CA2277678C - Elimination des nox de gaz contenant du dioxyde de soufre - Google Patents

Elimination des nox de gaz contenant du dioxyde de soufre Download PDF

Info

Publication number: CA2277678C
Authority: CA; Canada
Prior art keywords: concentration; catalyst; gas; stream; sulfuric acid
Prior art date: 1999-07-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 2277678

Other languages

English (en)

Other versions

CA2277678A1 (fr

Inventor

Graeme W. Norval

Drew J. Drexler

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Aker Solutions Canada Inc

Original Assignee

Kvaerner Chemetics Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-07-19

Filing date

1999-07-19

Publication date

2008-05-06

1999-07-19 Application filed by Kvaerner Chemetics Inc filed Critical Kvaerner Chemetics Inc

1999-07-19 Priority to CA 2277678 priority Critical patent/CA2277678C/fr

2001-01-19 Publication of CA2277678A1 publication Critical patent/CA2277678A1/fr

2008-05-06 Application granted granted Critical

2008-05-06 Publication of CA2277678C publication Critical patent/CA2277678C/fr

2019-07-19 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title claims abstract description 188
239000007789 gas Substances 0.000 title claims description 129
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 113
239000003054 catalyst Substances 0.000 claims abstract description 88
238000000034 method Methods 0.000 claims abstract description 73
230000008569 process Effects 0.000 claims abstract description 69
239000003638 chemical reducing agent Substances 0.000 claims abstract description 49
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims abstract description 44
238000007254 oxidation reaction Methods 0.000 claims abstract description 30
230000003197 catalytic effect Effects 0.000 claims abstract description 29
230000003647 oxidation Effects 0.000 claims abstract description 29
230000009467 reduction Effects 0.000 claims abstract description 14
230000000694 effects Effects 0.000 claims abstract description 5
230000001590 oxidative effect Effects 0.000 claims abstract description 5
230000006872 improvement Effects 0.000 claims abstract description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 105
229910052720 vanadium Inorganic materials 0.000 claims description 39
229910021529 ammonia Inorganic materials 0.000 claims description 29
238000010521 absorption reaction Methods 0.000 claims description 28
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
239000004202 carbamide Substances 0.000 claims description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
229910052760 oxygen Inorganic materials 0.000 claims description 4
239000001301 oxygen Substances 0.000 claims description 4
229910044991 metal oxide Inorganic materials 0.000 claims description 3
150000004706 metal oxides Chemical class 0.000 claims description 3
229910052697 platinum Inorganic materials 0.000 claims description 3
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 1
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 1
RXQNKKRGJJRMKD-UHFFFAOYSA-N 5-bromo-2-methylaniline Chemical compound CC1=CC=C(Br)C=C1N RXQNKKRGJJRMKD-UHFFFAOYSA-N 0.000 abstract description 9
238000011109 contamination Methods 0.000 abstract description 2
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 120
229910000069 nitrogen hydride Inorganic materials 0.000 description 23
238000004519 manufacturing process Methods 0.000 description 18
239000000047 product Substances 0.000 description 16
239000002253 acid Substances 0.000 description 13
238000006722 reduction reaction Methods 0.000 description 12
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 10
239000003595 mist Substances 0.000 description 10
239000000243 solution Substances 0.000 description 10
238000007792 addition Methods 0.000 description 8
238000004458 analytical method Methods 0.000 description 8
230000006378 damage Effects 0.000 description 8
-1 for example Chemical compound 0.000 description 8
239000000203 mixture Substances 0.000 description 8
238000002156 mixing Methods 0.000 description 7
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
238000012986 modification Methods 0.000 description 6
230000004048 modification Effects 0.000 description 6
238000010790 dilution Methods 0.000 description 5
239000012895 dilution Substances 0.000 description 5
230000009977 dual effect Effects 0.000 description 5
239000003546 flue gas Substances 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
239000010457 zeolite Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 3
235000011149 sulphuric acid Nutrition 0.000 description 3
238000005406 washing Methods 0.000 description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
239000001099 ammonium carbonate Substances 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
238000010531 catalytic reduction reaction Methods 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000008246 gaseous mixture Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
238000011084 recovery Methods 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
RWFBQHICRCUQJJ-NUHJPDEHSA-N (S)-nicotine N(1')-oxide Chemical compound C[N+]1([O-])CCC[C@H]1C1=CC=CN=C1 RWFBQHICRCUQJJ-NUHJPDEHSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
238000003723 Smelting Methods 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
235000012538 ammonium bicarbonate Nutrition 0.000 description 1
235000012501 ammonium carbonate Nutrition 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
238000004042 decolorization Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000007590 electrostatic spraying Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229910001657 ferrierite group Inorganic materials 0.000 description 1
238000007429 general method Methods 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000005297 pyrex Substances 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000004044 response Effects 0.000 description 1
238000012552 review Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
229910052815 sulfur oxide Inorganic materials 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000003053 toxin Substances 0.000 description 1
231100000765 toxin Toxicity 0.000 description 1
238000012546 transfer Methods 0.000 description 1
239000002918 waste heat Substances 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)
Catalysts (AREA)

CA 2277678 1999-07-19 1999-07-19 Elimination des nox de gaz contenant du dioxyde de soufre Expired - Lifetime CA2277678C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA 2277678 CA2277678C (fr)	1999-07-19	1999-07-19	Elimination des nox de gaz contenant du dioxyde de soufre

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA 2277678 CA2277678C (fr)	1999-07-19	1999-07-19	Elimination des nox de gaz contenant du dioxyde de soufre

Publications (2)

Publication Number	Publication Date
CA2277678A1 CA2277678A1 (fr)	2001-01-19
CA2277678C true CA2277678C (fr)	2008-05-06

Family

ID=4163774

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2277678 Expired - Lifetime CA2277678C (fr)	1999-07-19	1999-07-19	Elimination des nox de gaz contenant du dioxyde de soufre

Country Status (1)

Country	Link
CA (1)	CA2277678C (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9994451B2 (en)	2014-06-09	2018-06-12	Chemetics Inc.	Single contact, single absorption system for producing sulfuric acid with high conversion efficiency
CN105967150A (zh) *	2016-07-08	2016-09-28	华能国际电力股份有限公司	一种铂催化剂制取so3气体的设备及方法

1999
- 1999-07-19 CA CA 2277678 patent/CA2277678C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2277678A1 (fr)	2001-01-19

Legal Events

Date	Code	Title	Description
2003-11-12	EEER	Examination request

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