CA2200945C - Procede d'hydro-isomerisation de paraffine - Google Patents
Procede d'hydro-isomerisation de paraffine Download PDFInfo
- Publication number
- CA2200945C CA2200945C CA002200945A CA2200945A CA2200945C CA 2200945 C CA2200945 C CA 2200945C CA 002200945 A CA002200945 A CA 002200945A CA 2200945 A CA2200945 A CA 2200945A CA 2200945 C CA2200945 C CA 2200945C
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- wax
- feed
- dewaxing
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 89
- 230000008569 process Effects 0.000 title claims abstract description 76
- 239000010457 zeolite Substances 0.000 claims abstract description 104
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 85
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 82
- 239000011148 porous material Substances 0.000 claims abstract description 64
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 48
- 239000013078 crystal Substances 0.000 claims abstract description 40
- 239000001257 hydrogen Substances 0.000 claims abstract description 35
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 35
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000314 lubricant Substances 0.000 claims abstract description 25
- 239000002808 molecular sieve Substances 0.000 claims abstract description 21
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 230000003197 catalytic effect Effects 0.000 claims abstract description 19
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 17
- 229910000510 noble metal Inorganic materials 0.000 claims abstract description 17
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims description 162
- 238000006243 chemical reaction Methods 0.000 claims description 52
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 37
- 239000002184 metal Substances 0.000 claims description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 229910052796 boron Inorganic materials 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 210000002683 foot Anatomy 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 150000004706 metal oxides Chemical class 0.000 claims description 6
- 229910052680 mordenite Inorganic materials 0.000 claims description 6
- 239000004264 Petrolatum Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 229940066842 petrolatum Drugs 0.000 claims description 5
- 235000019271 petrolatum Nutrition 0.000 claims description 5
- 238000000638 solvent extraction Methods 0.000 claims description 4
- 239000001993 wax Substances 0.000 description 89
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 44
- 239000000047 product Substances 0.000 description 37
- 239000003921 oil Substances 0.000 description 31
- 238000005336 cracking Methods 0.000 description 18
- 238000009835 boiling Methods 0.000 description 16
- 230000000694 effects Effects 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 15
- 150000002739 metals Chemical class 0.000 description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 11
- 239000011737 fluorine Substances 0.000 description 11
- 229910052731 fluorine Inorganic materials 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 230000007935 neutral effect Effects 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- 238000001179 sorption measurement Methods 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 150000002222 fluorine compounds Chemical class 0.000 description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 6
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 6
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical compound CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 230000001588 bifunctional effect Effects 0.000 description 5
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- 239000002245 particle Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 229910001657 ferrierite group Inorganic materials 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229940116315 oxalic acid Drugs 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000010025 steaming Methods 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000010953 base metal Substances 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 238000007142 ring opening reaction Methods 0.000 description 3
