CA2201165C - Utilisation d'humates et d'humates modifies comme adjuvants dans les pesticides - Google Patents

Utilisation d'humates et d'humates modifies comme adjuvants dans les pesticides Download PDF

Info

Publication number: CA2201165C
Authority: CA; Canada
Prior art keywords: humate; pesticide; modified; humates; bisulfite
Prior art date: 1996-03-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 2201165

Other languages

English (en)

Other versions

CA2201165A1 (fr

Inventor

Stuart E. Lebo, Jr.

Kevin R. Wirtz

Stephen L. Dickman

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ligno Tech USA

Original Assignee

Ligno Tech USA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-03-28

Filing date

1997-03-26

Publication date

2001-04-24

1997-03-26 Application filed by Ligno Tech USA filed Critical Ligno Tech USA

1997-09-28 Publication of CA2201165A1 publication Critical patent/CA2201165A1/fr

2001-04-24 Application granted granted Critical

2001-04-24 Publication of CA2201165C publication Critical patent/CA2201165C/fr

2017-03-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000575 pesticide Substances 0.000 title claims abstract description 50
239000002671 adjuvant Substances 0.000 title abstract description 33
238000000034 method Methods 0.000 claims abstract description 38
239000000203 mixture Substances 0.000 claims abstract description 15
239000003513 alkali Substances 0.000 claims description 15
238000007254 oxidation reaction Methods 0.000 claims description 15
239000002917 insecticide Substances 0.000 claims description 14
230000003647 oxidation Effects 0.000 claims description 14
238000000605 extraction Methods 0.000 claims description 12
230000001590 oxidative effect Effects 0.000 claims description 12
238000006243 chemical reaction Methods 0.000 claims description 11
239000003245 coal Substances 0.000 claims description 11
241000193830 Bacillus <bacterium> Species 0.000 claims description 8
230000015556 catabolic process Effects 0.000 claims description 8
238000006731 degradation reaction Methods 0.000 claims description 8
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 8
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 6
239000003077 lignite Substances 0.000 claims description 6
238000006277 sulfonation reaction Methods 0.000 claims description 6
241000701451 unidentified granulovirus Species 0.000 claims description 5
235000010265 sodium sulphite Nutrition 0.000 claims description 4
230000003612 virological effect Effects 0.000 claims description 4
239000005660 Abamectin Substances 0.000 claims description 3
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 3
230000000895 acaricidal effect Effects 0.000 claims description 3
239000000642 acaricide Substances 0.000 claims description 3
VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims description 3
239000002802 bituminous coal Substances 0.000 claims description 3
230000000855 fungicidal effect Effects 0.000 claims description 3
239000000417 fungicide Substances 0.000 claims description 3
230000002363 herbicidal effect Effects 0.000 claims description 3
239000004009 herbicide Substances 0.000 claims description 3
239000003415 peat Substances 0.000 claims description 3
150000003217 pyrazoles Chemical class 0.000 claims description 3
235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 3
AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 claims description 2
241000193388 Bacillus thuringiensis Species 0.000 claims description 2
241000193386 Lysinibacillus sphaericus Species 0.000 claims description 2
229940097012 bacillus thuringiensis Drugs 0.000 claims description 2
150000004657 carbamic acid derivatives Chemical class 0.000 claims description 2
PCAXGMRPPOMODZ-UHFFFAOYSA-N disulfurous acid, diammonium salt Chemical compound [NH4+].[NH4+].[O-]S(=O)S([O-])(=O)=O PCAXGMRPPOMODZ-UHFFFAOYSA-N 0.000 claims description 2
230000002538 fungal effect Effects 0.000 claims description 2
239000002949 juvenile hormone Substances 0.000 claims description 2
DMRNCUCPRIKSTR-UHFFFAOYSA-L magnesium metabisulfite Chemical compound [Mg+2].[O-]S(=O)S([O-])(=O)=O DMRNCUCPRIKSTR-UHFFFAOYSA-L 0.000 claims description 2
LPHFLPKXBKBHRW-UHFFFAOYSA-L magnesium;hydrogen sulfite Chemical compound [Mg+2].OS([O-])=O.OS([O-])=O LPHFLPKXBKBHRW-UHFFFAOYSA-L 0.000 claims description 2
DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 claims description 2
229940099427 potassium bisulfite Drugs 0.000 claims description 2
235000010259 potassium hydrogen sulphite Nutrition 0.000 claims description 2
RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 claims description 2
229940043349 potassium metabisulfite Drugs 0.000 claims description 2
235000010263 potassium metabisulphite Nutrition 0.000 claims description 2
HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 2
229940001584 sodium metabisulfite Drugs 0.000 claims description 2
235000010262 sodium metabisulphite Nutrition 0.000 claims description 2
230000000087 stabilizing effect Effects 0.000 claims 1
230000000853 biopesticidal effect Effects 0.000 abstract description 7
230000000694 effects Effects 0.000 abstract description 6
238000009472 formulation Methods 0.000 abstract description 5
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
239000004021 humic acid Substances 0.000 description 19
QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical group C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 16
239000011541 reaction mixture Substances 0.000 description 13
241000701366 unidentified nuclear polyhedrosis viruses Species 0.000 description 11
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 9
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
239000001301 oxygen Substances 0.000 description 9
229910052760 oxygen Inorganic materials 0.000 description 9
239000003570 air Substances 0.000 description 8
235000011121 sodium hydroxide Nutrition 0.000 description 8
239000012141 concentrate Substances 0.000 description 6
239000007800 oxidant agent Substances 0.000 description 6
239000002245 particle Substances 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000002835 absorbance Methods 0.000 description 5
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
241001147758 Bacillus thuringiensis serovar kurstaki Species 0.000 description 4
239000000908 ammonium hydroxide Substances 0.000 description 4
238000001228 spectrum Methods 0.000 description 4
241000196324 Embryophyta Species 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
239000000284 extract Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
229960000490 permethrin Drugs 0.000 description 3
RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
239000002002 slurry Substances 0.000 description 3
241000701447 unidentified baculovirus Species 0.000 description 3
241000193363 Bacillus thuringiensis serovar aizawai Species 0.000 description 2
241000193369 Bacillus thuringiensis serovar tenebrionis Species 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
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238000001914 filtration Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
230000002401 inhibitory effect Effects 0.000 description 2
238000002955 isolation Methods 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
150000004053 quinones Chemical class 0.000 description 2
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239000002904 solvent Substances 0.000 description 2
238000004611 spectroscopical analysis Methods 0.000 description 2
239000007921 spray Substances 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000003053 toxin Substances 0.000 description 2
231100000765 toxin Toxicity 0.000 description 2
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
241000566553 Anagrapha falcifera Species 0.000 description 1
241001367049 Autographa Species 0.000 description 1
241000193365 Bacillus thuringiensis serovar israelensis Species 0.000 description 1
241000751139 Beauveria bassiana Species 0.000 description 1
241000537222 Betabaculovirus Species 0.000 description 1
KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical group NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
241000218631 Coniferophyta Species 0.000 description 1
241001266001 Cordyceps confragosa Species 0.000 description 1
240000008067 Cucumis sativus Species 0.000 description 1
235000009849 Cucumis sativus Nutrition 0.000 description 1
241001135545 Cydia pomonella granulovirus Species 0.000 description 1
241000233866 Fungi Species 0.000 description 1
241001352379 Harrisina Species 0.000 description 1
241000255967 Helicoverpa zea Species 0.000 description 1
229920001732 Lignosulfonate Polymers 0.000 description 1
241000721703 Lymantria dispar Species 0.000 description 1
244000141359 Malus pumila Species 0.000 description 1
241000223250 Metarhizium anisopliae Species 0.000 description 1
241001059820 Neodiprion lecontei nucleopolyhedrovirus Species 0.000 description 1
241000157040 Neodiprion sertifer nucleopolyhedrovirus Species 0.000 description 1
241001236817 Paecilomyces <Clavicipitaceae> Species 0.000 description 1
241000497111 Paralobesia viteana Species 0.000 description 1
244000046052 Phaseolus vulgaris Species 0.000 description 1
235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
241000255969 Pieris brassicae Species 0.000 description 1
241000907661 Pieris rapae Species 0.000 description 1
235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
235000011613 Pinus brutia Nutrition 0.000 description 1
241000018646 Pinus brutia Species 0.000 description 1
244000061456 Solanum tuberosum Species 0.000 description 1
235000002595 Solanum tuberosum Nutrition 0.000 description 1
241000256247 Spodoptera exigua Species 0.000 description 1
240000004460 Tanacetum coccineum Species 0.000 description 1
235000021307 Triticum Nutrition 0.000 description 1
244000098338 Triticum aestivum Species 0.000 description 1
ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
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239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
235000006708 antioxidants Nutrition 0.000 description 1
235000021016 apples Nutrition 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000005667 attractant Substances 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
239000003518 caustics Substances 0.000 description 1
235000013339 cereals Nutrition 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
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235000013399 edible fruits Nutrition 0.000 description 1
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239000007792 gaseous phase Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000002655 kraft paper Substances 0.000 description 1
235000021374 legumes Nutrition 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
229910052808 lithium carbonate Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
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238000006552 photochemical reaction Methods 0.000 description 1
235000021039 pomes Nutrition 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
229940015367 pyrethrum Drugs 0.000 description 1
239000005297 pyrex Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000012216 screening Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Landscapes

Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Agronomy & Crop Science (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Toxicology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CA 2201165 1996-03-28 1997-03-26 Utilisation d'humates et d'humates modifies comme adjuvants dans les pesticides Expired - Fee Related CA2201165C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US62299596A	1996-03-28	1996-03-28
US08/622,995		1996-03-28

Publications (2)

Publication Number	Publication Date
CA2201165A1 CA2201165A1 (fr)	1997-09-28
CA2201165C true CA2201165C (fr)	2001-04-24

Family

ID=24496360

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2201165 Expired - Fee Related CA2201165C (fr)	1996-03-28	1997-03-26	Utilisation d'humates et d'humates modifies comme adjuvants dans les pesticides

Country Status (3)

Country	Link
CA (1)	CA2201165C (fr)
DE (1)	DE19713129B4 (fr)
FR (1)	FR2746592B1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20080167374A1 (en) *	2007-01-09	2008-07-10	Loveland Products, Inc.	Pesticide composition and method of use
BR112022015264A2 (pt) *	2020-02-05	2022-09-20	Dow Global Technologies Llc	Formulação pesticida
EP4518655A1 (fr) *	2022-05-31	2025-03-12	Dow Global Technologies LLC	Compositions de lutte contre les nuisibles
JP2025517913A (ja) *	2022-05-31	2025-06-12	ダウグローバルテクノロジーズエルエルシー	有害生物防除組成物
JP2025517926A (ja) *	2022-05-31	2025-06-12	ダウグローバルテクノロジーズエルエルシー	有害生物防除組成物
CN119325980A (zh) *	2024-12-23	2025-01-21	山东百农思达生物科技有限公司	一种基于苯醚甲环唑的缓释型混配制剂以及制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS60180589A (ja) *	1984-02-27	1985-09-14	Sumitomo Ringyo Kk	植物病原菌防除活性のある固定化微生物複合体の製造法
DE4318210C2 (de) *	1993-06-01	1997-09-18	Chembico Chemisch Biolog Praep	Verwendung von Huminstoffen als Lichtschutzmittel in der Biotechnologie und in der Landwirtschaft

1997
- 1997-03-26 CA CA 2201165 patent/CA2201165C/fr not_active Expired - Fee Related
- 1997-03-26 FR FR9703692A patent/FR2746592B1/fr not_active Expired - Fee Related
- 1997-03-27 DE DE1997113129 patent/DE19713129B4/de not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2201165A1 (fr)	1997-09-28
FR2746592A1 (fr)	1997-10-03
MX9702218A (es)	1997-09-30
DE19713129A1 (de)	1997-10-02
FR2746592B1 (fr)	2001-08-10
DE19713129B4 (de)	2006-08-24

Legal Events

Date	Code	Title	Description
1997-10-21	EEER	Examination request
2009-03-26	MKLA	Lapsed

Publication	Publication Date	Title
AU2022200285B2 (en)	2023-12-14	Antifungal Paenibacillus strains, fusaricidin-type compounds, and their use
Isensee et al.	1971	Absorption and translocation of root and foliage applied to 2, 4-dichlorophenol, 2, 7-dichlorodibenzo-p-dioxin, and 2, 3, 7, 8-tetrachlorodibenzo-p-dioxin
CA1182303A (fr)	1985-02-12	Compositions a base d'alcali-lignine diminuant la phytotoxicite des pesticides
US4695462A (en)	1987-09-22	Cellular encapsulation of biological pesticides
CA2396655C (fr)	2013-02-26	Traitement de semences et/ou de plantes au moyen d'une culture de pseudomonas
Wicklow et al.	1988	Sclerotial metabolites of Aspergillus flavus toxic to a detritivorous maize insect (Carpophilus hemipterus, Nitidulidae)
US5750126A (en)	1998-05-12	Labile insecticide compositions
CA2201165C (fr)	2001-04-24	Utilisation d'humates et d'humates modifies comme adjuvants dans les pesticides
RO120446B1 (ro)	2006-02-28	Microcapsulă conţinând compuşi biologic activi
JPS61181372A (ja)	1986-08-14	或る種の鱗翅類害虫に対して改良された活性を有するバチルス・スリンギエンシスの株の製法及びそれにより製造された新規株
US5856526A (en)	1999-01-05	Pesticidal dry powder formulation enriched in azadirachtin up to 88% an emulsifiable concentrate enriched up to 30% of azadirachtin and a process for preparing such formulation and concentrate from neem seed/kernel
CN109964940A (zh)	2019-07-05	一种杀螨组合物及其制剂、杀螨组合物和制剂的应用
US6733802B1 (en)	2004-05-11	Natural azadirachtin composition
FR2684519A1 (fr)	1993-06-11	Association d'un fongicide de la famille des triazoles et d'imidacloprid.
Warrior et al.	2002	Formulation of biological control agents for pest and disease management
JP3798017B2 (ja)	2006-07-19	新規の双翅類活性化合物及びバチルスチューリングエンシス株
CA2190655A1 (fr)	1995-12-14	Procede de preparation de pesticides biologiques ameliores
MXPA97002218A (en)	1998-07-03	Use of humats and humats modified as coadyuvants in pesticide
EP1306008A1 (fr)	2003-05-02	Composition pour le traitement contre les larves de moustiques et procédé pour sa fabrication
PADILLA et al.	2002	EVALUATION OF POLYMER-BASED GRANULAR FORMULATIONS OF BACILLUS THURINGJENSIS ISRAELENSIS AGAINST LARVAL AEDES AEGYPTI IN THE LABORATORY
US5516514A (en)	1996-05-14	Insect controlling agent from strains of Bacillus thuringiensis var. Kurstaki
JPH0729896B2 (ja)	1995-04-05	ニーム油脂肪酸蒸留残渣ベース殺虫剤及びその製造方法
EP0028611A1 (fr)	1981-05-20	Technique pour ameliorer le rendement de produits chimiques dans le domaine des plantes
US7494662B2 (en)	2009-02-24	Oil soluble photoprotective compounds and compositions from plant oil processing
US3860411A (en)	1975-01-14	Sugar production