kaisha	Apatite du type phosphore-calcium possedant de nouvelles proprietes; et son procede de production
US5037470A (en) *	1985-12-17	1991-08-06	Isover Saint-Gobain	Nutritive glasses for agriculture
JPH0279910A (ja) *	1988-09-19	1990-03-20	Ninaki Akira	粒状天然ゼオライトを主成分とする混合園芸培土

1993
- 1993-10-15 NZ NZ257289A patent/NZ257289A/en unknown
- 1993-10-15 KR KR1019950701514A patent/KR950704190A/ko not_active Abandoned
- 1993-10-15 WO PCT/US1993/009906 patent/WO1994008896A1/fr not_active Ceased
- 1993-10-15 CA CA002146359A patent/CA2146359C/fr not_active Expired - Fee Related
- 1993-10-15 AU AU53623/94A patent/AU675257B2/en not_active Ceased
- 1993-10-15 GB GB9507918A patent/GB2288172B/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
GB2288172B (en)	1996-10-23
GB2288172A (en)	1995-10-11
CA2146359A1 (fr)	1994-04-28
KR950704190A (ko)	1995-11-17
NZ257289A (en)	1996-11-26
AU5362394A (en)	1994-05-09
WO1994008896A1 (fr)	1994-04-28
GB9507918D0 (en)	1995-07-12
AU675257B2 (en)	1997-01-30

Legal Events

Date	Code	Title	Description
1998-05-12	EEER	Examination request
2005-10-17	MKLA	Lapsed

Publication	Publication Date	Title
US5433766A (en)	1995-07-18	Slow-release fertilizer
US5451242A (en)	1995-09-19	Active synthetic soil
US11254622B2 (en)	2022-02-22	NPK-Si-humate fertilizer, method for production and use thereof
AU2011288134B2 (en)	2014-02-27	Phosphate fertilizers and methods of using the same
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