CA2287514A1 - Composition de cycle de rincage adoucissante et stable pour textiles renfermant un co-adoucissant a base de monostearate de glycerol - Google Patents
Composition de cycle de rincage adoucissante et stable pour textiles renfermant un co-adoucissant a base de monostearate de glycerol Download PDFInfo
- Publication number
- CA2287514A1 CA2287514A1 CA002287514A CA2287514A CA2287514A1 CA 2287514 A1 CA2287514 A1 CA 2287514A1 CA 002287514 A CA002287514 A CA 002287514A CA 2287514 A CA2287514 A CA 2287514A CA 2287514 A1 CA2287514 A1 CA 2287514A1
- Authority
- CA
- Canada
- Prior art keywords
- fabric softener
- softener composition
- composition
- quaternary ammonium
- emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000002979 fabric softener Substances 0.000 title claims abstract description 19
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 title claims abstract description 15
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000000203 mixture Substances 0.000 title claims description 63
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 17
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
- 239000004744 fabric Substances 0.000 claims description 18
- -1 fatty ester quaternary ammonium compound Chemical class 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 5
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 150000001450 anions Chemical group 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 238000010412 laundry washing Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 3
- 239000003125 aqueous solvent Substances 0.000 claims description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 1
- 238000007046 ethoxylation reaction Methods 0.000 claims 1
- 150000005690 diesters Chemical group 0.000 abstract description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000004667 Diesterquat Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- 235000011148 calcium chloride Nutrition 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000004669 nonionic softener Substances 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
L'invention concerne des agents adoucissants de cycle de rinçage pour textiles, lesquels agents sont stables et coulables, et renferment un adoucissant textile à base de diester quaternaire tel qu'un sel d'ammonium quaternaire d'ester N-méthyle, N,N,N-triéthanolamine ditallow en combinaison avec du monostéarate de glycérol et avec, comme émulsifiant, un tensio-actif d'éthoxylate d'alcool gras non ionique présentant un rapport hydrophile-lipophile supérieur à 7,5.
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2619498A | 1998-02-19 | 1998-02-19 | |
| US09/026,194 | 1998-02-19 | ||
| US7045398A | 1998-04-30 | 1998-04-30 | |
| US09/070,453 | 1998-04-30 | ||
| US09/237,528 US6057285A (en) | 1998-02-19 | 1999-01-27 | Stable rinse cycle fabric softener composition with GMS co-softener |
| US09/237,528 | 1999-01-27 | ||
| PCT/US1999/003378 WO1999042547A1 (fr) | 1998-02-19 | 1999-02-17 | Composition de cycle de rinçage adoucissante et stable pour textiles renfermant un co-adoucissant a base de monostearate de glycerol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2287514A1 true CA2287514A1 (fr) | 1999-08-26 |
Family
ID=27362708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002287514A Abandoned CA2287514A1 (fr) | 1998-02-19 | 1999-02-17 | Composition de cycle de rincage adoucissante et stable pour textiles renfermant un co-adoucissant a base de monostearate de glycerol |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0975726A1 (fr) |
| JP (1) | JP2001525020A (fr) |
| CN (1) | CN1177918C (fr) |
| AU (1) | AU2769299A (fr) |
| BG (1) | BG103896A (fr) |
| BR (1) | BR9904829A (fr) |
| CA (1) | CA2287514A1 (fr) |
| HU (1) | HUP0003822A3 (fr) |
| IL (1) | IL132332A (fr) |
| NZ (1) | NZ500399A (fr) |
| PL (1) | PL336221A1 (fr) |
| SK (1) | SK154999A3 (fr) |
| TR (1) | TR199902595T1 (fr) |
| WO (1) | WO1999042547A1 (fr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU5777800A (en) * | 1999-07-02 | 2001-01-22 | Dow Chemical Company, The | Clear softening formulations including alkoxylated additives |
| KR100386420B1 (ko) * | 2000-12-20 | 2003-06-02 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
| JP4959879B2 (ja) * | 2001-02-02 | 2012-06-27 | 株式会社Ａｄｅｋａ | 抗菌剤 |
| US6887243B2 (en) | 2001-03-30 | 2005-05-03 | Triage Medical, Inc. | Method and apparatus for bone fixation with secondary compression |
| GB0118347D0 (en) | 2001-07-27 | 2001-09-19 | Unilever Plc | Fabric conditioning compositions |
| ATE389197T1 (de) * | 2001-08-23 | 2008-03-15 | Fujifilm Corp | Spülzusammensetzung für die behandlung von farbphotographischem silberhalogenidmaterial, verarbeitungsgerät und verarbeitungsverfahren |
| JP2005524787A (ja) * | 2002-05-16 | 2005-08-18 | ザ プロクター アンド ギャンブル カンパニー | リンス溶液の外観を向上させるための剤を含む布地仕上げ組成物 |
| EP1504082A1 (fr) | 2002-05-16 | 2005-02-09 | The Procter & Gamble Company | Composition pour le traitement de tissus a ajouter au rincage, procedes et utilisations associes |
| GB0512423D0 (en) * | 2005-06-17 | 2005-07-27 | Unilever Plc | Fabric conditioning composition and use |
| JP5479691B2 (ja) * | 2008-06-16 | 2014-04-23 | 花王株式会社 | 液体洗浄剤組成物 |
| JP5281388B2 (ja) * | 2008-12-25 | 2013-09-04 | 花王株式会社 | 液体洗浄剤組成物 |
| WO2011149475A1 (fr) * | 2010-05-28 | 2011-12-01 | Colgate-Palmolive Company | Saturation d'une chaîne d'acides gras dans un esterquat à base d'alcanolamine |
| CN103249824A (zh) * | 2010-12-01 | 2013-08-14 | 宝洁公司 | 织物护理组合物 |
| CN109208328B (zh) * | 2017-07-07 | 2021-10-22 | 广州蓝月亮实业有限公司 | 含水织物柔软组合物 |
| US12534688B2 (en) | 2019-10-07 | 2026-01-27 | Conopco, Inc. | Fabric softener composition comprising a betaine ester and a fatty co-softener |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5066414A (en) * | 1989-03-06 | 1991-11-19 | The Procter & Gamble Co. | Stable biodegradable fabric softening compositions containing linear alkoxylated alcohols |
| US5501806A (en) * | 1993-07-15 | 1996-03-26 | Colgate-Palmolive Co. | Concentrated liquid fabric softening composition |
| DE4420188A1 (de) * | 1994-06-09 | 1995-12-14 | Hoechst Ag | Wäscheweichspülmittelkonzentrate |
| DE19623764A1 (de) * | 1996-06-14 | 1997-12-18 | Henkel Kgaa | Wäßriges Wäscheweichspülmittel mit hohem Zeta-Potential |
| US5747108A (en) * | 1997-03-19 | 1998-05-05 | Colgate-Palmolive Co. | Super-concentrated liquid rinse cycle fabric softening composition |
-
1999
- 1999-02-17 HU HU0003822A patent/HUP0003822A3/hu unknown
- 1999-02-17 TR TR1999/02595T patent/TR199902595T1/xx unknown
- 1999-02-17 CA CA002287514A patent/CA2287514A1/fr not_active Abandoned
- 1999-02-17 BR BR9904829-9A patent/BR9904829A/pt not_active Application Discontinuation
- 1999-02-17 PL PL99336221A patent/PL336221A1/xx unknown
- 1999-02-17 AU AU27692/99A patent/AU2769299A/en not_active Abandoned
- 1999-02-17 SK SK1549-99A patent/SK154999A3/sk unknown
- 1999-02-17 WO PCT/US1999/003378 patent/WO1999042547A1/fr not_active Ceased
- 1999-02-17 CN CNB998003158A patent/CN1177918C/zh not_active Expired - Fee Related
- 1999-02-17 IL IL13233299A patent/IL132332A/xx not_active IP Right Cessation
- 1999-02-17 NZ NZ500399A patent/NZ500399A/xx unknown
- 1999-02-17 JP JP54267899A patent/JP2001525020A/ja active Pending
- 1999-02-17 EP EP99908200A patent/EP0975726A1/fr not_active Withdrawn
- 1999-11-16 BG BG103896A patent/BG103896A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SK154999A3 (en) | 2000-07-11 |
| CN1258313A (zh) | 2000-06-28 |
| TR199902595T1 (en) | 2000-10-23 |
| WO1999042547A1 (fr) | 1999-08-26 |
| CN1177918C (zh) | 2004-12-01 |
| IL132332A0 (en) | 2001-03-19 |
| JP2001525020A (ja) | 2001-12-04 |
| BR9904829A (pt) | 2000-05-23 |
| PL336221A1 (en) | 2000-06-19 |
| HUP0003822A3 (en) | 2003-02-28 |
| IL132332A (en) | 2003-02-12 |
| NZ500399A (en) | 2000-11-24 |
| EP0975726A1 (fr) | 2000-02-02 |
| BG103896A (en) | 2000-07-31 |
| HUP0003822A2 (en) | 2001-03-28 |
| AU2769299A (en) | 1999-09-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |