CA2302632A1 - Compositions granulaires d'acetonitrile d'ammonium n-alkyle - Google Patents

Compositions granulaires d'acetonitrile d'ammonium n-alkyle Download PDF

Info

Publication number: CA2302632A1
Authority: CA; Canada
Prior art keywords: granules; alkyl; salt; formula; atom
Prior art date: 1999-03-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2302632

Other languages

English (en)

Inventor

William P. Sibert

Gregory M. Piche

David C. Sandoval

Susan P. Huestis

Agnes Jaszenovics

Sarah P. Blondeau

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Clorox Co

Original Assignee

Clorox Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-03-29

Filing date

2000-03-28

Publication date

2000-09-29

1999-03-29 Priority claimed from US09/280,178 external-priority patent/US6183665B1/en

2000-03-28 Application filed by Clorox Co filed Critical Clorox Co

2000-09-29 Publication of CA2302632A1 publication Critical patent/CA2302632A1/fr

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 84
WEVYAHXRMPXWCK-UHFFFAOYSA-N methyl cyanide Natural products CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 title description 19
239000008187 granular material Substances 0.000 claims abstract description 70
239000007787 solid Substances 0.000 claims abstract description 42
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 34
150000003839 salts Chemical class 0.000 claims abstract description 34
125000003545 alkoxy group Chemical group 0.000 claims abstract description 26
125000000217 alkyl group Chemical group 0.000 claims abstract description 24
125000004429 atom Chemical group 0.000 claims abstract description 23
229910052760 oxygen Inorganic materials 0.000 claims abstract description 19
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 17
239000001301 oxygen Substances 0.000 claims abstract description 17
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 16
229920006395 saturated elastomer Polymers 0.000 claims abstract description 15
125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 12
125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 12
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 11
125000001424 substituent group Chemical group 0.000 claims abstract description 11
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
239000004927 clay Substances 0.000 claims abstract description 7
229910052799 carbon Inorganic materials 0.000 claims abstract description 5
125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 5
125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 5
229910002027 silica gel Inorganic materials 0.000 claims abstract description 5
239000000741 silica gel Substances 0.000 claims abstract description 5
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 4
230000001590 oxidative effect Effects 0.000 claims abstract description 4
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 4
229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
125000004434 sulfur atom Chemical group 0.000 claims abstract description 4
125000006413 ring segment Chemical group 0.000 claims abstract description 3
238000004061 bleaching Methods 0.000 claims description 37
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 26
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
239000004094 surface-active agent Substances 0.000 claims description 16
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 14
239000002245 particle Substances 0.000 claims description 14
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 13
102000004190 Enzymes Human genes 0.000 claims description 11
108090000790 Enzymes Proteins 0.000 claims description 11
238000000576 coating method Methods 0.000 claims description 11
239000002738 chelating agent Substances 0.000 claims description 10
239000003795 chemical substances by application Substances 0.000 claims description 9
239000011248 coating agent Substances 0.000 claims description 9
230000002378 acidificating effect Effects 0.000 claims description 8
150000001412 amines Chemical group 0.000 claims description 7
239000007864 aqueous solution Substances 0.000 claims description 7
239000000872 buffer Substances 0.000 claims description 4
230000036571 hydration Effects 0.000 claims description 4
238000006703 hydration reaction Methods 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 4
238000005282 brightening Methods 0.000 claims description 3
ONANWDUDFJIIGP-UHFFFAOYSA-N carbamoyl carbamoperoxoate Chemical class NC(=O)OOC(N)=O ONANWDUDFJIIGP-UHFFFAOYSA-N 0.000 claims description 3
238000004090 dissolution Methods 0.000 claims description 3
230000002087 whitening effect Effects 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
239000012670 alkaline solution Substances 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
229910052936 alkali metal sulfate Inorganic materials 0.000 claims 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
150000003335 secondary amines Chemical class 0.000 claims 1
150000003512 tertiary amines Chemical class 0.000 claims 1
-1 peroxyacid compounds Chemical class 0.000 description 42
150000002826 nitrites Chemical class 0.000 description 32
LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 31
238000000034 method Methods 0.000 description 27
238000006243 chemical reaction Methods 0.000 description 23
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 22
IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite group Chemical group N(=O)[O-] IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 22
239000012190 activator Substances 0.000 description 21
230000008569 process Effects 0.000 description 21
239000007788 liquid Substances 0.000 description 20
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 18
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
150000001875 compounds Chemical class 0.000 description 18
239000002253 acid Substances 0.000 description 17
239000000243 solution Substances 0.000 description 17
VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 16
150000004965 peroxy acids Chemical class 0.000 description 14
239000000047 product Substances 0.000 description 14
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 13
229910052783 alkali metal Inorganic materials 0.000 description 13
238000004140 cleaning Methods 0.000 description 13
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
239000003599 detergent Substances 0.000 description 12
238000001816 cooling Methods 0.000 description 11
239000000975 dye Substances 0.000 description 11
239000000463 material Substances 0.000 description 11
239000000155 melt Substances 0.000 description 11
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
150000001340 alkali metals Chemical class 0.000 description 10
230000008901 benefit Effects 0.000 description 10
239000007844 bleaching agent Substances 0.000 description 10
239000013078 crystal Substances 0.000 description 10
229940088598 enzyme Drugs 0.000 description 10
238000001704 evaporation Methods 0.000 description 10
230000008020 evaporation Effects 0.000 description 10
238000004519 manufacturing process Methods 0.000 description 10
239000000377 silicon dioxide Substances 0.000 description 10
238000003860 storage Methods 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
229910021536 Zeolite Inorganic materials 0.000 description 8
239000006227 byproduct Substances 0.000 description 8
239000000969 carrier Substances 0.000 description 8
239000010457 zeolite Substances 0.000 description 8
239000002168 alkylating agent Substances 0.000 description 7
229940100198 alkylating agent Drugs 0.000 description 7
230000000694 effects Effects 0.000 description 7
125000005842 heteroatom Chemical group 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
238000007711 solidification Methods 0.000 description 7
230000008023 solidification Effects 0.000 description 7
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
239000000654 additive Substances 0.000 description 6
150000008051 alkyl sulfates Chemical class 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
235000014113 dietary fatty acids Nutrition 0.000 description 6
239000004744 fabric Substances 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
229930195729 fatty acid Natural products 0.000 description 6
238000009472 formulation Methods 0.000 description 6
238000005469 granulation Methods 0.000 description 6
230000003179 granulation Effects 0.000 description 6
238000002156 mixing Methods 0.000 description 6
150000002978 peroxides Chemical class 0.000 description 6
239000002243 precursor Substances 0.000 description 6
235000011121 sodium hydroxide Nutrition 0.000 description 6
102000013142 Amylases Human genes 0.000 description 5
108010065511 Amylases Proteins 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
235000019418 amylase Nutrition 0.000 description 5
238000013459 approach Methods 0.000 description 5
239000012736 aqueous medium Substances 0.000 description 5
238000002425 crystallisation Methods 0.000 description 5
230000008025 crystallization Effects 0.000 description 5
230000002349 favourable effect Effects 0.000 description 5
125000005624 silicic acid group Chemical class 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000011734 sodium Substances 0.000 description 5
229910000029 sodium carbonate Inorganic materials 0.000 description 5
239000008247 solid mixture Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
108091005804 Peptidases Proteins 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
239000004365 Protease Substances 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
DFNYGALUNNFWKJ-UHFFFAOYSA-N aminoacetonitrile Chemical compound NCC#N DFNYGALUNNFWKJ-UHFFFAOYSA-N 0.000 description 4
239000012876 carrier material Substances 0.000 description 4
238000010924 continuous production Methods 0.000 description 4
125000004122 cyclic group Chemical group 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
239000012467 final product Substances 0.000 description 4
238000005755 formation reaction Methods 0.000 description 4
LTYRAPJYLUPLCI-UHFFFAOYSA-N glycolonitrile Chemical compound OCC#N LTYRAPJYLUPLCI-UHFFFAOYSA-N 0.000 description 4
238000006460 hydrolysis reaction Methods 0.000 description 4
238000011065 in-situ storage Methods 0.000 description 4
150000002825 nitriles Chemical class 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
239000011591 potassium Substances 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
150000004760 silicates Chemical class 0.000 description 4
229960001922 sodium perborate Drugs 0.000 description 4
238000003756 stirring Methods 0.000 description 4
