CA2200536A1 - 4-acylamidopiperidines dans des combinaisons stabilisatrices pour polymeres chlores - Google Patents

4-acylamidopiperidines dans des combinaisons stabilisatrices pour polymeres chlores

Info

Publication number: CA2200536A1
Authority: CA; Canada
Prior art keywords: tert; butyl; acid; c8alkyl; bis
Prior art date: 1996-03-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002200536A

Other languages

English (en)

Inventor

Horst Zinke

Wolfgang Wehner

Karl Josef Kuhn

Valerio Borzatta

Gerhard Rytz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Galata Chemicals GmbH

Original Assignee

Ciba Spezialitaetenchemie Holding AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-03-22

Filing date

1997-03-20

Publication date

1997-09-22

1997-03-20 Application filed by Ciba Spezialitaetenchemie Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG

1997-09-22 Publication of CA2200536A1 publication Critical patent/CA2200536A1/fr

Status Abandoned legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 58
239000003381 stabilizer Substances 0.000 title claims abstract description 37
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title description 13
239000000460 chlorine Substances 0.000 title description 13
229910052801 chlorine Inorganic materials 0.000 title description 13
-1 zinc carboxylate Chemical class 0.000 claims abstract description 70
150000001875 compounds Chemical class 0.000 claims abstract description 34
229910052736 halogen Inorganic materials 0.000 claims abstract description 12
150000002367 halogens Chemical class 0.000 claims abstract description 12
239000010457 zeolite Substances 0.000 claims description 52
239000000203 mixture Substances 0.000 claims description 51
150000002148 esters Chemical class 0.000 claims description 24
239000011575 calcium Substances 0.000 claims description 15
229910052717 sulfur Inorganic materials 0.000 claims description 12
229910052791 calcium Inorganic materials 0.000 claims description 9
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 8
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
229910052782 aluminium Inorganic materials 0.000 claims description 7
235000014113 dietary fatty acids Nutrition 0.000 claims description 7
239000000194 fatty acid Substances 0.000 claims description 7
229930195729 fatty acid Natural products 0.000 claims description 7
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 7
239000000126 substance Substances 0.000 claims description 7
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 6
239000004411 aluminium Substances 0.000 claims description 6
125000004925 dihydropyridyl group Chemical group N1(CC=CC=C1)* 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
229920005862 polyol Polymers 0.000 claims description 6
229910052760 oxygen Inorganic materials 0.000 claims description 5
150000003077 polyols Chemical class 0.000 claims description 5
230000000087 stabilizing effect Effects 0.000 claims description 5
RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 claims description 4
239000003963 antioxidant agent Substances 0.000 claims description 4
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 4
150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 3
150000001399 aluminium compounds Chemical class 0.000 claims description 3
229940077746 antacid containing aluminium compound Drugs 0.000 claims description 3
150000002118 epoxides Chemical class 0.000 claims description 3
239000004611 light stabiliser Substances 0.000 claims description 3
239000006096 absorbing agent Substances 0.000 claims description 2
150000001339 alkali metal compounds Chemical class 0.000 claims 2
239000011701 zinc Substances 0.000 abstract description 26
229910052725 zinc Inorganic materials 0.000 abstract description 19
229910021536 Zeolite Inorganic materials 0.000 description 38
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 37
239000004800 polyvinyl chloride Substances 0.000 description 22
229920000915 polyvinyl chloride Polymers 0.000 description 22
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 17
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 14
239000011734 sodium Substances 0.000 description 14
229910052700 potassium Inorganic materials 0.000 description 13
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
229910052708 sodium Inorganic materials 0.000 description 12
239000004014 plasticizer Substances 0.000 description 11
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 10
229920001577 copolymer Polymers 0.000 description 10
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 10
239000000654 additive Substances 0.000 description 9
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
229910052783 alkali metal Inorganic materials 0.000 description 8
150000001340 alkali metals Chemical class 0.000 description 8
239000004305 biphenyl Substances 0.000 description 8
235000010290 biphenyl Nutrition 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 8
239000000049 pigment Substances 0.000 description 8
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
229910052784 alkaline earth metal Inorganic materials 0.000 description 7
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
229910052749 magnesium Inorganic materials 0.000 description 7
239000011777 magnesium Substances 0.000 description 7
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 5
BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 5
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
150000001342 alkaline earth metals Chemical class 0.000 description 5
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
229910052744 lithium Inorganic materials 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 5
229940117969 neopentyl glycol Drugs 0.000 description 5
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 5
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
235000019260 propionic acid Nutrition 0.000 description 5
235000013772 propylene glycol Nutrition 0.000 description 5
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 5
229940113165 trimethylolpropane Drugs 0.000 description 5
ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 4
ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 description 4
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
238000000576 coating method Methods 0.000 description 4
229910052681 coesite Inorganic materials 0.000 description 4
229910052906 cristobalite Inorganic materials 0.000 description 4
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
238000009472 formulation Methods 0.000 description 4
239000000314 lubricant Substances 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
150000002815 nickel Chemical class 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
238000012545 processing Methods 0.000 description 4
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
235000012239 silicon dioxide Nutrition 0.000 description 4
229910052682 stishovite Inorganic materials 0.000 description 4
229910052712 strontium Inorganic materials 0.000 description 4
150000005846 sugar alcohols Polymers 0.000 description 4
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
239000011732 tocopherol Substances 0.000 description 4
229910052905 tridymite Inorganic materials 0.000 description 4
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
SQHKJSPPFSVNDF-UHFFFAOYSA-N 1,2,2,3-tetrakis(hydroxymethyl)cyclohexan-1-ol Chemical compound OCC1CCCC(O)(CO)C1(CO)CO SQHKJSPPFSVNDF-UHFFFAOYSA-N 0.000 description 3
YEWBOZCFGXOUQW-UHFFFAOYSA-N 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ylmethanol Chemical compound C1OP2OCC1(CO)CO2 YEWBOZCFGXOUQW-UHFFFAOYSA-N 0.000 description 3
PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical class CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 3
KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 3
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239000007983 Tris buffer Substances 0.000 description 3
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 3
235000006708 antioxidants Nutrition 0.000 description 3
229910052788 barium Inorganic materials 0.000 description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
150000007942 carboxylates Chemical class 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical group CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 3
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239000011707 mineral Substances 0.000 description 3
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150000003839 salts Chemical class 0.000 description 3
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125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
239000008096 xylene Substances 0.000 description 3
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SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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239000011709 vitamin E Substances 0.000 description 1
235000019165 vitamin E Nutrition 0.000 description 1
229940046009 vitamin E Drugs 0.000 description 1
239000010456 wollastonite Substances 0.000 description 1
229910052882 wollastonite Inorganic materials 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
239000011667 zinc carbonate Substances 0.000 description 1
235000004416 zinc carbonate Nutrition 0.000 description 1
229910000010 zinc carbonate Inorganic materials 0.000 description 1
BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1
229960001296 zinc oxide Drugs 0.000 description 1
229910052984 zinc sulfide Inorganic materials 0.000 description 1
IQBAOEIFIGDDCB-UHFFFAOYSA-L zinc;2,2-bis(octylsulfanyl)propanoate Chemical compound [Zn+2].CCCCCCCCSC(C)(C([O-])=O)SCCCCCCCC.CCCCCCCCSC(C)(C([O-])=O)SCCCCCCCC IQBAOEIFIGDDCB-UHFFFAOYSA-L 0.000 description 1
RBEYUVZBFYVXEX-UHFFFAOYSA-L zinc;2-sulfanylacetate Chemical compound [Zn+2].[O-]C(=O)CS.[O-]C(=O)CS RBEYUVZBFYVXEX-UHFFFAOYSA-L 0.000 description 1
JIXJDKNPPOUBJH-UHFFFAOYSA-L zinc;2-sulfanylbenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1S.[O-]C(=O)C1=CC=CC=C1S JIXJDKNPPOUBJH-UHFFFAOYSA-L 0.000 description 1
YCFZZALTCSESPA-UHFFFAOYSA-L zinc;2-sulfanylbutanedioate Chemical compound [Zn+2].[O-]C(=O)CC(S)C([O-])=O YCFZZALTCSESPA-UHFFFAOYSA-L 0.000 description 1
WLVAUUBKRRARBW-UHFFFAOYSA-L zinc;2-sulfanylpropanoate Chemical compound [Zn+2].CC(S)C([O-])=O.CC(S)C([O-])=O WLVAUUBKRRARBW-UHFFFAOYSA-L 0.000 description 1
YMTQMTSQMKJKPX-UHFFFAOYSA-L zinc;diphenoxide Chemical class [Zn+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 YMTQMTSQMKJKPX-UHFFFAOYSA-L 0.000 description 1
PCHQDTOLHOFHHK-UHFFFAOYSA-L zinc;hydrogen carbonate Chemical compound [Zn+2].OC([O-])=O.OC([O-])=O PCHQDTOLHOFHHK-UHFFFAOYSA-L 0.000 description 1
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/138—Phenolates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA002200536A 1996-03-22 1997-03-20 4-acylamidopiperidines dans des combinaisons stabilisatrices pour polymeres chlores Abandoned CA2200536A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH75196		1996-03-22
CH751/96		1996-03-22

Publications (1)

Publication Number	Publication Date
CA2200536A1 true CA2200536A1 (fr)	1997-09-22

Family

ID=4194353

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002200536A Abandoned CA2200536A1 (fr)	1996-03-22	1997-03-20	4-acylamidopiperidines dans des combinaisons stabilisatrices pour polymeres chlores

Country Status (16)

Country	Link
JP (1)	JPH1045983A (fr)
AT (1)	AT413210B (fr)
BE (1)	BE1012198A5 (fr)
BR (1)	BR9701422A (fr)
CA (1)	CA2200536A1 (fr)
DE (1)	DE19711690A1 (fr)
DK (1)	DK29697A (fr)
ES (1)	ES2147078B1 (fr)
FR (1)	FR2746405A1 (fr)
GB (1)	GB2311292B (fr)
IT (1)	IT1290431B1 (fr)
NL (1)	NL1005608C2 (fr)
NO (1)	NO971335L (fr)
SE (1)	SE9701011L (fr)
TW (1)	TW354800B (fr)
ZA (1)	ZA972426B (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19752481A1 (de) *	1997-11-27	1999-06-02	Cit Alcatel	Isoliermaterial auf der Basis von Polyvinylchlorid
JP2000273248A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法
JP2000273254A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法
GB0219260D0 (en) *	2002-08-19	2002-09-25	Clariant Gmbh	Improvements in or relating to organic compounds
WO2009027180A1 (fr)	2007-08-28	2009-03-05	Basf Se	Mélange stabilisant
CN103554009B (zh) *	2013-10-22	2016-05-04	山西省化工研究所（有限公司）	一种尼龙多功能稳定剂的制备方法
CN118812417A (zh) *	2024-06-21	2024-10-22	福建帝盛科技股份有限公司	N,n-双(2,2,6,6-四甲基哌啶基)-1,4-乙二酰胺的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3684765A (en) *	1970-01-08	1972-08-15	Sankyo Co	Stabilization of synthetic polymers
DE59010370D1 (de) *	1989-10-06	1996-07-18	Ciba Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen
EP0432096A1 (fr) *	1989-12-06	1991-06-12	Ciba-Geigy Ag	Composition stabilisée contenant du chlore
EP0446171A3 (en) *	1990-03-08	1992-05-20	Ciba-Geigy Ag	Stabilised chlorinated polymer compositions
EP0488951B1 (fr) *	1990-11-30	1996-09-25	Ciba-Geigy Ag	Polymères chlorés stabilisés
DE59106533D1 (de) *	1990-11-30	1995-10-26	Ciba Geigy Ag	Stabilisierte chlorhaltige Polymere.
US5283273A (en) *	1990-11-30	1994-02-01	Ciba-Geigy Corporation	Stabilized chlorine-containing polymers
EP0570337B1 (fr) *	1992-05-13	1998-03-18	Ciba SC Holding AG	Compositions stabilisées de polymères contenant du chlore
EP0796888B1 (fr) *	1996-03-22	2005-12-14	Wolfgang Wehner	Composition de stabilisateurs pour polymères contenant du chlore

1997
- 1997-03-17 DK DK029697A patent/DK29697A/da not_active Application Discontinuation
- 1997-03-19 SE SE9701011A patent/SE9701011L/xx not_active Application Discontinuation
- 1997-03-20 CA CA002200536A patent/CA2200536A1/fr not_active Abandoned
- 1997-03-20 ZA ZA9702426A patent/ZA972426B/xx unknown
- 1997-03-20 FR FR9703402A patent/FR2746405A1/fr not_active Withdrawn
- 1997-03-20 DE DE19711690A patent/DE19711690A1/de not_active Withdrawn
- 1997-03-21 BE BE9700251A patent/BE1012198A5/fr not_active IP Right Cessation
- 1997-03-21 IT IT97MI000662A patent/IT1290431B1/it active IP Right Grant
- 1997-03-21 ES ES009700618A patent/ES2147078B1/es not_active Expired - Fee Related
- 1997-03-21 TW TW086103573A patent/TW354800B/zh active
- 1997-03-21 GB GB9705846A patent/GB2311292B/en not_active Expired - Fee Related
- 1997-03-21 AT AT0050297A patent/AT413210B/de not_active IP Right Cessation
- 1997-03-21 NO NO971335A patent/NO971335L/no not_active Application Discontinuation
- 1997-03-21 BR BR9701422A patent/BR9701422A/pt not_active Application Discontinuation
- 1997-03-21 NL NL1005608A patent/NL1005608C2/nl not_active IP Right Cessation
- 1997-03-21 JP JP9108012A patent/JPH1045983A/ja active Pending

Also Published As

Publication number	Publication date
ES2147078B1 (es)	2001-04-01
TW354800B (en)	1999-03-21
IT1290431B1 (it)	1998-12-03
SE9701011L (sv)	1997-09-23
GB2311292A (en)	1997-09-24
ZA972426B (en)	1997-09-22
NO971335L (no)	1997-09-23
GB2311292B (en)	2000-10-04
DE19711690A1 (de)	1997-11-06
NL1005608A1 (nl)	1997-09-23
ES2147078A1 (es)	2000-08-16
GB9705846D0 (en)	1997-05-07
SE9701011D0 (sv)	1997-03-19
DK29697A (da)	1997-09-23
BR9701422A (pt)	1998-11-10
BE1012198A5 (fr)	2000-07-04
ITMI970662A1 (it)	1998-09-21
ATA50297A (de)	2005-05-15
JPH1045983A (ja)	1998-02-17
AT413210B (de)	2005-12-15
NL1005608C2 (nl)	2000-05-22
NO971335D0 (no)	1997-03-21
FR2746405A1 (fr)	1997-09-26

Legal Events

Date	Code	Title	Description
2003-03-20	FZDE	Dead

Publication	Publication Date	Title
AU714489B2 (en)	2000-01-06	Stabiliser combinations for chlorine-containing polymers
US6013703A (en)	2000-01-11	Stabilizer combination for chlorine-containing polymers
DE19741777B4 (de)	2010-07-01	Monomere Bisphosphite als Stabilisatoren für halogenhaltige Polymere und für Schmierstoffe
NO309941B1 (no)	2001-04-23	Stabilisert myk-PVC-blanding, dens fremstilling og anvendelse
EP0967209A1 (fr)	1999-12-29	6-aminouraciles modifiés sur le NH2, comme stabilisateurs pour des polymères halogènes
AU748404B2 (en)	2002-06-06	Cyanoacetylureas for stabilizing halogenated polymers
EP1510545A2 (fr)	2005-03-02	6-aminouraciles substitués en 1,3 pour stabiliser des polymères halogénés
EP1569994B1 (fr)	2008-01-09	6-amino-uraciles monosubstitues utilises pour stabiliser des polymeres a base d'halogenes
NO312895B1 (no)	2002-07-15	5-substituerte 6-aminouraciler som stabilisatorer for halogenholdige polymerer, materialer omfattende slike forbindelserog anvendelse av slike forbindelser
CA2200536A1 (fr)	1997-09-22	4-acylamidopiperidines dans des combinaisons stabilisatrices pour polymeres chlores
US5804622A (en)	1998-09-08	Monomeric N-piperidinylmelamines as stabilizers for chlorine-containing polymers
CA2200529A1 (fr)	1997-09-22	Stabilisateurs pour polymeres chlores
GB2345695A (en)	2000-07-19	Stabilizer combinations for halogen-containing polymers
JPH07300544A (ja)	1995-11-14	安定化ハロゲン含有ポリマー
AU2003203242B2 (en)	2004-11-25	Stabiliser combinations for chlorine-containing polymers
AU7257200A (en)	2001-04-05	Stabiliser combinations for chlorine-containing polymers
MXPA99005989A (en)	2000-12-06	6-aminouraciles replaced in position 5 as stabilizers for halogenic polymers
MXPA97007315A (es)	1998-11-12	Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo)