CA2187984C - Pile electrochimique alcaline rechargeable - Google Patents

Pile electrochimique alcaline rechargeable

Info

Publication number: CA2187984C
Authority: CA; Canada
Prior art keywords: current collector; anode; anode current; weight; cell
Prior art date: 1996-04-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002187984A

Other languages

English (en)

Other versions

CA2187984A1 (fr

Inventor

Robert J. Jacus

Janna L. Rose

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Spectrum Brands Inc

Original Assignee

Rayovac Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-04-12

Filing date

1996-10-16

Publication date

2001-01-30

1996-10-16 Application filed by Rayovac Corp filed Critical Rayovac Corp

1997-10-13 Publication of CA2187984A1 publication Critical patent/CA2187984A1/fr

2001-01-30 Application granted granted Critical

2001-01-30 Publication of CA2187984C publication Critical patent/CA2187984C/fr

2016-10-16 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 claims abstract description 78
239000010949 copper Substances 0.000 claims abstract description 55
229910052802 copper Inorganic materials 0.000 claims abstract description 54
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 53
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 46
229910052725 zinc Inorganic materials 0.000 claims abstract description 44
239000011701 zinc Substances 0.000 claims abstract description 44
229910052710 silicon Inorganic materials 0.000 claims abstract description 41
239000010703 silicon Substances 0.000 claims abstract description 41
238000006243 chemical reaction Methods 0.000 claims abstract description 25
230000003647 oxidation Effects 0.000 claims abstract description 25
238000007254 oxidation reaction Methods 0.000 claims abstract description 25
230000002427 irreversible effect Effects 0.000 claims abstract description 12
239000003792 electrolyte Substances 0.000 claims description 13
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 11
229910052748 manganese Inorganic materials 0.000 claims description 11
239000011572 manganese Substances 0.000 claims description 11
230000002441 reversible effect Effects 0.000 claims description 10
229920000298 Cellophane Polymers 0.000 claims description 4
230000004888 barrier function Effects 0.000 claims description 2
230000009286 beneficial effect Effects 0.000 claims 1
230000002708 enhancing effect Effects 0.000 claims 1
229910001369 Brass Inorganic materials 0.000 abstract description 14
239000010951 brass Substances 0.000 abstract description 14
230000002829 reductive effect Effects 0.000 abstract description 9
230000010287 polarization Effects 0.000 abstract description 7
230000010261 cell growth Effects 0.000 abstract description 3
230000000694 effects Effects 0.000 abstract 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 26
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 23
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 18
239000005751 Copper oxide Substances 0.000 description 18
229910000431 copper oxide Inorganic materials 0.000 description 18
238000012360 testing method Methods 0.000 description 16
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
238000005260 corrosion Methods 0.000 description 9
230000007797 corrosion Effects 0.000 description 9
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
230000004048 modification Effects 0.000 description 8
238000012986 modification Methods 0.000 description 8
239000000463 material Substances 0.000 description 7
239000000654 additive Substances 0.000 description 6
238000000034 method Methods 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
150000001879 copper Chemical class 0.000 description 5
239000007789 gas Substances 0.000 description 5
230000008569 process Effects 0.000 description 5
SZKTYYIADWRVSA-UHFFFAOYSA-N zinc manganese(2+) oxygen(2-) Chemical compound [O--].[O--].[Mn++].[Zn++] SZKTYYIADWRVSA-UHFFFAOYSA-N 0.000 description 5
229910045601 alloy Inorganic materials 0.000 description 4
239000000956 alloy Substances 0.000 description 4
239000011787 zinc oxide Substances 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
230000000996 additive effect Effects 0.000 description 3
239000010405 anode material Substances 0.000 description 3
230000005611 electricity Effects 0.000 description 3
238000003487 electrochemical reaction Methods 0.000 description 3
239000012535 impurity Substances 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
-1 polyethylene Polymers 0.000 description 3
229920001343 polytetrafluoroethylene Polymers 0.000 description 3
239000004810 polytetrafluoroethylene Substances 0.000 description 3
230000009467 reduction Effects 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
229920001131 Pulp (paper) Polymers 0.000 description 2
GOPYZMJAIPBUGX-UHFFFAOYSA-N [O-2].[O-2].[Mn+4] Chemical compound [O-2].[O-2].[Mn+4] GOPYZMJAIPBUGX-UHFFFAOYSA-N 0.000 description 2
230000004075 alteration Effects 0.000 description 2
239000010406 cathode material Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000004020 conductor Substances 0.000 description 2
230000001627 detrimental effect Effects 0.000 description 2
238000007599 discharging Methods 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000012777 electrically insulating material Substances 0.000 description 2
230000006870 function Effects 0.000 description 2
229910002804 graphite Inorganic materials 0.000 description 2
239000010439 graphite Substances 0.000 description 2
238000000465 moulding Methods 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
229920001059 synthetic polymer Polymers 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000006182 cathode active material Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
238000002788 crimping Methods 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000003349 gelling agent Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
150000002472 indium compounds Chemical class 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
150000002697 manganese compounds Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000000615 nonconductor Substances 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000012466 permeate Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920002492 poly(sulfone) Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
230000002250 progressing effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
238000005215 recombination Methods 0.000 description 1
230000006798 recombination Effects 0.000 description 1
230000027756 respiratory electron transport chain Effects 0.000 description 1
239000000565 sealant Substances 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
230000001629 suppression Effects 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Battery Electrode And Active Subsutance (AREA)
Silicon Compounds (AREA)
Primary Cells (AREA)

CA002187984A 1996-04-12 1996-10-16 Pile electrochimique alcaline rechargeable Expired - Fee Related CA2187984C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US1536896P	1996-04-12	1996-04-12
US60/015,368		1996-04-12

Publications (2)

Publication Number	Publication Date
CA2187984A1 CA2187984A1 (fr)	1997-10-13
CA2187984C true CA2187984C (fr)	2001-01-30

Family

ID=21770999

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002187984A Expired - Fee Related CA2187984C (fr)	1996-04-12	1996-10-16	Pile electrochimique alcaline rechargeable

Country Status (1)

Country	Link
CA (1)	CA2187984C (fr)

1996
- 1996-10-16 CA CA002187984A patent/CA2187984C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2187984A1 (fr)	1997-10-13

Legal Events

Date	Code	Title	Description
1996-11-08	EEER	Examination request
2004-10-18	MKLA	Lapsed

Publication	Publication Date	Title
EP0747983B1 (fr)	1999-08-11	Cellule alcaline avec une cathode contenant un additif
JP3462877B2 (ja)	2003-11-05	亜鉛アノードを用いた電気化学電池
US5424145A (en)	1995-06-13	High capacity rechargeable cell having manganese dioxide electrode
US5607796A (en)	1997-03-04	Rechargeable alkaline electrochemical cell
CA1310362C (fr)	1992-11-17	Cellule electrochimique rechargeable a electrolyte alkakin et cathode zinc-dioxyde de manganese, a capacite amelioree
CN100524909C (zh)	2009-08-05	用于碱性电池的阴极材料和添加剂
US7314681B2 (en)	2008-01-01	Cylindrical alkaline cells with increased discharge performance
HU215866B (hu)	1999-03-29	Katódszerkezet alkáli mangán-dioxid-cink cellákhoz megnövelt kapacitással
CN101317287B (zh)	2010-11-17	容量衰减减缓和循环寿命改善的可再充电碱性锰电池
US3288642A (en)	1966-11-29	Rechargeable dry cell having gelled electrolyte
CA2187984C (fr)	2001-01-30	Pile electrochimique alcaline rechargeable
EP0801432B1 (fr)	2000-01-26	Pile électrochimique rechargeable à électrolyte alcalin
HU208596B (en)	1993-11-29	Rechargeable electrochemical cell
EP1293002B1 (fr)	2005-05-11	Pile electrochimique avec une anode contenant du soufre
JP2011513910A (ja)	2011-04-28	単３及び単４電池用のカソード
JPH11339846A (ja)	1999-12-10	密閉型アルカリ亜鉛蓄電池
EP0822607A1 (fr)	1998-02-04	Pile électrochimique rechargeable à électrolyte alcalin
CA2037744A1 (fr)	1992-09-08	Element manganese alcalin rechargeable a capacite et densite d'energie ameliorees
JP2559593B2 (ja)	1996-12-04	密閉型ニッケル−カドミウム蓄電池とその充電方法
HK1007406B (en)	2000-06-16	Alkaline cell having a cathode including an additive
CA2188120A1 (fr)	1998-01-31	Pile electrochimique alcaline rechargeable
JPH01117273A (ja)	1989-05-10	鉛蓄電池
JPH11329508A (ja)	1999-11-30	アルカリマンガン電池の充電方法