CA2191679A1 - Process for preparing colour contrasts on articles obtained by molding from polymerizable compositions - Google Patents

Process for preparing colour contrasts on articles obtained by molding from polymerizable compositions

Info

Publication number: CA2191679A1
Authority: CA; Canada
Prior art keywords: weight; composition; articles; polymerizable; molding process
Prior art date: 1995-11-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002191679A

Other languages

English (en)

French (fr)

Inventor

Franco Marciandi

Marco Bertani

Giorgio Zanzottera

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Atohaas Holding CV

Original Assignee

Atohaas Holding CV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-11-30

Filing date

1996-11-29

Publication date

1997-05-31

1996-11-29 Application filed by Atohaas Holding CV filed Critical Atohaas Holding CV

1997-05-31 Publication of CA2191679A1 publication Critical patent/CA2191679A1/en

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 72
238000000465 moulding Methods 0.000 title claims abstract description 12
238000004519 manufacturing process Methods 0.000 title description 2
239000004925 Acrylic resin Substances 0.000 claims abstract description 30
229920000178 Acrylic resin Polymers 0.000 claims abstract description 30
239000012530 fluid Substances 0.000 claims abstract description 23
239000000178 monomer Substances 0.000 claims abstract description 23
239000006185 dispersion Substances 0.000 claims abstract description 17
238000000034 method Methods 0.000 claims abstract description 16
239000002904 solvent Substances 0.000 claims abstract description 16
230000008569 process Effects 0.000 claims abstract description 12
238000000576 coating method Methods 0.000 claims abstract description 9
125000000524 functional group Chemical group 0.000 claims abstract description 9
239000011248 coating agent Substances 0.000 claims abstract description 8
238000004040 coloring Methods 0.000 claims abstract description 7
238000004132 cross linking Methods 0.000 claims abstract description 7
238000011049 filling Methods 0.000 claims abstract description 6
239000001023 inorganic pigment Substances 0.000 claims abstract description 6
239000000049 pigment Substances 0.000 claims abstract description 6
239000007788 liquid Substances 0.000 claims abstract description 4
239000003960 organic solvent Substances 0.000 claims abstract description 3
239000000945 filler Substances 0.000 claims description 16
238000006116 polymerization reaction Methods 0.000 claims description 14
239000011347 resin Substances 0.000 claims description 12
229920005989 resin Polymers 0.000 claims description 12
-1 amidic Chemical group 0.000 claims description 11
239000002270 dispersing agent Substances 0.000 claims description 11
239000003795 chemical substances by application Substances 0.000 claims description 10
125000003700 epoxy group Chemical group 0.000 claims description 8
229920001187 thermosetting polymer Polymers 0.000 claims description 7
239000000654 additive Substances 0.000 claims description 6
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
239000012190 activator Substances 0.000 claims description 4
239000003431 cross linking reagent Substances 0.000 claims description 4
239000004094 surface-active agent Substances 0.000 claims description 4
239000003085 diluting agent Substances 0.000 claims description 3
239000003112 inhibitor Substances 0.000 claims description 3
239000012860 organic pigment Substances 0.000 claims description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
239000000306 component Substances 0.000 description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
229920001577 copolymer Polymers 0.000 description 12
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 11
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
239000003973 paint Substances 0.000 description 9
229940102838 methylmethacrylate Drugs 0.000 description 8
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
239000000377 silicon dioxide Substances 0.000 description 6
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
239000012764 mineral filler Substances 0.000 description 5
150000002978 peroxides Chemical class 0.000 description 5
239000000126 substance Substances 0.000 description 5
XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 4
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
229940038597 peroxide anti-acne preparations for topical use Drugs 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 3
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
150000004665 fatty acids Chemical group 0.000 description 3
229940090044 injection Drugs 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
239000004926 polymethyl methacrylate Substances 0.000 description 3
229920001296 polysiloxane Polymers 0.000 description 3
229910000077 silane Inorganic materials 0.000 description 3
238000003756 stirring Methods 0.000 description 3
229920001169 thermoplastic Polymers 0.000 description 3
239000004416 thermosoftening plastic Substances 0.000 description 3
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
241000529895 Stercorarius Species 0.000 description 2
239000002253 acid Substances 0.000 description 2
229920000180 alkyd Polymers 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
239000000975 dye Substances 0.000 description 2
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
239000003999 initiator Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
125000005395 methacrylic acid group Chemical group 0.000 description 2
229920000847 nonoxynol Polymers 0.000 description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
238000002444 silanisation Methods 0.000 description 2
239000006188 syrup Substances 0.000 description 2
235000020357 syrup Nutrition 0.000 description 2
150000003505 terpenes Chemical class 0.000 description 2
235000007586 terpenes Nutrition 0.000 description 2
238000005406 washing Methods 0.000 description 2
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
GONFBOIJNUKKST-UHFFFAOYSA-N 5-ethylsulfanyl-2h-tetrazole Chemical compound CCSC=1N=NNN=1 GONFBOIJNUKKST-UHFFFAOYSA-N 0.000 description 1
OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
229920005440 Altuglas® Polymers 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical group CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
ZMJBYMUCKBYSCP-UHFFFAOYSA-N Hydroxycitric acid Chemical compound OC(=O)C(O)C(O)(C(O)=O)CC(O)=O ZMJBYMUCKBYSCP-UHFFFAOYSA-N 0.000 description 1
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
125000005595 acetylacetonate group Chemical group 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
MOYAFQVGZZPNRA-UHFFFAOYSA-N alpha-Terpinolene Natural products CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
230000008901 benefit Effects 0.000 description 1
229960003328 benzoyl peroxide Drugs 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
229910002026 crystalline silica Inorganic materials 0.000 description 1
230000007547 defect Effects 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003822 epoxy resin Substances 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
FKIRSCKRJJUCNI-UHFFFAOYSA-N ethyl 7-bromo-1h-indole-2-carboxylate Chemical compound C1=CC(Br)=C2NC(C(=O)OCC)=CC2=C1 FKIRSCKRJJUCNI-UHFFFAOYSA-N 0.000 description 1
239000011521 glass Substances 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000011256 inorganic filler Substances 0.000 description 1
229910003475 inorganic filler Inorganic materials 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
231100001231 less toxic Toxicity 0.000 description 1
239000000463 material Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
125000000896 monocarboxylic acid group Chemical group 0.000 description 1
125000005609 naphthenate group Chemical group 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
125000005474 octanoate group Chemical group 0.000 description 1
239000003921 oil Substances 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
125000005634 peroxydicarbonate group Chemical group 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
150000004053 quinones Chemical class 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
239000012763 reinforcing filler Substances 0.000 description 1
229920006395 saturated elastomer Chemical class 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
239000011669 selenium Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
229920006337 unsaturated polyester resin Polymers 0.000 description 1
229940117958 vinyl acetate Drugs 0.000 description 1
125000002348 vinylic group Chemical group 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
- B29C37/0032—In-mould coating, e.g. by introducing the coating material into the mould after forming the article the coating being applied upon the mould surface before introducing the moulding compound, e.g. applying a gelcoat
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/0007—Manufacturing coloured articles not otherwise provided for, e.g. by colour change
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
- B29C2037/0035—In-mould coating, e.g. by introducing the coating material into the mould after forming the article the coating being applied as liquid, gel, paste or the like
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/002—Coloured

