CA2199869A1 - Procede de polymerisation - Google Patents

Procede de polymerisation

Info

Publication number
CA2199869A1
CA2199869A1 CA002199869A CA2199869A CA2199869A1 CA 2199869 A1 CA2199869 A1 CA 2199869A1 CA 002199869 A CA002199869 A CA 002199869A CA 2199869 A CA2199869 A CA 2199869A CA 2199869 A1 CA2199869 A1 CA 2199869A1
Authority
CA
Canada
Prior art keywords
polymer
accordance
ethylene
range
metallocene catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002199869A
Other languages
English (en)
Inventor
Scott Kevin Jackson
Vispi Rustom Sagar
Eugene Edmond Poirot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/306,055 external-priority patent/US5763543A/en
Priority claimed from US08/332,162 external-priority patent/US5712353A/en
Application filed by Individual filed Critical Individual
Publication of CA2199869A1 publication Critical patent/CA2199869A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La présente invention concerne un procédé de polymérisation en phase gazeuse d'oléfines, consistant à utiliser un système catalyseur à alliage organo-métallique pour produire des polymères basse densité à poids moléculaire relativement élevé.
CA002199869A 1994-09-14 1995-09-13 Procede de polymerisation Abandoned CA2199869A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/306,055 1994-09-14
US08/306,055 US5763543A (en) 1994-09-14 1994-09-14 Olefin polymerization process with little or no scavenger present
US08/332,162 1994-10-31
US08/332,162 US5712353A (en) 1994-10-31 1994-10-31 Gas phase polymerization process

Publications (1)

Publication Number Publication Date
CA2199869A1 true CA2199869A1 (fr) 1996-03-21

Family

ID=26974934

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002199869A Abandoned CA2199869A1 (fr) 1994-09-14 1995-09-13 Procede de polymerisation

Country Status (6)

Country Link
EP (1) EP0781301A1 (fr)
JP (1) JPH10506659A (fr)
KR (1) KR970706320A (fr)
AU (1) AU3587495A (fr)
CA (1) CA2199869A1 (fr)
WO (1) WO1996008521A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4595140B2 (ja) * 1997-11-12 2010-12-08 住友化学株式会社 熱可塑性樹脂組成物
CA2381723C (fr) * 1999-08-13 2007-10-30 Basell Polyolefine Gmbh Copolymeres d'ethylene et d'.alpha.-olefines c3-c12
US7125933B2 (en) 2000-06-22 2006-10-24 Univation Technologies, Llc Very low density polyethylene blends
US6932592B2 (en) 2000-06-22 2005-08-23 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes
EP1325073B1 (fr) * 2000-06-22 2007-05-09 ExxonMobil Chemical Patents Inc. Polyethylenes tres basse densite produits par catalyse metallocenique
US7259211B2 (en) 2003-12-12 2007-08-21 Mitsui Chemicals, Inc. Ethylene type ternary copolymer and propylene type resin composition
JP2010159217A (ja) * 2009-01-07 2010-07-22 National Institute Of Advanced Industrial Science & Technology 遺伝子及び溶解性制御因子を含む組織再生用スキャッフォールド、及びその製造方法
ES2975017T3 (es) 2015-07-09 2024-07-02 Ineos Europe Ag Copolímeros y películas de los mismos

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5017665A (en) * 1989-07-25 1991-05-21 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin and 1,4-diolefin copolymerization
US5246783A (en) * 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
US5241031A (en) * 1992-02-19 1993-08-31 Exxon Chemical Patents Inc. Elastic articles having improved unload power and a process for their production
CA2141616A1 (fr) * 1992-08-05 1994-02-17 Gregory G. Hlatky Polymerisation en phase gazeuse d'ethylene et d'olefines c7 a c10

Also Published As

Publication number Publication date
MX9701924A (es) 1998-07-31
KR970706320A (ko) 1997-11-03
JPH10506659A (ja) 1998-06-30
AU3587495A (en) 1996-03-29
EP0781301A1 (fr) 1997-07-02
WO1996008521A1 (fr) 1996-03-21

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Legal Events

Date Code Title Description
FZDC Correction of dead application (reinstatement)
FZDE Dead