OOSOCAXREAGIGA-UHFFFAOYSA-N 2-morpholin-4-ylacetonitrile Chemical compound N#CCN1CCOCC1 OOSOCAXREAGIGA-UHFFFAOYSA-N 0.000 description 3
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 3
238000012935 Averaging Methods 0.000 description 3
108091005658 Basic proteases Proteins 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
239000004614 Process Aid Substances 0.000 description 3
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 3
ANFUBNUHCOCTIT-UHFFFAOYSA-N acetonitrile methylazanium methyl sulfate Chemical compound COS(=O)(=O)[O-].C(C)#N.C[NH3+] ANFUBNUHCOCTIT-UHFFFAOYSA-N 0.000 description 3
SWLWZVHQLWXZTQ-UHFFFAOYSA-N acetonitrile;4-methylmorpholin-4-ium;methyl sulfate Chemical compound CC#N.COS([O-])(=O)=O.C[NH+]1CCOCC1 SWLWZVHQLWXZTQ-UHFFFAOYSA-N 0.000 description 3
WFACTXCBWPYESL-UHFFFAOYSA-N acetonitrile;4-methylmorpholine Chemical compound CC#N.CN1CCOCC1 WFACTXCBWPYESL-UHFFFAOYSA-N 0.000 description 3
YDCNECXDBVLHLS-UHFFFAOYSA-N acetonitrile;azane Chemical compound N.CC#N YDCNECXDBVLHLS-UHFFFAOYSA-N 0.000 description 3
230000009471 action Effects 0.000 description 3
150000001299 aldehydes Chemical class 0.000 description 3
229940025131 amylases Drugs 0.000 description 3
239000003945 anionic surfactant Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000002585 base Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000012530 fluid Substances 0.000 description 3
239000000499 gel Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
230000007062 hydrolysis Effects 0.000 description 3
239000012535 impurity Substances 0.000 description 3
239000000543 intermediate Substances 0.000 description 3
238000004900 laundering Methods 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
229910052744 lithium Inorganic materials 0.000 description 3
239000002736 nonionic surfactant Substances 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical class [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
239000000049 pigment Substances 0.000 description 3
229920001983 poloxamer Polymers 0.000 description 3
239000011148 porous material Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
238000012545 processing Methods 0.000 description 3
238000005956 quaternization reaction Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
230000001105 regulatory effect Effects 0.000 description 3
229910052938 sodium sulfate Inorganic materials 0.000 description 3
235000011152 sodium sulphate Nutrition 0.000 description 3
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
239000000725 suspension Substances 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 3
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical class OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
239000004382 Amylase Substances 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
102000004882 Lipase Human genes 0.000 description 2
108090001060 Lipase Proteins 0.000 description 2
239000004367 Lipase Substances 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
102000035195 Peptidases Human genes 0.000 description 2
229920002266 Pluriol® Polymers 0.000 description 2
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
108010056079 Subtilisins Proteins 0.000 description 2
102000005158 Subtilisins Human genes 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000004996 alkyl benzenes Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
235000012211 aluminium silicate Nutrition 0.000 description 2
229940077388 benzenesulfonate Drugs 0.000 description 2
230000001851 biosynthetic effect Effects 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
239000003086 colorant Substances 0.000 description 2
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
VRZVPALEJCLXPR-UHFFFAOYSA-N ethyl 4-methylbenzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=C(C)C=C1 VRZVPALEJCLXPR-UHFFFAOYSA-N 0.000 description 2
239000003205 fragrance Substances 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000004898 kneading Methods 0.000 description 2
235000019421 lipase Nutrition 0.000 description 2
VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 2
JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical class COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
235000019419 proteases Nutrition 0.000 description 2
150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
238000011084 recovery Methods 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
229910000342 sodium bisulfate Inorganic materials 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
241000894007 species Species 0.000 description 2
125000003107 substituted aryl group Chemical group 0.000 description 2
239000000758 substrate Substances 0.000 description 2
150000003871 sulfonates Chemical class 0.000 description 2
230000001629 suppression Effects 0.000 description 2
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238000012360 testing method Methods 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000010409 thin film Substances 0.000 description 1
125000005490 tosylate group Chemical group 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Chemical class OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
XLRPYZSEQKXZAA-OCAPTIKFSA-N tropane Chemical group C1CC[C@H]2CC[C@@H]1N2C XLRPYZSEQKXZAA-OCAPTIKFSA-N 0.000 description 1
229930004006 tropane Natural products 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

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Detergent Compositions (AREA)

CA 2302632 1999-03-29 2000-03-28 Compositions granulaires d'acetonitrile d'ammonium n-alkyle Abandoned CA2302632A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US09/280,178 US6183665B1 (en)	1995-06-07	1999-03-29	Granular N-alkyl ammonium acetonitrile compositions
US09/280,178		1999-03-29

Publications (1)

Publication Number	Publication Date
CA2302632A1 true CA2302632A1 (fr)	2000-09-29

Family

ID=23072011

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2302632 Abandoned CA2302632A1 (fr)	1999-03-29	2000-03-28	Compositions granulaires d'acetonitrile d'ammonium n-alkyle

Country Status (1)

Country	Link
CA (1)	CA2302632A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN113828014A (zh) *	2021-09-14	2021-12-24	海南金海浆纸业有限公司	一种聚合氯化铝溶液的纯化脱色工艺

2000
- 2000-03-28 CA CA 2302632 patent/CA2302632A1/fr not_active Abandoned

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN113828014A (zh) *	2021-09-14	2021-12-24	海南金海浆纸业有限公司	一种聚合氯化铝溶液的纯化脱色工艺
CN113828014B (zh) *	2021-09-14	2023-03-17	海南金海浆纸业有限公司	一种聚合氯化铝溶液的纯化脱色工艺

Legal Events

Date	Code	Title	Description
2006-03-28	FZDE	Dead

Publication	Publication Date	Title
US5888419A (en)	1999-03-30	Granular N-alkyl ammonium acetontrile compositions
AU746352B2 (en)	2002-04-18	Mixed peroxygen activator compositions
MXPA99005077A (fr)	2000-05-01
MXPA99005080A (en)	2000-07-01	Mixed peroxygen activator compositions
EP1036070B1 (fr)	2004-02-18	Sels d'acetonitrile d'ammonium n-alkyle, procedes associes et compositions contenant ces sels
MXPA99005078A (en)	2000-06-01	N-alkyl ammonium acetonitrile salts, methods therefor and compositions therewith
US6183665B1 (en)	2001-02-06	Granular N-alkyl ammonium acetonitrile compositions
US6235218B1 (en)	2001-05-22	Process for preparing N-alkyl ammonium acetonitrile compounds
AU742769B2 (en)	2002-01-10	Process for preparing N-alkyl ammonium acetonitrile compounds
US6764613B2 (en)	2004-07-20	N-alkyl ammonium acetonitrile salts, methods therefor and compositions therewith
CA2302632A1 (fr)	2000-09-29	Compositions granulaires d'acetonitrile d'ammonium n-alkyle
MXPA99005076A (en)	2000-06-01	Process for preparing n-alkyl ammonium acetonitrile compounds
AU1881402A (en)	2002-04-18	Granular N-alkyl ammonium acetonitrile compositions
AU1020302A (en)	2002-03-21	N-alkyl ammonium acetonitrile salts methods therefor and compositions therewith