CA2174723C - Processus de production d'alcools gras par fractionnement a partir de graisses et d'huiles vegetales - Google Patents

Processus de production d'alcools gras par fractionnement a partir de graisses et d'huiles vegetales Download PDF

Info

Publication number: CA2174723C
Authority: CA; Canada
Prior art keywords: fatty; fatty alcohols; acid methyl; fatty acid; fatty alcohol
Prior art date: 1993-10-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002174723A

Other languages

English (en)

Other versions

CA2174723A1 (fr

Inventor

Michael Koehler

Karl-Heinz Schmid

Guenther Demmering

Horst-Dieter Komp

Hans-Peter Kubersky

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Personal Care and Nutrition GmbH

Original Assignee

Cognis Deutschland GmbH and Co KG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-10-20

Filing date

1994-10-12

Publication date

2006-10-03

1993-10-20 Priority claimed from DE4335781A external-priority patent/DE4335781C2/de

1994-10-12 Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG

1995-04-27 Publication of CA2174723A1 publication Critical patent/CA2174723A1/fr

2006-10-03 Application granted granted Critical

2006-10-03 Publication of CA2174723C publication Critical patent/CA2174723C/fr

2014-10-12 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

150000002191 fatty alcohols Chemical class 0.000 title claims abstract description 97
235000015112 vegetable and seed oil Nutrition 0.000 title claims abstract description 22
238000000034 method Methods 0.000 title claims abstract description 20
238000004519 manufacturing process Methods 0.000 title claims abstract description 12
239000003921 oil Substances 0.000 title claims description 20
235000019871 vegetable fat Nutrition 0.000 title claims description 17
238000005194 fractionation Methods 0.000 title description 12
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 37
229910052740 iodine Inorganic materials 0.000 claims abstract description 37
239000011630 iodine Substances 0.000 claims abstract description 37
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 21
229930195729 fatty acid Natural products 0.000 claims abstract description 21
239000000194 fatty acid Substances 0.000 claims abstract description 21
235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 21
150000004665 fatty acids Chemical class 0.000 claims abstract description 21
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
229920006395 saturated elastomer Polymers 0.000 claims abstract description 8
239000000470 constituent Substances 0.000 claims abstract description 7
150000001875 compounds Chemical class 0.000 claims description 9
239000003599 detergent Substances 0.000 claims description 4
238000004140 cleaning Methods 0.000 claims description 2
238000004851 dishwashing Methods 0.000 claims description 2
239000000047 product Substances 0.000 abstract description 28
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 9
238000005984 hydrogenation reaction Methods 0.000 abstract description 9
239000000203 mixture Substances 0.000 abstract description 5
239000008158 vegetable oil Substances 0.000 abstract description 5
238000004821 distillation Methods 0.000 abstract description 4
239000002994 raw material Substances 0.000 abstract description 4
239000007795 chemical reaction product Substances 0.000 abstract description 3
150000003626 triacylglycerols Chemical class 0.000 abstract description 3
150000001298 alcohols Chemical class 0.000 abstract 1
125000000217 alkyl group Chemical group 0.000 abstract 1
239000003795 chemical substances by application Substances 0.000 abstract 1
239000012459 cleaning agent Substances 0.000 abstract 1
230000009183 running Effects 0.000 abstract 1
238000005406 washing Methods 0.000 abstract 1
239000003925 fat Substances 0.000 description 9
235000019197 fats Nutrition 0.000 description 9
230000000875 corresponding effect Effects 0.000 description 7
238000009826 distribution Methods 0.000 description 5
150000004702 methyl esters Chemical class 0.000 description 5
239000003346 palm kernel oil Substances 0.000 description 5
235000019865 palm kernel oil Nutrition 0.000 description 5
235000019484 Rapeseed oil Nutrition 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 3
239000002253 acid Substances 0.000 description 3
230000002349 favourable effect Effects 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
235000019198 oils Nutrition 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
238000007127 saponification reaction Methods 0.000 description 3
239000003054 catalyst Substances 0.000 description 2
HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
239000003240 coconut oil Substances 0.000 description 2
235000019864 coconut oil Nutrition 0.000 description 2
239000002537 cosmetic Substances 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
102220254284 rs755928199 Human genes 0.000 description 2
238000005809 transesterification reaction Methods 0.000 description 2
DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
235000013311 vegetables Nutrition 0.000 description 2
241000196324 Embryophyta Species 0.000 description 1
235000019482 Palm oil Nutrition 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
235000019486 Sunflower oil Nutrition 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
235000012000 cholesterol Nutrition 0.000 description 1
239000012043 crude product Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
230000009965 odorless effect Effects 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000010517 secondary reaction Methods 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
150000003431 steroids Chemical class 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000002600 sunflower oil Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
-1 unsaturated fatty acid methyl esters Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2027—Monohydric alcohols unsaturated
- C11D3/2031—Monohydric alcohols unsaturated fatty or with at least 8 carbon atoms in the alkenyl chain
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
- C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
- C11D3/202—Monohydric alcohols branched fatty or with at least 8 carbon atoms in the alkyl chain

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Emergency Medicine (AREA)
Wood Science & Technology (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Animal Behavior & Ethology (AREA)
General Health & Medical Sciences (AREA)
Public Health (AREA)
Veterinary Medicine (AREA)
Dermatology (AREA)
Birds (AREA)
Epidemiology (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Fats And Perfumes (AREA)
Detergent Compositions (AREA)

CA002174723A 1993-10-20 1994-10-12 Processus de production d'alcools gras par fractionnement a partir de graisses et d'huiles vegetales Expired - Lifetime CA2174723C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE4335781A DE4335781C2 (de)	1993-10-20	1993-10-20	Fettalkohole auf pflanzlicher Basis und Verfahren zu Ihrer Herstellung
DEP4335781.4		1993-10-20
PCT/EP1994/003348 WO1995011210A1 (fr)	1993-10-20	1994-10-12	Procede de production d'alcools gras a base vegetale par distillation fractionnee

Publications (2)

Publication Number	Publication Date
CA2174723A1 CA2174723A1 (fr)	1995-04-27
CA2174723C true CA2174723C (fr)	2006-10-03

Family

ID=37101732

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002174723A Expired - Lifetime CA2174723C (fr)	1993-10-20	1994-10-12	Processus de production d'alcools gras par fractionnement a partir de graisses et d'huiles vegetales

Country Status (1)

Country	Link
CA (1)	CA2174723C (fr)

1994
- 1994-10-12 CA CA002174723A patent/CA2174723C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2174723A1 (fr)	1995-04-27

Legal Events

Date	Code	Title	Description
2001-10-05	EEER	Examination request
2014-12-16	MKEX	Expiry	Effective date: 20141014

Publication	Publication Date	Title
US5672781A (en)	1997-09-30	Process for the production of fatty alcohols based on vegetable fats and oils by fractionation
US4164505A (en)	1979-08-14	Flow process for conjugating unconjugated unsaturation of fatty acids
US7169959B2 (en)	2007-01-30	Unsaturated palm oil fatty alcohols
JPH10502115A (ja)	1998-02-24	改良された低温挙動を有する不飽和脂肪物質
JP2001523654A5 (fr)	2006-01-05
US4754090A (en)	1988-06-28	Process for the preparation of hexamethyl tetracosanes
CA2422804C (fr)	2011-08-02	Procede de fabrication de produits bruts pour l'obtention d'acide linoleique conjugue
CA2174723C (fr)	2006-10-03	Processus de production d'alcools gras par fractionnement a partir de graisses et d'huiles vegetales
US6187974B1 (en)	2001-02-13	Process for producing unsaturated fatty alcohols from lauric oils
US7408087B2 (en)	2008-08-05	Process for making unsaturated coconut and/or palm nut fatty alcohols
US6548717B1 (en)	2003-04-15	Process for making branched, substantially unsaturated fatty alcohols
Combs	1985	Processing for industrial fatty acids‐I
JP2001523655A (ja)	2001-11-27	ヤシおよび／またはパーム核不飽和脂肪アルコール
US6232480B1 (en)	2001-05-15	Method of making hydrogenated acids
Diamond et al.	1970	Some chemical processes utilizing oleic safflower oil
DE19736737C2 (de)	1999-11-11	Verfahren zu Herstellung von oxidationsstabilen Oleinen und ihre Verwendung zur Herstellung von Wasch- und Reinigungsmitteln, kosmetischen und/oder pharmazeutischen Formulierungen, ungesättigten Fettalkoholen oder Estern
DE4338974C2 (de)	1996-12-05	Verfahren zur Herstellung von Fettalkoholen mit verbesserter Produktqualität
US20260062368A1 (en)	2026-03-05	Insect Oils as Natural Raw Materials for Alcohol Production
Akaike	1985	Other oleochemical uses: palm oil products
DE19912683C2 (de)	2001-07-12	Verfahren zur Herstellung von Palmfettalkoholen
DE19912684A1 (de)	2000-09-28	Verfahren zur Herstellung von Kokos- und/oder Palmkernfettalkoholen
CA1117138A (fr)	1982-01-26	Dynamique pour conjuguer l'insaturation non conjuguee d'acides gras
DE9422265U1 (de)	1999-09-09	Fettalkohole auf pflanzlicher Basis
JPH08245997A (ja)	1996-09-24	石鹸原料の製造法