CA2287602C - Procede biologique de desencrage - Google Patents

Procede biologique de desencrage Download PDF

Info

Publication number: CA2287602C
Authority: CA; Canada
Prior art keywords: enzyme; printed paper; waste printed; pulp; ink particles
Prior art date: 1990-12-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 2287602

Other languages

English (en)

Other versions

CA2287602A1 (fr

Inventor

Tae Jin Eom

Steven Say-Kyoun Ow

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Korea Research Institute of Chemical Technology KRICT

Original Assignee

Korea Research Institute of Chemical Technology KRICT

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-12-14

Filing date

1990-12-14

Publication date

2007-07-03

1990-12-14 Application filed by Korea Research Institute of Chemical Technology KRICT filed Critical Korea Research Institute of Chemical Technology KRICT

1992-06-15 Publication of CA2287602A1 publication Critical patent/CA2287602A1/fr

2007-07-03 Application granted granted Critical

2007-07-03 Publication of CA2287602C publication Critical patent/CA2287602C/fr

2010-12-14 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000010893 paper waste Substances 0.000 title claims abstract description 27
239000002761 deinking Substances 0.000 title abstract description 34
238000010170 biological method Methods 0.000 title abstract description 3
239000002245 particle Substances 0.000 claims abstract description 31
239000000835 fiber Substances 0.000 claims abstract description 26
238000005406 washing Methods 0.000 claims abstract description 9
238000000034 method Methods 0.000 claims description 48
239000000976 ink Substances 0.000 claims description 46
108090000790 Enzymes Proteins 0.000 claims description 38
102000004190 Enzymes Human genes 0.000 claims description 38
238000005188 flotation Methods 0.000 claims description 23
238000004537 pulping Methods 0.000 claims description 19
239000002699 waste material Substances 0.000 claims description 13
239000003513 alkali Substances 0.000 claims description 4
239000012736 aqueous medium Substances 0.000 claims description 3
239000002952 polymeric resin Substances 0.000 claims description 3
229920003002 synthetic resin Polymers 0.000 claims description 3
229920002678 cellulose Polymers 0.000 claims description 2
239000001913 cellulose Substances 0.000 claims description 2
230000007071 enzymatic hydrolysis Effects 0.000 claims description 2
238000006047 enzymatic hydrolysis reaction Methods 0.000 claims description 2
230000000694 effects Effects 0.000 claims 2
239000002609 medium Substances 0.000 claims 2
238000010979 pH adjustment Methods 0.000 claims 2
102000005575 Cellulases Human genes 0.000 claims 1
108010084185 Cellulases Proteins 0.000 claims 1
239000000463 material Substances 0.000 claims 1
239000000203 mixture Substances 0.000 claims 1
238000004064 recycling Methods 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
238000009291 froth flotation Methods 0.000 abstract description 5
108010059892 Cellulase Proteins 0.000 abstract description 3
229940106157 cellulase Drugs 0.000 abstract description 3
229940088598 enzyme Drugs 0.000 description 26
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
239000004094 surface-active agent Substances 0.000 description 14
235000014113 dietary fatty acids Nutrition 0.000 description 13
239000000194 fatty acid Substances 0.000 description 13
229930195729 fatty acid Natural products 0.000 description 13
150000004665 fatty acids Chemical class 0.000 description 13
239000000126 substance Substances 0.000 description 12
238000007792 addition Methods 0.000 description 11
239000013055 pulp slurry Substances 0.000 description 7
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
235000011121 sodium hydroxide Nutrition 0.000 description 6
238000007796 conventional method Methods 0.000 description 5
229920001131 Pulp (paper) Polymers 0.000 description 4
239000000344 soap Substances 0.000 description 4
239000004115 Sodium Silicate Substances 0.000 description 3
230000004071 biological effect Effects 0.000 description 3
239000010899 old newspaper Substances 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
239000007844 bleaching agent Substances 0.000 description 2
159000000007 calcium salts Chemical class 0.000 description 2
239000002738 chelating agent Substances 0.000 description 2
230000001461 cytolytic effect Effects 0.000 description 2
230000008021 deposition Effects 0.000 description 2
239000003599 detergent Substances 0.000 description 2
238000007865 diluting Methods 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
150000002191 fatty alcohols Chemical class 0.000 description 2
238000005187 foaming Methods 0.000 description 2
238000009897 hydrogen peroxide bleaching Methods 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
230000002351 pectolytic effect Effects 0.000 description 2
239000002002 slurry Substances 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
239000002023 wood Substances 0.000 description 2
238000004383 yellowing Methods 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
229920003043 Cellulose fiber Polymers 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
-1 anionic long-chain fatty acid Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
238000006065 biodegradation reaction Methods 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000003518 caustics Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000009088 enzymatic function Effects 0.000 description 1
230000006870 function Effects 0.000 description 1
238000010191 image analysis Methods 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000004900 laundering Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
230000002085 persistent effect Effects 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000019351 sodium silicates Nutrition 0.000 description 1
239000000243 solution Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
238000004394 yellowing prevention Methods 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C1/00—Pretreatment of the finely-divided materials before digesting
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling

Landscapes

Paper (AREA)

CA 2287602 1990-12-14 1990-12-14 Procede biologique de desencrage Expired - Lifetime CA2287602C (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA 2032256 CA2032256C (fr)	1990-12-14	1990-12-14	Procede biologique de desencrage

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2032256 Division CA2032256C (fr)	1990-12-14	1990-12-14	Procede biologique de desencrage

Publications (2)

Publication Number	Publication Date
CA2287602A1 CA2287602A1 (fr)	1992-06-15
CA2287602C true CA2287602C (fr)	2007-07-03

Family

ID=4146648

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
CA 2032256 Expired - Lifetime CA2032256C (fr)	1990-12-14	1990-12-14	Procede biologique de desencrage
CA 2287602 Expired - Lifetime CA2287602C (fr)	1990-12-14	1990-12-14	Procede biologique de desencrage

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
CA 2032256 Expired - Lifetime CA2032256C (fr)	1990-12-14	1990-12-14	Procede biologique de desencrage

Country Status (1)

Country	Link
CA (2)	CA2032256C (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6426200B1 (en)	1994-09-15	2002-07-30	University Of Georgia Research Foundation, Inc.	Methods for enzymatic deinking of waste paper
US7282113B2 (en)	2004-11-17	2007-10-16	Tritexco, Inc.	Method for enzymatic deinking of waste papers, the waste papers so treated and the treating composition
ES2908691T3 (es)	2011-10-27	2022-05-03	Buckman Laboratories Int Inc	Método y composición para el tratamiento enzimático de la fibra para la fabricación de papel, y productos de papel hechos del mismo

1990
- 1990-12-14 CA CA 2032256 patent/CA2032256C/fr not_active Expired - Lifetime
- 1990-12-14 CA CA 2287602 patent/CA2287602C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2032256C (fr)	2000-02-22
CA2032256A1 (fr)	1992-06-15
CA2287602A1 (fr)	1992-06-15

Legal Events

Date	Code	Title	Description
1999-12-10	EEER	Examination request
2010-12-14	MKLA	Lapsed
2012-12-02	MKEC	Expiry (correction)	Effective date: 20121202

Publication	Publication Date	Title
US5785809A (en)	1998-07-28	Biological de-inking method
US4586982A (en)	1986-05-06	Process for the de-inking of printed waste paper
US5415733A (en)	1995-05-16	Method of removing hydrophilic ink
US5401360A (en)	1995-03-28	Method for de-inking printed paper
JP2761608B2 (ja)	1998-06-04	廃紙材料のインク抜き方法
US5228953A (en)	1993-07-20	Deinking waste paper using a polyglycol and a phosphoric ester mixture
US5632857A (en)	1997-05-27	Process for removing waterborne flexographic inks from substrates
JPH07507109A (ja)	1995-08-03	故紙の処理方法
US5234543A (en)	1993-08-10	Deinking method using ink agglomeration
CA2287602C (fr)	2007-07-03	Procede biologique de desencrage
NZ239438A (en)	1992-11-25	Composition for de-inking newsprint comprising anionic surfactant and dispersant for the ink particles; process for de-inking groundwood newsprint
CA2199745A1 (fr)	1996-03-21	Composition et methode de desencrage pour desencrage de vieux papiers
Borchardt	1997	The use of surfactants in de-inking paper for paper recycling
AU673782B2 (en)	1996-11-21	Treatment of cellulosic material and compositions for use in this
Turvey	1995	Chemical use in recycling
JP6875828B2 (ja)	2021-05-26	脱墨フロス由来のパルプ繊維を含む紙
WO2010093233A1 (fr)	2010-08-19	Procédé de désencrage bioenzymatique de papier
CA2184458A1 (fr)	1997-06-21	Procede et agent de desencrage de papier use
US6217706B1 (en)	2001-04-17	Method of de-inking paper and other cellulosic materials
KR100242929B1 (ko)	2000-02-01	수식셀룰라아제에 의한 폐지의 재생방법
US20050145349A1 (en)	2005-07-07	Method of de-inking paper and other cellulosic materials
KR920010648B1 (ko)	1992-12-12	백상지고지의 재생방법
JP4571290B2 (ja)	2010-10-27	古紙の脱墨方法
Mayeli et al.	2015	Influence of hydrophile–lipophile balance and sodium tripolyphosphate on the properties of biological deinked pulps
Chaiarrekij	2001	Enzymatic deinking of flexographic water-based inks