CA2159093C - Composition intumescente et methode pour son utilisation - Google Patents

Composition intumescente et methode pour son utilisation Download PDF

Info

Publication number: CA2159093C
Authority: CA; Canada
Prior art keywords: composition; stabilizing agent; accordance; intumescent; char
Prior art date: 1993-04-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002159093A

Other languages

English (en)

Other versions

CA2159093A1 (fr

Inventor

Walton W. Welna

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

3M Co

Original Assignee

Minnesota Mining and Manufacturing Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-04-19

Filing date

1994-02-18

Publication date

2005-12-13

1994-02-18 Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co

1994-02-18 Priority claimed from PCT/US1994/001747 external-priority patent/WO1994024227A1/fr

1994-10-27 Publication of CA2159093A1 publication Critical patent/CA2159093A1/fr

2005-12-13 Application granted granted Critical

2005-12-13 Publication of CA2159093C publication Critical patent/CA2159093C/fr

2014-02-18 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 99
238000000034 method Methods 0.000 title description 4
239000003381 stabilizer Substances 0.000 claims abstract description 31
239000011230 binding agent Substances 0.000 claims abstract description 29
239000000463 material Substances 0.000 claims abstract description 27
150000001875 compounds Chemical class 0.000 claims abstract description 18
239000003063 flame retardant Substances 0.000 claims abstract description 14
125000000217 alkyl group Chemical group 0.000 claims abstract description 12
238000002844 melting Methods 0.000 claims abstract description 10
230000008018 melting Effects 0.000 claims abstract description 10
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
239000001257 hydrogen Substances 0.000 claims abstract description 6
230000006835 compression Effects 0.000 claims description 36
238000007906 compression Methods 0.000 claims description 36
229920001971 elastomer Polymers 0.000 claims description 25
239000011888 foil Substances 0.000 claims description 20
229920001084 poly(chloroprene) Polymers 0.000 claims description 20
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 19
229910052717 sulfur Inorganic materials 0.000 claims description 19
239000011593 sulfur Substances 0.000 claims description 19
229910052782 aluminium Inorganic materials 0.000 claims description 15
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 8
229920005989 resin Polymers 0.000 claims description 8
239000011347 resin Substances 0.000 claims description 8
239000005060 rubber Substances 0.000 claims description 8
239000000654 additive Substances 0.000 claims description 6
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239000002184 metal Substances 0.000 claims description 4
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-1 melamine aldehyde Chemical class 0.000 claims description 3
239000005011 phenolic resin Substances 0.000 claims description 3
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239000005061 synthetic rubber Substances 0.000 claims description 3
MJQUUQZMGJEVJG-UHFFFAOYSA-N methylcarbamothioyl n-methylcarbamodithioate Chemical group CNC(=S)SC(=S)NC MJQUUQZMGJEVJG-UHFFFAOYSA-N 0.000 claims description 2
229920003052 natural elastomer Polymers 0.000 claims description 2
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239000010935 stainless steel Substances 0.000 claims description 2
229920000877 Melamine resin Polymers 0.000 claims 1
229920001195 polyisoprene Polymers 0.000 claims 1
239000000806 elastomer Substances 0.000 description 17
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 14
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 12
239000003795 chemical substances by application Substances 0.000 description 11
239000000047 product Substances 0.000 description 11
239000004615 ingredient Substances 0.000 description 10
239000000126 substance Substances 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
239000003921 oil Substances 0.000 description 7
238000012360 testing method Methods 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
239000003963 antioxidant agent Substances 0.000 description 6
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230000035515 penetration Effects 0.000 description 6
239000002243 precursor Substances 0.000 description 6
239000000779 smoke Substances 0.000 description 6
OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 5
229910000831 Steel Inorganic materials 0.000 description 5
230000003078 antioxidant effect Effects 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 5
239000010959 steel Substances 0.000 description 5
238000004073 vulcanization Methods 0.000 description 5
239000004115 Sodium Silicate Substances 0.000 description 4
239000003086 colorant Substances 0.000 description 4
239000002131 composite material Substances 0.000 description 4
REQPQFUJGGOFQL-UHFFFAOYSA-N dimethylcarbamothioyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SC(=S)N(C)C REQPQFUJGGOFQL-UHFFFAOYSA-N 0.000 description 4
VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 4
239000002245 particle Substances 0.000 description 4
238000011084 recovery Methods 0.000 description 4
238000010998 test method Methods 0.000 description 4
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 4
150000004684 trihydrates Chemical class 0.000 description 4
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
239000002585 base Substances 0.000 description 3
239000011324 bead Substances 0.000 description 3
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000003365 glass fiber Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000000395 magnesium oxide Substances 0.000 description 3
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
238000002156 mixing Methods 0.000 description 3
230000000452 restraining effect Effects 0.000 description 3
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
239000011787 zinc oxide Substances 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
239000012190 activator Substances 0.000 description 2
230000003679 aging effect Effects 0.000 description 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000003490 calendering Methods 0.000 description 2
CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
229920006037 cross link polymer Polymers 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
239000003431 cross linking reagent Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
229920001038 ethylene copolymer Polymers 0.000 description 2
239000000835 fiber Substances 0.000 description 2
229910021485 fumed silica Inorganic materials 0.000 description 2
239000012784 inorganic fiber Substances 0.000 description 2
238000010030 laminating Methods 0.000 description 2
230000007774 longterm Effects 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
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238000002360 preparation method Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
230000006641 stabilisation Effects 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
CAQVSRBJJKXQMO-UHFFFAOYSA-N 1-(8-methylnonyl)-2-phenylbenzene;phosphoric acid Chemical compound OP(O)(O)=O.CC(C)CCCCCCCC1=CC=CC=C1C1=CC=CC=C1 CAQVSRBJJKXQMO-UHFFFAOYSA-N 0.000 description 1
MONCZSPIFIQNAX-UHFFFAOYSA-N 1-chloro-4-[2,2,2-trichloro-1-(4-chlorophenyl)ethyl]benzene;dimethoxy-(4-nitrophenoxy)-sulfanylidene-$l^{5}-phosphane Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C=C1.C1=CC(Cl)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(Cl)C=C1 MONCZSPIFIQNAX-UHFFFAOYSA-N 0.000 description 1
LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 description 1
XUKUURHRXDUEBC-KAYWLYCHSA-N Atorvastatin Chemical compound C=1C=CC=CC=1C1=C(C=2C=CC(F)=CC=2)N(CC[C@@H](O)C[C@@H](O)CC(O)=O)C(C(C)C)=C1C(=O)NC1=CC=CC=C1 XUKUURHRXDUEBC-KAYWLYCHSA-N 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920013683 Celanese Polymers 0.000 description 1
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
229920001875 Ebonite Polymers 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
241001517310 Eria Species 0.000 description 1
241000411532 Erites Species 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
101100364827 Prochlorococcus marinus (strain SARG / CCMP1375 / SS120) ahcY gene Proteins 0.000 description 1
239000006004 Quartz sand Substances 0.000 description 1
101150081953 SAM1 gene Proteins 0.000 description 1
230000032683 aging Effects 0.000 description 1
230000004075 alteration Effects 0.000 description 1
229920003235 aromatic polyamide Polymers 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000011111 cardboard Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
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238000011161 development Methods 0.000 description 1
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238000006073 displacement reaction Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
239000004744 fabric Substances 0.000 description 1
230000009970 fire resistant effect Effects 0.000 description 1
239000010881 fly ash Substances 0.000 description 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229920002681 hypalon Polymers 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000009434 installation Methods 0.000 description 1
238000009413 insulation Methods 0.000 description 1
239000011133 lead Substances 0.000 description 1
231100001231 less toxic Toxicity 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000011490 mineral wool Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
RNVCVTLRINQCPJ-UHFFFAOYSA-N o-toluidine Chemical compound CC1=CC=CC=C1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 description 1
239000000123 paper Substances 0.000 description 1
239000011087 paperboard Substances 0.000 description 1
239000010451 perlite Substances 0.000 description 1
235000019362 perlite Nutrition 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
239000002985 plastic film Substances 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
229910001948 sodium oxide Inorganic materials 0.000 description 1
235000019351 sodium silicates Nutrition 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
238000004154 testing of material Methods 0.000 description 1
239000010455 vermiculite Substances 0.000 description 1
229910052902 vermiculite Inorganic materials 0.000 description 1
235000019354 vermiculite Nutrition 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA002159093A 1993-04-19 1994-02-18 Composition intumescente et methode pour son utilisation Expired - Fee Related CA2159093C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US4951993A	1993-04-19	1993-04-19
US08/049519		1993-04-19
PCT/US1994/001747 WO1994024227A1 (fr)	1993-04-19	1994-02-18	Composition intumescente et procede d'utilisation

Publications (2)

Publication Number	Publication Date
CA2159093A1 CA2159093A1 (fr)	1994-10-27
CA2159093C true CA2159093C (fr)	2005-12-13

Family

ID=35517564

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002159093A Expired - Fee Related CA2159093C (fr)	1993-04-19	1994-02-18	Composition intumescente et methode pour son utilisation

Country Status (1)

Country	Link
CA (1)	CA2159093C (fr)

1994
- 1994-02-18 CA CA002159093A patent/CA2159093C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2159093A1 (fr)	1994-10-27

Legal Events

Date	Code	Title	Description
2000-10-04	EEER	Examination request
2011-02-18	MKLA	Lapsed

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