Landscapes

Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Mechanical Engineering (AREA)
Paints Or Removers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerisation Methods In General (AREA)
Casting Or Compression Moulding Of Plastics Or The Like (AREA)

CA002191679A 1995-11-30 1996-11-29 Process for preparing colour contrasts on articles obtained by molding from polymerizable compositions Abandoned CA2191679A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT95MI002514A IT1277005B1 (it)	1995-11-30	1995-11-30	Processo per preparare contrasti di colore su articoli ottenuti per stampaggio da composizioni polimerizzabili
ITMI95A002514		1995-11-30

Publications (1)

Publication Number	Publication Date
CA2191679A1 true CA2191679A1 (en)	1997-05-31

Family

ID=11372637

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002191679A Abandoned CA2191679A1 (en)	1995-11-30	1996-11-29	Process for preparing colour contrasts on articles obtained by molding from polymerizable compositions

Country Status (6)

Country	Link
EP (1)	EP0776748A2 (it)
JP (1)	JPH09174578A (it)
CN (1)	CN1157773A (it)
CA (1)	CA2191679A1 (it)
IT (1)	IT1277005B1 (it)
MX (1)	MX9606040A (it)

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DE102009059210A1 (de) *	2009-12-18	2011-06-22	fischerwerke GmbH & Co. KG, 72178	Radikalisch polymerisierbarer Befestigungsmörtel mit Silanzusätzen
US20150048536A1 (en) *	2013-08-15	2015-02-19	Tamicare Limited	Method for colouring products on a mould surface
CN118076696A (zh) *	2022-01-12	2024-05-24	积水化学工业株式会社	无机微粒分散用载体组合物、无机微粒分散用载体组合物的制造方法、无机微粒分散浆料组合物和电子部件的制造方法