- 238000010561 standard procedure Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- -1 dicarboxylic acid Chemical class 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229940078552 o-xylene Drugs 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 229940075554 sorbate Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- MMZYCBHLNZVROM-UHFFFAOYSA-N 1-fluoro-2-methylbenzene Chemical compound CC1=CC=CC=C1F MMZYCBHLNZVROM-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- YUHQYWMEQKLWSB-UHFFFAOYSA-H [Ni+2].[W+4].[F-].[F-].[F-].[F-].[F-].[F-] Chemical compound [Ni+2].[W+4].[F-].[F-].[F-].[F-].[F-].[F-] YUHQYWMEQKLWSB-UHFFFAOYSA-H 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 229940063013 borate ion Drugs 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- NSNHWTBQMQIDCF-UHFFFAOYSA-N dihydrate;hydrochloride Chemical compound O.O.Cl NSNHWTBQMQIDCF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000013628 high molecular weight specie Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000005300 metallic glass Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910019655 synthetic inorganic crystalline material Inorganic materials 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/38—Chemical modification of petroleum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La présente invention concerne un procédé pour produire un lubrifiant à haut indice de viscosité présentant une viscosité d'au moins 125, à partir d'une charge d'hydrocarbure paraffineux possédant une teneur en paraffine d'au moins 40 % en poids. Ce procédé consiste à déparaffiner par voie catalytique des paraffines cireuses présentes dans la charge, principalement par isomérisation, en présence d'hydrogène et d'un tamis moléculaire de faible acidité en zéolite à pores de grande dimension, présentant une grosseur cristalline inférieure à 0,1 micron, une valeur alpha non supérieure à 30 et contenant un constituant d'hydrogénation en métal précieux. Cette zéolite à pores de grande dimension est de préférence une zéolite béta chargée de 0,3 à 2 % en poids de Tp. La charge peut subir un hydrocraquage avant le déparaffinage avec la zéolite à pores de grande dimension. Les effluents issus de ce procédé peuvent également être déparaffinés davantage par un solvant ou un agent catalytique pour permettre l'obtention du point d'écoulement recherché.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32991494A | 1994-10-27 | 1994-10-27 | |
| US329,914 | 1994-10-27 | ||
| PCT/US1995/012823 WO1996013563A1 (fr) | 1994-10-27 | 1995-10-13 | Procede d'hydro-isomerisation de paraffine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2200945A1 CA2200945A1 (fr) | 1996-05-09 |
| CA2200945C true CA2200945C (fr) | 2006-06-06 |
Family
ID=23287559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002200945A Expired - Fee Related CA2200945C (fr) | 1994-10-27 | 1995-10-13 | Procede d'hydro-isomerisation de paraffine |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0788533B1 (fr) |
| JP (1) | JP3628023B2 (fr) |
| KR (1) | KR100289923B1 (fr) |
| AU (1) | AU698961B2 (fr) |
| CA (1) | CA2200945C (fr) |
| DE (1) | DE69533139T2 (fr) |
| ES (1) | ES2220940T3 (fr) |
| WO (1) | WO1996013563A1 (fr) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6090989A (en) * | 1997-10-20 | 2000-07-18 | Mobil Oil Corporation | Isoparaffinic lube basestock compositions |
| US6663768B1 (en) | 1998-03-06 | 2003-12-16 | Chevron U.S.A. Inc. | Preparing a HGH viscosity index, low branch index dewaxed |
| US6398946B1 (en) | 1999-12-22 | 2002-06-04 | Chevron U.S.A., Inc. | Process for making a lube base stock from a lower molecular weight feedstock |
| US6294077B1 (en) * | 2000-02-02 | 2001-09-25 | Mobil Oil Corporation | Production of high viscosity lubricating oil stock with improved ZSM-5 catalyst |
| US6773578B1 (en) | 2000-12-05 | 2004-08-10 | Chevron U.S.A. Inc. | Process for preparing lubes with high viscosity index values |
| US6652735B2 (en) * | 2001-04-26 | 2003-11-25 | Exxonmobil Research And Engineering Company | Process for isomerization dewaxing of hydrocarbon streams |
| JP4116617B2 (ja) * | 2002-06-28 | 2008-07-09 | ハルドール・トプサー・アクチエゼルスカベット | ゼオライトベータを含む触媒及びそれを炭化水素の転化法に使用する方法 |
| US6846778B2 (en) | 2002-10-08 | 2005-01-25 | Exxonmobil Research And Engineering Company | Synthetic isoparaffinic premium heavy lubricant base stock |
| US7132042B2 (en) | 2002-10-08 | 2006-11-07 | Exxonmobil Research And Engineering Company | Production of fuels and lube oils from fischer-tropsch wax |
| US7344631B2 (en) | 2002-10-08 | 2008-03-18 | Exxonmobil Research And Engineering Company | Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product |
| US7201838B2 (en) | 2002-10-08 | 2007-04-10 | Exxonmobil Research And Engineering Company | Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product |
| US7166756B2 (en) | 2003-02-14 | 2007-01-23 | Exxonmobil Research And Engineering Company | Method for hydrocarbon isomerization |
| US7198710B2 (en) | 2003-03-10 | 2007-04-03 | Chevron U.S.A. Inc. | Isomerization/dehazing process for base oils from Fischer-Tropsch wax |
| US6962651B2 (en) | 2003-03-10 | 2005-11-08 | Chevron U.S.A. Inc. | Method for producing a plurality of lubricant base oils from paraffinic feedstock |
| EP1548088A1 (fr) | 2003-12-23 | 2005-06-29 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'une huile de base non-trouble |
| EP1550709A1 (fr) * | 2003-12-23 | 2005-07-06 | Shell Internationale Researchmaatschappij B.V. | Procédé de preparation d'une huile non-trouble |
| US7345211B2 (en) | 2004-07-08 | 2008-03-18 | Conocophillips Company | Synthetic hydrocarbon products |
| US7906013B2 (en) | 2006-12-29 | 2011-03-15 | Uop Llc | Hydrocarbon conversion process |
| EP2155840B1 (fr) * | 2007-06-13 | 2018-03-21 | ExxonMobil Research and Engineering Company | Hydrotraitement intégré avec des catalyseurs à haute productivité |
| US7803269B2 (en) | 2007-10-15 | 2010-09-28 | Uop Llc | Hydroisomerization process |
| US7740065B2 (en) * | 2007-11-28 | 2010-06-22 | Saudi Arabian Oil Company | Process to upgrade whole crude oil by hot pressurized water and recovery fluid |
| JP5800448B2 (ja) * | 2008-03-25 | 2015-10-28 | Ｊｘ日鉱日石エネルギー株式会社 | 潤滑油基油及びその製造方法並びに潤滑油組成物 |
| US8008534B2 (en) | 2008-06-30 | 2011-08-30 | Uop Llc | Liquid phase hydroprocessing with temperature management |
| US9279087B2 (en) | 2008-06-30 | 2016-03-08 | Uop Llc | Multi-staged hydroprocessing process and system |
| US8999141B2 (en) | 2008-06-30 | 2015-04-07 | Uop Llc | Three-phase hydroprocessing without a recycle gas compressor |
| US8221706B2 (en) | 2009-06-30 | 2012-07-17 | Uop Llc | Apparatus for multi-staged hydroprocessing |
| US8518241B2 (en) | 2009-06-30 | 2013-08-27 | Uop Llc | Method for multi-staged hydroprocessing |
| US9284500B2 (en) | 2013-03-14 | 2016-03-15 | Exxonmobil Research And Engineering Company | Production of base oils from petrolatum |
| CN116064106B (zh) * | 2021-10-31 | 2025-01-28 | 中国石油化工股份有限公司 | 生产高粘度指数润滑油基础油的加氢方法 |
| CN118788380B (zh) * | 2024-06-07 | 2025-11-18 | 太原理工大学 | 一种应用于菲选择性加氢环移异构一步法制对称八氢蒽催化剂 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4983274A (en) * | 1986-12-04 | 1991-01-08 | Mobil Oil Corp. | Shape selective crystalline silicate zeolite containing intermetallic component and use as catalyst in hydrocarbon conversions |
| US4851109A (en) * | 1987-02-26 | 1989-07-25 | Mobil Oil Corporation | Integrated hydroprocessing scheme for production of premium quality distillates and lubricants |
| US5282958A (en) * | 1990-07-20 | 1994-02-01 | Chevron Research And Technology Company | Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons |
| US5275719A (en) * | 1992-06-08 | 1994-01-04 | Mobil Oil Corporation | Production of high viscosity index lubricants |
| US5362378A (en) * | 1992-12-17 | 1994-11-08 | Mobil Oil Corporation | Conversion of Fischer-Tropsch heavy end products with platinum/boron-zeolite beta catalyst having a low alpha value |
| US5302279A (en) * | 1992-12-23 | 1994-04-12 | Mobil Oil Corporation | Lubricant production by hydroisomerization of solvent extracted feedstocks |
-
1995
- 1995-10-13 CA CA002200945A patent/CA2200945C/fr not_active Expired - Fee Related
- 1995-10-13 AU AU37633/95A patent/AU698961B2/en not_active Ceased
- 1995-10-13 WO PCT/US1995/012823 patent/WO1996013563A1/fr not_active Ceased
- 1995-10-13 KR KR1019970702702A patent/KR100289923B1/ko not_active Expired - Lifetime
- 1995-10-13 ES ES95935723T patent/ES2220940T3/es not_active Expired - Lifetime
- 1995-10-13 EP EP95935723A patent/EP0788533B1/fr not_active Expired - Lifetime
- 1995-10-13 DE DE69533139T patent/DE69533139T2/de not_active Expired - Lifetime
- 1995-10-13 JP JP51459796A patent/JP3628023B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0788533A1 (fr) | 1997-08-13 |
| AU3763395A (en) | 1996-05-23 |
| WO1996013563A1 (fr) | 1996-05-09 |
| KR970707260A (ko) | 1997-12-01 |
| DE69533139T2 (de) | 2004-09-30 |
| KR100289923B1 (ko) | 2001-05-15 |
| CA2200945A1 (fr) | 1996-05-09 |
| AU698961B2 (en) | 1998-11-12 |
| JP3628023B2 (ja) | 2005-03-09 |
| DE69533139D1 (de) | 2004-07-15 |
| EP0788533B1 (fr) | 2004-06-09 |
| EP0788533A4 (fr) | 1998-08-05 |
| JPH10508058A (ja) | 1998-08-04 |
| ES2220940T3 (es) | 2004-12-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |