CA2306724A1 - Pastilles de detergent renfermant des liants solides - Google Patents

Pastilles de detergent renfermant des liants solides Download PDF

Info

Publication number: CA2306724A1
Authority: CA; Canada
Prior art keywords: weight; detergent tablets; paraffins; tablets; room temperature
Prior art date: 1999-04-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2306724

Other languages

English (en)

Inventor

Peter Schmiedel

Ute Krupp

Monika Boecker

Fred Schambil

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-04-29

Filing date

2000-04-27

Publication date

2000-10-29

2000-04-27 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2000-10-29 Publication of CA2306724A1 publication Critical patent/CA2306724A1/fr

Status Abandoned legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 116
239000007787 solid Substances 0.000 title claims abstract description 43
239000011230 binding agent Substances 0.000 title description 9
239000002245 particle Substances 0.000 claims abstract description 53
238000005299 abrasion Methods 0.000 claims abstract description 10
238000000034 method Methods 0.000 claims description 53
239000004094 surface-active agent Substances 0.000 claims description 43
239000007844 bleaching agent Substances 0.000 claims description 39
-1 pH regulators Substances 0.000 claims description 39
229920002678 cellulose Polymers 0.000 claims description 33
239000001913 cellulose Substances 0.000 claims description 25
238000002844 melting Methods 0.000 claims description 24
230000008018 melting Effects 0.000 claims description 24
239000008187 granular material Substances 0.000 claims description 23
239000002304 perfume Substances 0.000 claims description 22
239000002736 nonionic surfactant Substances 0.000 claims description 21
239000012188 paraffin wax Substances 0.000 claims description 21
102000004190 Enzymes Human genes 0.000 claims description 20
108090000790 Enzymes Proteins 0.000 claims description 20
239000003945 anionic surfactant Substances 0.000 claims description 18
239000000126 substance Substances 0.000 claims description 17
239000003112 inhibitor Substances 0.000 claims description 16
239000004615 ingredient Substances 0.000 claims description 14
239000000975 dye Substances 0.000 claims description 12
238000007711 solidification Methods 0.000 claims description 12
230000008023 solidification Effects 0.000 claims description 12
239000012190 activator Substances 0.000 claims description 11
238000004519 manufacturing process Methods 0.000 claims description 10
125000000129 anionic group Chemical group 0.000 claims description 9
230000003287 optical effect Effects 0.000 claims description 6
239000000969 carrier Substances 0.000 claims description 4
238000002845 discoloration Methods 0.000 claims description 4
239000006260 foam Substances 0.000 claims description 4
238000012546 transfer Methods 0.000 claims description 4
238000005260 corrosion Methods 0.000 claims description 3
230000007797 corrosion Effects 0.000 claims description 3
229920002545 silicone oil Polymers 0.000 claims description 3
DIIBXMIIOQXTHW-UHFFFAOYSA-N pirozadil Chemical compound COC1=C(OC)C(OC)=CC(C(=O)OCC=2N=C(COC(=O)C=3C=C(OC)C(OC)=C(OC)C=3)C=CC=2)=C1 DIIBXMIIOQXTHW-UHFFFAOYSA-N 0.000 claims 1
229950008646 pirozadil Drugs 0.000 claims 1
239000003826 tablet Substances 0.000 description 165
239000000203 mixture Substances 0.000 description 51
239000002253 acid Substances 0.000 description 31
235000010980 cellulose Nutrition 0.000 description 31
239000010457 zeolite Substances 0.000 description 29
150000003839 salts Chemical class 0.000 description 27
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 25
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 23
229910021536 Zeolite Inorganic materials 0.000 description 22
239000010410 layer Substances 0.000 description 21
229940088598 enzyme Drugs 0.000 description 19
150000007513 acids Chemical class 0.000 description 18
125000004432 carbon atom Chemical group C* 0.000 description 18
235000019441 ethanol Nutrition 0.000 description 18
239000003921 oil Substances 0.000 description 17
235000019832 sodium triphosphate Nutrition 0.000 description 17
238000005406 washing Methods 0.000 description 16
239000011734 sodium Substances 0.000 description 14
229910052708 sodium Inorganic materials 0.000 description 14
230000000694 effects Effects 0.000 description 13
150000002191 fatty alcohols Chemical class 0.000 description 13
238000011049 filling Methods 0.000 description 13
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
150000001875 compounds Chemical class 0.000 description 11
239000000047 product Substances 0.000 description 11
239000000243 solution Substances 0.000 description 11
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
235000014113 dietary fatty acids Nutrition 0.000 description 10
239000000194 fatty acid Substances 0.000 description 10
229930195729 fatty acid Natural products 0.000 description 10
150000004760 silicates Chemical class 0.000 description 10
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
229920002245 Dextrose equivalent Polymers 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
150000001298 alcohols Chemical class 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
108091005804 Peptidases Proteins 0.000 description 8
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
239000004365 Protease Substances 0.000 description 8
239000000463 material Substances 0.000 description 8
239000011591 potassium Substances 0.000 description 8
229910052700 potassium Inorganic materials 0.000 description 8
239000000843 powder Substances 0.000 description 8
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 8
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
239000012013 faujasite Substances 0.000 description 7
238000005469 granulation Methods 0.000 description 7
230000003179 granulation Effects 0.000 description 7
230000007062 hydrolysis Effects 0.000 description 7
238000006460 hydrolysis reaction Methods 0.000 description 7
