CA2243288A1 - Methode pour fabriquer des polyamides a apparence metallique a l'aide d'un developpement de couleur et un brillant ameliores - Google Patents

Methode pour fabriquer des polyamides a apparence metallique a l'aide d'un developpement de couleur et un brillant ameliores Download PDF

Info

Publication number: CA2243288A1
Authority: CA; Canada
Prior art keywords: metallic; nylon; effect; process according; nylon material
Prior art date: 1997-10-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2243288

Other languages

English (en)

Inventor

James M. Hurley

Timothy M. Young

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Corp

Original Assignee

BASF Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-10-27

Filing date

1998-09-02

Publication date

1999-04-27

1998-09-02 Application filed by BASF Corp filed Critical BASF Corp

1999-04-27 Publication of CA2243288A1 publication Critical patent/CA2243288A1/fr

Status Abandoned legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 56
239000004952 Polyamide Substances 0.000 title description 23
229920002647 polyamide Polymers 0.000 title description 23
238000011161 development Methods 0.000 title description 2
239000000049 pigment Substances 0.000 claims abstract description 99
229920001778 nylon Polymers 0.000 claims abstract description 72
239000000463 material Substances 0.000 claims abstract description 71
239000004677 Nylon Substances 0.000 claims abstract description 66
239000000203 mixture Substances 0.000 claims abstract description 28
230000008569 process Effects 0.000 claims abstract description 22
239000012744 reinforcing agent Substances 0.000 claims description 28
239000000835 fiber Substances 0.000 claims description 21
229910052500 inorganic mineral Inorganic materials 0.000 claims description 18
239000011707 mineral Substances 0.000 claims description 18
229910052751 metal Inorganic materials 0.000 claims description 15
239000002184 metal Substances 0.000 claims description 15
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XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
239000011574 phosphorus Substances 0.000 claims description 10
229910052698 phosphorus Inorganic materials 0.000 claims description 10
239000002253 acid Substances 0.000 claims description 9
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150000002989 phenols Chemical class 0.000 claims description 8
229910052618 mica group Inorganic materials 0.000 claims description 7
238000000465 moulding Methods 0.000 claims description 7
ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 6
239000010456 wollastonite Substances 0.000 claims description 6
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VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 4
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229910001379 sodium hypophosphite Inorganic materials 0.000 description 3
WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 description 2
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
239000004609 Impact Modifier Substances 0.000 description 2
OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 2
229920000299 Nylon 12 Polymers 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
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XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
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239000002585 base Substances 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
239000010974 bronze Substances 0.000 description 2
239000004917 carbon fiber Substances 0.000 description 2
YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
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QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000010439 graphite Substances 0.000 description 2
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IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
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NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
238000004898 kneading Methods 0.000 description 2
150000003951 lactams Chemical class 0.000 description 2
239000004611 light stabiliser Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
HYLDLLCHFLSKAG-UHFFFAOYSA-M lissamine flavine FF Chemical compound [Na+].C1=CC(C)=CC=C1N(C1=O)C(=O)C2=C3C1=CC=CC3=C(N)C(S([O-])(=O)=O)=C2 HYLDLLCHFLSKAG-UHFFFAOYSA-M 0.000 description 2
239000007769 metal material Substances 0.000 description 2
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239000012170 montan wax Substances 0.000 description 2
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AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
239000011527 polyurethane coating Substances 0.000 description 2
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PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
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HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
230000000007 visual effect Effects 0.000 description 2
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QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
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229960003351 prussian blue Drugs 0.000 description 1
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TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 1
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150000004756 silanes Chemical class 0.000 description 1
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229910010271 silicon carbide Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000012748 slip agent Substances 0.000 description 1
BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 1
239000000243 solution Substances 0.000 description 1
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239000010959 steel Substances 0.000 description 1
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229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
239000003784 tall oil Substances 0.000 description 1
150000003504 terephthalic acids Chemical class 0.000 description 1
CNALVHVMBXLLIY-IUCAKERBSA-N tert-butyl n-[(3s,5s)-5-methylpiperidin-3-yl]carbamate Chemical compound C[C@@H]1CNC[C@@H](NC(=O)OC(C)(C)C)C1 CNALVHVMBXLLIY-IUCAKERBSA-N 0.000 description 1
ZXQVPEBHZMCRMC-UHFFFAOYSA-R tetraazanium;iron(2+);hexacyanide Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] ZXQVPEBHZMCRMC-UHFFFAOYSA-R 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
238000001721 transfer moulding Methods 0.000 description 1
AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
SRJILAWEMJPPCW-UHFFFAOYSA-N tris(4-decylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCCC)C=C1 SRJILAWEMJPPCW-UHFFFAOYSA-N 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
239000012178 vegetable wax Substances 0.000 description 1
239000003981 vehicle Substances 0.000 description 1
LLWJPGAKXJBKKA-UHFFFAOYSA-N victoria blue B Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C(C=C1)C2=CC=CC=C2C1=[NH+]C1=CC=CC=C1 LLWJPGAKXJBKKA-UHFFFAOYSA-N 0.000 description 1
235000012431 wafers Nutrition 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000001018 xanthene dye Substances 0.000 description 1
239000001052 yellow pigment Substances 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA 2243288 1997-10-27 1998-09-02 Methode pour fabriquer des polyamides a apparence metallique a l'aide d'un developpement de couleur et un brillant ameliores Abandoned CA2243288A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US95880197A	1997-10-27	1997-10-27
US08/958,801		1997-10-27

Publications (1)

Publication Number	Publication Date
CA2243288A1 true CA2243288A1 (fr)	1999-04-27

Family

ID=25501318

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2243288 Abandoned CA2243288A1 (fr)	1997-10-27	1998-09-02	Methode pour fabriquer des polyamides a apparence metallique a l'aide d'un developpement de couleur et un brillant ameliores

Country Status (1)

Country	Link
CA (1)	CA2243288A1 (fr)

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WO2000055401A1 (fr) *	1999-03-12	2000-09-21	E.I. Du Pont De Nemours And Company	Filaments scintillants utilises dans les brosses
WO2006125036A3 (fr) *	2005-05-17	2008-07-03	Exxonmobil Res & Eng Co	Compositions de polypropylene renforcees par des fibres et leur procede de fabrication
US7479523B2 (en) *	2001-11-08	2009-01-20	Martin Paul	Metallic-colored thermoplastic molding compound
CN104804416A (zh) *	2015-03-17	2015-07-29	南京利华工程塑料有限公司	彩色耐光老化玻纤增强聚酰胺及其制备方法
CN109735099A (zh) *	2018-12-27	2019-05-10	会通新材料(上海)有限公司	一种改善耐光老化特性的聚酰胺56组合物及其应用
CN110204890A (zh) *	2019-06-27	2019-09-06	金旸（厦门）新材料科技有限公司	一种开孔降噪耐热聚酰胺材料及其制备方法和应用
GB2573403A (en) *	2018-05-03	2019-11-06	Si Group Switzerland Chaa Gmbh	Antidegradant blend
EP3875532A4 (fr) *	2018-10-31	2022-01-05	Unitika Ltd.	Granule de résine thermoplastique à ton métallique
US11608423B2 (en)	2016-01-21	2023-03-21	Ticona Llc	Polyamide composition containing a metallic pigment

1998
- 1998-09-02 CA CA 2243288 patent/CA2243288A1/fr not_active Abandoned

Cited By (18)

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