CA2303375A1 - Articles elastomeres fabriques a partir d'un melange de chloroprene et d'acrylonitrile - Google Patents
Articles elastomeres fabriques a partir d'un melange de chloroprene et d'acrylonitrile Download PDFInfo
- Publication number
- CA2303375A1 CA2303375A1 CA002303375A CA2303375A CA2303375A1 CA 2303375 A1 CA2303375 A1 CA 2303375A1 CA 002303375 A CA002303375 A CA 002303375A CA 2303375 A CA2303375 A CA 2303375A CA 2303375 A1 CA2303375 A1 CA 2303375A1
- Authority
- CA
- Canada
- Prior art keywords
- polymer
- butadiene
- weight
- parts
- acrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 229920001084 poly(chloroprene) Polymers 0.000 title claims abstract description 17
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title claims description 7
- 229920002959 polymer blend Polymers 0.000 claims abstract description 29
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920001971 elastomer Polymers 0.000 claims description 26
- 229920001577 copolymer Polymers 0.000 claims description 24
- 239000000806 elastomer Substances 0.000 claims description 23
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- IVBPWRJIKBNGEP-UHFFFAOYSA-N 2-bromo-3-chlorobuta-1,3-diene Chemical compound ClC(=C)C(Br)=C IVBPWRJIKBNGEP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 5
- 238000004073 vulcanization Methods 0.000 claims description 5
- GVTJVTFUVRQJKK-UHFFFAOYSA-N 2,3-dibromobuta-1,3-diene Chemical compound BrC(=C)C(Br)=C GVTJVTFUVRQJKK-UHFFFAOYSA-N 0.000 claims description 4
- LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 claims description 4
- 239000013536 elastomeric material Substances 0.000 claims description 4
- 230000002040 relaxant effect Effects 0.000 claims description 2
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 229920006173 natural rubber latex Polymers 0.000 abstract description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 6
- 229920002554 vinyl polymer Polymers 0.000 abstract description 6
- 150000002825 nitriles Chemical class 0.000 abstract 3
- 229920000126 latex Polymers 0.000 description 18
- 239000004816 latex Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 18
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 16
- 238000007598 dipping method Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- -1 poly(2-chloro-1,3-butadiene) Polymers 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 101000952180 Morus alba Mulatexin Proteins 0.000 description 3
- 239000013566 allergen Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229920013624 Tylac Polymers 0.000 description 2
- 230000002009 allergenic effect Effects 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 208000007811 Latex Hypersensitivity Diseases 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- TVEOPXGOFVVUHS-UHFFFAOYSA-N buta-1,3-diene;nitrous acid Chemical compound ON=O.C=CC=C TVEOPXGOFVVUHS-UHFFFAOYSA-N 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
- C08L11/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
- C08L13/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Materials For Medical Uses (AREA)
Abstract
L'invention concerne des articles élastomères profilés, par exemple des gants, des préservatifs, et des sacs respiratoires, préparés à partir d'une composition mélangée de polymères. Cette composition renferment environ entre 10 et 90 parties en poids d'un polymère de chloroprène, et environ entre 10 et 90 parties en poids d'un polymère de nitrile, sur la base de 100 parties en poids du polymère total. Une fois durci, cet article présente une épaisseur variant entre 0,05 et 50 mils, une résistance à la traction d'au moins 9 MPA, et une élongation atteignant au moins 300 %. Lorsque cet article est étiré pour venir s'ajuster sur un membre du corps humain, par exemple la main, il exerce une pression initiale avant de se relâcher de manière à exercer une pression réduite, qui atteint au moins 50 % de ladite pression initiale. Cette invention concerne également un mélange de chloroprène et de nitrile, permettant de produire des articles provoquant une sensation et une fonctionnalité équivalente ou similaire à celles d'un gant classique en latex de caoutchouc naturel. Ces articles donnent donc une sensation équivalente ou meilleure que les gants en vinyle ou en nitrile actuellement disponibles.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6474297P | 1997-11-07 | 1997-11-07 | |
| US60/064,742 | 1997-11-07 | ||
| PCT/US1998/023640 WO1999024507A1 (fr) | 1997-11-07 | 1998-11-06 | Articles elastomeres fabriques a partir d'un melange de chloroprene et d'acrylonitrile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2303375A1 true CA2303375A1 (fr) | 1999-05-20 |
Family
ID=22057996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002303375A Abandoned CA2303375A1 (fr) | 1997-11-07 | 1998-11-06 | Articles elastomeres fabriques a partir d'un melange de chloroprene et d'acrylonitrile |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1030883A4 (fr) |
| JP (1) | JP2001522921A (fr) |
| AU (1) | AU741202B2 (fr) |
| CA (1) | CA2303375A1 (fr) |
| ID (1) | ID25890A (fr) |
| WO (1) | WO1999024507A1 (fr) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6195805B1 (en) * | 1998-02-27 | 2001-03-06 | Allegiance Corporation | Powder free neoprene surgical gloves |
| US6000061A (en) * | 1998-11-18 | 1999-12-14 | Pt. Irama Dinamika Latex | Glove made from a blend of chloroprene rubber and a carboxylated synthetic butadiene rubber |
| US6451893B1 (en) * | 2001-05-22 | 2002-09-17 | Microflex Corporation | Soft nitrile zinc oxide free medical gloves |
| GB0211027D0 (en) * | 2002-05-14 | 2002-06-26 | Ssl Internat | Double-donnable glove |
| US7971276B2 (en) * | 2005-12-01 | 2011-07-05 | Ansell Healthcare Products, Llc | Glove with hand-friendly coating and method of making |
| WO2009021229A1 (fr) * | 2007-08-09 | 2009-02-12 | Playtex Products, Inc. | Composé de latex polymère |
| ES2487528T3 (es) | 2009-02-05 | 2014-08-21 | Diptech Pte Limited | Producción de films elastómeros |
| RU2550827C2 (ru) * | 2013-07-01 | 2015-05-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Чувашский государственный университет имени И.Н. Ульянова" | Резиновая смесь |
| RU2547477C2 (ru) * | 2013-07-09 | 2015-04-10 | Федеральное государственное унитарное предприятие "Научно-производственное предприятие "Прогресс" (ФГУП "НПП "Прогресс") | Маслостойкая резиновая композиция |
| WO2015006808A1 (fr) | 2013-07-16 | 2015-01-22 | Skinprotect Corporation Sdn Bhd | Compositions de formation de film élastomère et articles fabriqués à partir du film élastomère |
| US10626283B2 (en) | 2013-11-19 | 2020-04-21 | Ansell Limited | Polymer blends of nitrile rubber and polychloroprene |
| EP3289012A2 (fr) * | 2015-04-28 | 2018-03-07 | Avent, Inc. | Gant en caoutchouc nitrile à modificateur d'étirement |
| US10154699B2 (en) | 2015-09-10 | 2018-12-18 | Ansell Limited | Highly chemical resistant glove |
| CN110234684B (zh) * | 2016-12-30 | 2023-02-10 | 皮肤防护有限公司 | 形成弹性体膜的组合物以及相关的制品和方法 |
| CN110054819B (zh) * | 2019-04-22 | 2021-07-27 | 山东津莱环海医疗科技有限公司 | 一种氯丁橡胶麻醉储气囊 |
| MY196386A (en) * | 2019-05-23 | 2023-03-28 | Top Glove Int Sdn Bhd | Elastomeric Article |
| AU2022319176B2 (en) | 2021-07-27 | 2026-03-05 | Ansell Limited | Accelerator free synthetic gloves with high tear resistance |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3943192A (en) * | 1968-03-05 | 1976-03-09 | Polysar Limited | Elastomeric blends |
| US3823024A (en) * | 1972-05-10 | 1974-07-09 | Grace W R & Co | Process for forming a strippable coating |
| US4048261A (en) * | 1975-11-10 | 1977-09-13 | The B. F. Goodrich Company | Vulcanizable compositions of a halogen-containing polymer and a diene-nitrile rubber having active halogen cure sites |
| DE3934954A1 (de) * | 1989-10-20 | 1991-04-25 | Bayer Ag | Kautschukmischungen aus polychloropren und hydriertem nitrilkautschuk |
| US5084514A (en) * | 1990-11-14 | 1992-01-28 | Reichhold Chemicals, Inc. | Latex gloves with improved donnability |
| EP0830151B9 (fr) * | 1995-06-07 | 2004-03-17 | Allegiance Corporation | Gants de chirurgie realises a partir de copolymeres de neoprene |
-
1998
- 1998-11-06 EP EP98956637A patent/EP1030883A4/fr not_active Withdrawn
- 1998-11-06 WO PCT/US1998/023640 patent/WO1999024507A1/fr not_active Ceased
- 1998-11-06 ID IDW20000405A patent/ID25890A/id unknown
- 1998-11-06 JP JP2000520509A patent/JP2001522921A/ja active Pending
- 1998-11-06 CA CA002303375A patent/CA2303375A1/fr not_active Abandoned
- 1998-11-06 AU AU13114/99A patent/AU741202B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| ID25890A (id) | 2000-11-09 |
| AU1311499A (en) | 1999-05-31 |
| WO1999024507A1 (fr) | 1999-05-20 |
| AU741202B2 (en) | 2001-11-22 |
| JP2001522921A (ja) | 2001-11-20 |
| EP1030883A4 (fr) | 2005-09-21 |
| EP1030883A1 (fr) | 2000-08-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |