CA2291722C - Process for treating spent, waste, alkaline digestion liquor from paper pulping operations and product - Google Patents

Process for treating spent, waste, alkaline digestion liquor from paper pulping operations and product Download PDF

Info

Publication number: CA2291722C
Authority: CA; Canada
Prior art keywords: liquor; spent; digestion liquor; process according; digestion
Prior art date: 1997-05-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002291722A

Other languages

English (en)

French (fr)

Other versions

CA2291722A1 (en

Inventor

Hassan El Shall

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bountiful Applied Research Corp

Original Assignee

Bountiful Applied Research Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-05-29

Filing date

1997-05-29

Publication date

2006-06-13

1997-05-29 Application filed by Bountiful Applied Research Corp filed Critical Bountiful Applied Research Corp

1997-05-29 Priority claimed from PCT/US1997/009418 external-priority patent/WO1998054400A1/en

1998-12-03 Publication of CA2291722A1 publication Critical patent/CA2291722A1/en

2006-06-13 Application granted granted Critical

2006-06-13 Publication of CA2291722C publication Critical patent/CA2291722C/en

2017-05-29 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

230000029087 digestion Effects 0.000 title claims abstract description 95
238000000034 method Methods 0.000 title claims description 88
230000008569 process Effects 0.000 title claims description 71
238000004537 pulping Methods 0.000 title claims description 42
239000002699 waste material Substances 0.000 title description 21
239000007787 solid Substances 0.000 claims abstract description 65
229920005610 lignin Polymers 0.000 claims abstract description 58
239000007788 liquid Substances 0.000 claims abstract description 43
238000000926 separation method Methods 0.000 claims abstract description 23
230000020477 pH reduction Effects 0.000 claims abstract description 20
239000000701 coagulant Substances 0.000 claims abstract description 18
239000003795 chemical substances by application Substances 0.000 claims abstract description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 49
239000002655 kraft paper Substances 0.000 claims description 39
239000000377 silicon dioxide Substances 0.000 claims description 24
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 23
238000011084 recovery Methods 0.000 claims description 19
239000004094 surface-active agent Substances 0.000 claims description 9
239000000123 paper Substances 0.000 claims description 7
239000000446 fuel Substances 0.000 claims description 3
238000002156 mixing Methods 0.000 claims description 3
150000002894 organic compounds Chemical class 0.000 claims description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 1
239000013530 defoamer Substances 0.000 abstract description 10
230000005484 gravity Effects 0.000 abstract description 6
150000003839 salts Chemical class 0.000 abstract description 5
230000001079 digestive effect Effects 0.000 abstract description 3
229920000642 polymer Polymers 0.000 description 39
239000000126 substance Substances 0.000 description 23
241000196324 Embryophyta Species 0.000 description 17
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
239000000203 mixture Substances 0.000 description 13
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 11
239000002244 precipitate Substances 0.000 description 11
239000000835 fiber Substances 0.000 description 9
239000002994 raw material Substances 0.000 description 9
238000001914 filtration Methods 0.000 description 8
239000000463 material Substances 0.000 description 8
239000002253 acid Substances 0.000 description 7
239000000243 solution Substances 0.000 description 7
239000002023 wood Substances 0.000 description 7
238000004519 manufacturing process Methods 0.000 description 6
238000012545 processing Methods 0.000 description 6
238000012216 screening Methods 0.000 description 6
229910052979 sodium sulfide Inorganic materials 0.000 description 6
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
230000008901 benefit Effects 0.000 description 5
235000014633 carbohydrates Nutrition 0.000 description 5
150000001720 carbohydrates Chemical class 0.000 description 5
239000000047 product Substances 0.000 description 5
235000011121 sodium hydroxide Nutrition 0.000 description 5
239000010902 straw Substances 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
239000003513 alkali Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
239000003153 chemical reaction reagent Substances 0.000 description 4
239000000470 constituent Substances 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
239000000706 filtrate Substances 0.000 description 4
239000007789 gas Substances 0.000 description 4
-1 kraft Chemical compound 0.000 description 4
239000000523 sample Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
229920003043 Cellulose fiber Polymers 0.000 description 3
240000007594 Oryza sativa Species 0.000 description 3
235000007164 Oryza sativa Nutrition 0.000 description 3
229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
239000001913 cellulose Substances 0.000 description 3
235000013339 cereals Nutrition 0.000 description 3
239000000084 colloidal system Substances 0.000 description 3
238000010411 cooking Methods 0.000 description 3
239000003265 pulping liquor Substances 0.000 description 3
235000009566 rice Nutrition 0.000 description 3
239000006228 supernatant Substances 0.000 description 3
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
230000009471 action Effects 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
238000000975 co-precipitation Methods 0.000 description 2
238000005345 coagulation Methods 0.000 description 2
230000015271 coagulation Effects 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000009826 distribution Methods 0.000 description 2
159000000011 group IA salts Chemical class 0.000 description 2
239000011121 hardwood Substances 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
239000011707 mineral Substances 0.000 description 2
235000010755 mineral Nutrition 0.000 description 2
150000007522 mineralic acids Chemical class 0.000 description 2
239000002245 particle Substances 0.000 description 2
229920002401 polyacrylamide Polymers 0.000 description 2
238000003825 pressing Methods 0.000 description 2
239000011347 resin Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011122 softwood Substances 0.000 description 2
239000003784 tall oil Substances 0.000 description 2
235000013311 vegetables Nutrition 0.000 description 2
PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
241000218631 Coniferophyta Species 0.000 description 1
240000000491 Corchorus aestuans Species 0.000 description 1
235000011777 Corchorus aestuans Nutrition 0.000 description 1
235000010862 Corchorus capsularis Nutrition 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
240000000111 Saccharum officinarum Species 0.000 description 1
235000007201 Saccharum officinarum Nutrition 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
241000209140 Triticum Species 0.000 description 1
235000021307 Triticum Nutrition 0.000 description 1
240000000359 Triticum dicoccon Species 0.000 description 1
229920002522 Wood fibre Polymers 0.000 description 1
238000004220 aggregation Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
238000007605 air drying Methods 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229920006318 anionic polymer Polymers 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
YXZBWJWYWHRIMU-UBPCSPHJSA-I calcium trisodium 2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate ytterbium-169 Chemical compound [Na+].[Na+].[Na+].[Ca+2].[169Yb].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O YXZBWJWYWHRIMU-UBPCSPHJSA-I 0.000 description 1
235000009120 camo Nutrition 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
229920006317 cationic polymer Polymers 0.000 description 1
210000002421 cell wall Anatomy 0.000 description 1
235000005607 chanvre indien Nutrition 0.000 description 1
238000005352 clarification Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
239000013068 control sample Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
229910000397 disodium phosphate Inorganic materials 0.000 description 1
235000019800 disodium phosphate Nutrition 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000013505 freshwater Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000011487 hemp Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000010805 inorganic waste Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000000178 monomer Substances 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
150000002898 organic sulfur compounds Chemical class 0.000 description 1
239000013618 particulate matter Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000010008 shearing Methods 0.000 description 1
239000000344 soap Substances 0.000 description 1
229940047670 sodium acrylate Drugs 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000012265 solid product Substances 0.000 description 1
241000894007 species Species 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
230000000153 supplemental effect Effects 0.000 description 1
229920001864 tannin Polymers 0.000 description 1
239000001648 tannin Substances 0.000 description 1
235000018553 tannin Nutrition 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000002025 wood fiber Substances 0.000 description 1

Landscapes

Paper (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Degasification And Air Bubble Elimination (AREA)
Separation Of Suspended Particles By Flocculating Agents (AREA)

CA002291722A 1997-05-29 1997-05-29 Process for treating spent, waste, alkaline digestion liquor from paper pulping operations and product Expired - Fee Related CA2291722C (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
PCT/US1997/009418 WO1998054400A1 (en)	1993-08-20	1997-05-29	Process for treating spent, waste, alkaline digestion liquor from paper pulping operations and product

Publications (2)

Publication Number	Publication Date
CA2291722A1 CA2291722A1 (en)	1998-12-03
CA2291722C true CA2291722C (en)	2006-06-13

Family

ID=22261000

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002291722A Expired - Fee Related CA2291722C (en)	1997-05-29	1997-05-29	Process for treating spent, waste, alkaline digestion liquor from paper pulping operations and product

Country Status (5)

Country	Link
JP (1)	JP2002500707A (de)
AT (1)	ATE288967T1 (de)
AU (1)	AU3224797A (de)
CA (1)	CA2291722C (de)
DE (1)	DE69732499D1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP4670011B2 (ja) *	2005-10-18	2011-04-13	独立行政法人産業技術総合研究所	リグニン含有樹脂、その製造方法、及びリグニン分離方法
WO2011162420A1 (ja) *	2010-06-25	2011-12-29	ロペスアンドエヌティ有限会社	パルプ蒸解廃液から中性領域でリグニンを回収する方法

1997
- 1997-05-29 JP JP50061699A patent/JP2002500707A/ja active Pending
- 1997-05-29 AT AT97927900T patent/ATE288967T1/de not_active IP Right Cessation
- 1997-05-29 AU AU32247/97A patent/AU3224797A/en not_active Abandoned
- 1997-05-29 DE DE69732499T patent/DE69732499D1/de not_active Expired - Lifetime
- 1997-05-29 CA CA002291722A patent/CA2291722C/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2291722A1 (en)	1998-12-03
DE69732499D1 (de)	2005-03-17
JP2002500707A (ja)	2002-01-08
AU3224797A (en)	1998-12-30
ATE288967T1 (de)	2005-02-15

Legal Events

Date	Code	Title	Description
2001-07-26	EEER	Examination request
2017-07-11	MKLA	Lapsed	Effective date: 20170529

Publication	Publication Date	Title
US6632327B1 (en)	2003-10-14	Process for treating spent, waste, alkaline digestion liquor from paper pulping operations and product
EP1797236B1 (de)	2011-06-15	Verfahren zur abtrennung von lignin aus einer ligninhaltigen flüssigkeit bzw. aufschlämmung
US20080214796A1 (en)	2008-09-04	Method
US5777086A (en)	1998-07-07	Method of recovering lignin from pulp and paper sludge
US20100325947A1 (en)	2010-12-30	Method for separating lignin from black liquor, a lignin product, and use of a lignin product for the production of fuels or materials
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