CA2203388C - Procede et catalyseur d'hydrogenation directe d'esters carboxyliques - Google Patents

Procede et catalyseur d'hydrogenation directe d'esters carboxyliques Download PDF

Info

Publication number
CA2203388C
CA2203388C CA002203388A CA2203388A CA2203388C CA 2203388 C CA2203388 C CA 2203388C CA 002203388 A CA002203388 A CA 002203388A CA 2203388 A CA2203388 A CA 2203388A CA 2203388 C CA2203388 C CA 2203388C
Authority
CA
Canada
Prior art keywords
catalyst
range
temperature
rare earth
copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002203388A
Other languages
English (en)
Other versions
CA2203388A1 (fr
Inventor
Brendan Dermot Murray
David Michael Singleton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Canada Ltd
Original Assignee
Shell Canada Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/335,021 external-priority patent/US5475160A/en
Priority claimed from US08/335,024 external-priority patent/US5463143A/en
Priority claimed from US08/335,018 external-priority patent/US5475159A/en
Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd
Priority claimed from PCT/EP1995/004380 external-priority patent/WO1996014280A1/fr
Publication of CA2203388A1 publication Critical patent/CA2203388A1/fr
Application granted granted Critical
Publication of CA2203388C publication Critical patent/CA2203388C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention se rapporte à un catalyseur d'hydrogénation directe d'esters carboxyliques et au procédé consistant à mettre en contact et à faire réagir au moins un ester avec de l'hydrogène dans des conditions d'hydrogénation à phase liquide prédominante en présence d'un catalyseur comprenant un composé de cuivre, un composé de zinc et au moins un composé sélectionné dans le groupe constitué d'aluminium, zirconium, magnésium, terres rares et de mélanges de ceux-ci. On prépare ce catalyseur en calcinant ces composés à une température comprise entre 200 et 400 DEG C.
CA002203388A 1994-11-07 1995-11-06 Procede et catalyseur d'hydrogenation directe d'esters carboxyliques Expired - Fee Related CA2203388C (fr)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US08/335,021 1994-11-07
US08/335,021 US5475160A (en) 1994-11-07 1994-11-07 Process for the direct hydrogenation of triglycerides
US08/335,024 US5463143A (en) 1994-11-07 1994-11-07 Process for the direct hydrogenation of wax esters
US08/335,018 1994-11-07
US08/335,018 US5475159A (en) 1994-11-07 1994-11-07 Process for the direct hydrogenation of methyl esters
US08/335,024 1994-11-07
PCT/EP1995/004380 WO1996014280A1 (fr) 1994-11-07 1995-11-06 Procede et catalyseur d'hydrogenation directe d'esters carboxyliques

Publications (2)

Publication Number Publication Date
CA2203388A1 CA2203388A1 (fr) 1996-05-17
CA2203388C true CA2203388C (fr) 2006-10-03

Family

ID=37101746

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002203388A Expired - Fee Related CA2203388C (fr) 1994-11-07 1995-11-06 Procede et catalyseur d'hydrogenation directe d'esters carboxyliques

Country Status (1)

Country Link
CA (1) CA2203388C (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116943667B (zh) * 2023-06-26 2025-08-19 浙江恒逸石化研究院有限公司 一种CuMgScO类水滑石催化剂及其制备方法、应用

Also Published As

Publication number Publication date
CA2203388A1 (fr) 1996-05-17

Similar Documents

Publication Publication Date Title
US5475160A (en) Process for the direct hydrogenation of triglycerides
US5475159A (en) Process for the direct hydrogenation of methyl esters
US5463143A (en) Process for the direct hydrogenation of wax esters
EP0804396B1 (fr) Procede d'hydrogenation directe d'esters carboxyliques
KR100296811B1 (ko) 촉매조성물을사용하여카복실산에스테르를수소화시키는방법
EP0198682B1 (fr) Production d'alcools par hydrogénation d'acides carboxyliques
US5616817A (en) Preparation of 1,2-propanediol
EP0456754B1 (fr) Hydrogenation d'esters d'acide carboxylique
EP0296734B1 (fr) Catalyseur en cuivre pour la conversion de l'oxyde de carbone
US4918248A (en) Process for preparation of alcohols
EP0175558A1 (fr) Procédé d'hydrogénation en phase gazeuse d'acides carboxyliques en esters et alcools
US5554574A (en) Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol
US5658843A (en) Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol
US4361711A (en) Alcohols from olefins and synthesis gas
EP0567347A1 (fr) Catalyseur d'hydrogénation, procédé pour sa préparation et procédé pour l'utilisation de ce catalyseur
GB2150560A (en) Production of alcohols by hydrogenolysis of esters
CA2203388C (fr) Procede et catalyseur d'hydrogenation directe d'esters carboxyliques
US4614728A (en) Catalyst composition for producing ethylene glycol and process for producing the catalyst composition
US5536889A (en) Process for the two-stage hydrogenation of methyl esters
CA2090770C (fr) Methode de preparation d'alcools ou d'amines
US5206203A (en) Acid-resistant copper oxide-chromium oxide catalyst for the hydrogenation of fatty acids and fatty esters
US5011806A (en) Catalyst composition for the hydrogenation of carboxylic acid esters
US5250713A (en) Process for producing desulfurized fats and oils or fatty acid esters and process for producing alcohols by using said desulfurized fats and oils or fatty acid esters
JP2989704B2 (ja) 脱硫された油脂又は脂肪酸エステルの製造方法
US6683225B2 (en) Oxidic aluminum/zinc catalysts and a process of producing unsaturated fatty alcohols

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20131106