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US3324074A (en)	1965-01-06	1967-06-06	Monsanto Co	Methacrylate polymers with fillers and coupling agents
GB1493393A (en)	1974-05-29	1977-11-30	Ici Ltd	Fluid curable compositions containing particulate fillers and composite polymeric materials obtained therefrom
DE3278462D1 (en)	1981-03-20	1988-06-16	Ici Plc	Process for providing colour contrast on surface of moulded article
GB8521652D0 (en)	1985-08-30	1985-10-02	Ici Plc	Moulding articles & composition
IT1223502B (it)	1987-12-17	1990-09-19	Vedril Spa	Procedimento per la preparazione di sospensioni fluidi stabili ed induribili e composizioni cosi' ottenute

1995
- 1995-11-30 IT IT95MI002514A patent/IT1277005B1/it active IP Right Grant
1996
- 1996-11-26 EP EP96118880A patent/EP0776748A2/en not_active Withdrawn
- 1996-11-27 JP JP8316540A patent/JPH09174578A/ja active Pending
- 1996-11-29 CA CA002191679A patent/CA2191679A1/en not_active Abandoned
- 1996-11-30 CN CN96118999.1A patent/CN1157773A/zh active Pending
- 1996-12-02 MX MX9606040A patent/MX9606040A/es unknown

Also Published As

Publication number	Publication date
CN1157773A (zh)	1997-08-27
IT1277005B1 (it)	1997-11-04
MX9606040A (es)	1997-08-30
ITMI952514A1 (it)	1997-05-30
JPH09174578A (ja)	1997-07-08
EP0776748A2 (en)	1997-06-04
ITMI952514A0 (it)	1995-11-30

Legal Events

Date	Code	Title	Description
2011-04-01	FZDE	Discontinued	Effective date: 19991129

Publication	Publication Date	Title
CN103382324B (zh)	2017-05-10	用于利用反应注塑涂覆成型体的反应性混合物和经涂覆的成型体
US5266253A (en)	1993-11-30	Method of manufacturing molded polymer articles containing highly filled casting resins and having color differentiated surface regions
AU657180B2 (en)	1995-03-02	Polymerisable compositions
DE69214516T2 (de)	1997-03-06	Hochgefüllte Polymerisierbare Zusammensetzungen
KR100232546B1 (ko)	1999-12-01	(메타)아크릴시럽 및 그 제조방법, (메타)아크릴시럽을 함유하는 성형재료의 제조방법
EP0362884A2 (en)	1990-04-11	Granite-like artificial stone
CA1218493A (en)	1987-02-24	Use of iron oxide pigments in a polymethyl methacrylate article
JPS6030256B2 (ja)	1985-07-15	プラスチックモ−ルド部品の製造方法
US5556666A (en)	1996-09-17	Process for preparing color contrasts on articles obtained by molding from polymerizable compositions
US20020169236A1 (en)	2002-11-14	Decorative solid surfacing materials filled with ceramic microspheres
EP0776748A2 (en)	1997-06-04	Process for preparing colour contrasts on articles obtained by molding from polymerizable compositions
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CA2191680A1 (en)	1997-05-31	Process for preparing colour contrasts on articles obtained by molding from polymerizable compositions
CN1240793C (zh)	2006-02-08	加压涂覆方法和组合物
CA2012949C (en)	2000-05-09	Acrylic composite materials
MXPA96006040A (en)	1997-08-01	Procedure for the preparation of color contrast in articles obtained by molding from part polymerizab compositions
MXPA96006039A (en)	1997-08-01	Procedure for the preparation of decolor contrast in articles obtained by molding from polymerizab compositions
KR100571951B1 (ko)	2006-04-18	충전 아크릴 고체 표면 재료에서의 3차원 옹이의 형성
JP3943707B2 (ja)	2007-07-11	樹脂成形品の製造方法
GB2277477A (en)	1994-11-02	Preparation of lustrous polymer articles
US5294676A (en)	1994-03-15	Methacrylic resin compositions with improved tacky adhesion and method for preparation thereof
DE2243991C3 (de)	1976-07-22	Herstellung ruB-gefärbter Formgegenstände aus ungesättigten Polyesterharzen
JPH11240042A (ja)	1999-09-07	樹脂成形品の製造方法
FR2704550A1 (fr)	1994-11-04	Procédé de préparation de matières plastiques d'acrylate colorées ayant une surface à brillant métallique.
KR19990001317A (ko)	1999-01-15	열경화성 아크릴 수지 조성물 및 그것을 이용한 성형품의 제조방법