230000002366 lipolytic effect Effects 0.000 description 7
229920003023 plastic Polymers 0.000 description 7
239000004033 plastic Substances 0.000 description 7
229920005646 polycarboxylate Polymers 0.000 description 7
238000003825 pressing Methods 0.000 description 7
239000000344 soap Substances 0.000 description 7
239000001226 triphosphate Substances 0.000 description 7
239000004375 Dextrin Substances 0.000 description 6
229920001353 Dextrin Polymers 0.000 description 6
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
108090001060 Lipase Proteins 0.000 description 6
102000004882 Lipase Human genes 0.000 description 6
239000004367 Lipase Substances 0.000 description 6
229910019142 PO4 Inorganic materials 0.000 description 6
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
238000000576 coating method Methods 0.000 description 6
239000000470 constituent Substances 0.000 description 6
235000019425 dextrin Nutrition 0.000 description 6
150000004665 fatty acids Chemical class 0.000 description 6
235000019421 lipase Nutrition 0.000 description 6
235000021317 phosphate Nutrition 0.000 description 6
235000011007 phosphoric acid Nutrition 0.000 description 6
239000001488 sodium phosphate Substances 0.000 description 6
108010059892 Cellulase Proteins 0.000 description 5
108010084185 Cellulases Proteins 0.000 description 5
102000005575 Cellulases Human genes 0.000 description 5
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 5
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 5
239000000654 additive Substances 0.000 description 5
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
239000011248 coating agent Substances 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 5
239000010419 fine particle Substances 0.000 description 5
125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
239000000178 monomer Substances 0.000 description 5
150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
235000019419 proteases Nutrition 0.000 description 5
230000002829 reductive effect Effects 0.000 description 5
159000000000 sodium salts Chemical class 0.000 description 5
238000003860 storage Methods 0.000 description 5
239000003760 tallow Substances 0.000 description 5
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
108010065511 Amylases Proteins 0.000 description 4
102000013142 Amylases Human genes 0.000 description 4
235000008733 Citrus aurantifolia Nutrition 0.000 description 4
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
102000004157 Hydrolases Human genes 0.000 description 4
108090000604 Hydrolases Proteins 0.000 description 4
239000004115 Sodium Silicate Substances 0.000 description 4
235000011941 Tilia x europaea Nutrition 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
150000001408 amides Chemical class 0.000 description 4
235000019418 amylase Nutrition 0.000 description 4
239000004305 biphenyl Substances 0.000 description 4
229940106157 cellulase Drugs 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
239000001177 diphosphate Substances 0.000 description 4
238000004851 dishwashing Methods 0.000 description 4
238000009826 distribution Methods 0.000 description 4
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
239000008103 glucose Substances 0.000 description 4
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
239000004571 lime Substances 0.000 description 4
235000019796 monopotassium phosphate Nutrition 0.000 description 4
229910000402 monopotassium phosphate Inorganic materials 0.000 description 4
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
229920001223 polyethylene glycol Polymers 0.000 description 4
229920006324 polyoxymethylene Polymers 0.000 description 4
BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 4
239000004753 textile Substances 0.000 description 4
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
244000060011 Cocos nucifera Species 0.000 description 3
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DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 3
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JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 3
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238000005056 compaction Methods 0.000 description 3
150000004691 decahydrates Chemical class 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
230000003111 delayed effect Effects 0.000 description 3
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
235000011180 diphosphates Nutrition 0.000 description 3
ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 3
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238000000227 grinding Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
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235000019271 petrolatum Nutrition 0.000 description 3
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235000011009 potassium phosphates Nutrition 0.000 description 3
235000019828 potassium polyphosphate Nutrition 0.000 description 3
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
AQMNWCRSESPIJM-UHFFFAOYSA-M sodium metaphosphate Chemical compound [Na+].[O-]P(=O)=O AQMNWCRSESPIJM-UHFFFAOYSA-M 0.000 description 3
235000019351 sodium silicates Nutrition 0.000 description 3
235000019698 starch Nutrition 0.000 description 3
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FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 3
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229910000406 trisodium phosphate Inorganic materials 0.000 description 3
ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 description 2
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230000000007 visual effect Effects 0.000 description 1
239000011800 void material Substances 0.000 description 1
ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA 2306724 1999-04-29 2000-04-27 Pastilles de detergent renfermant des liants solides Abandoned CA2306724A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE1999119445 DE19919445A1 (de)	1999-04-29	1999-04-29	Wasch- und Reinigungsmittelformkörper mit festen Bindemitteln
DE19919445.9		1999-04-29

Publications (1)

Publication Number	Publication Date
CA2306724A1 true CA2306724A1 (fr)	2000-10-29

Family

ID=7906235

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2306724 Abandoned CA2306724A1 (fr)	1999-04-29	2000-04-27	Pastilles de detergent renfermant des liants solides

Country Status (5)

Country	Link
AR (1)	AR023622A1 (fr)
AU (1)	AU4402000A (fr)
CA (1)	CA2306724A1 (fr)
DE (1)	DE19919445A1 (fr)
WO (1)	WO2000066698A1 (fr)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4408718A1 (de) *	1994-03-15	1995-09-21	Henkel Kgaa	Bruch- und lagerstabile, polyfunktionelle Reinigungstabletten, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19752601C1 (de) *	1997-11-28	1998-12-10	Henkel Kgaa	Verfahren zur Herstellung von Geschirrspülmitteltabletten
DE19758178A1 (de) *	1997-12-30	1999-07-01	Henkel Kgaa	Geschirrspülmittelformkörper mit Chlorbleichmitteln

1999
- 1999-04-29 DE DE1999119445 patent/DE19919445A1/de not_active Withdrawn
2000
- 2000-04-20 AU AU44020/00A patent/AU4402000A/en not_active Abandoned
- 2000-04-20 WO PCT/EP2000/003598 patent/WO2000066698A1/fr not_active Ceased
- 2000-04-27 CA CA 2306724 patent/CA2306724A1/fr not_active Abandoned
- 2000-04-28 AR ARP000102030 patent/AR023622A1/es unknown

Also Published As

Publication number	Publication date
WO2000066698A1 (fr)	2000-11-09
AR023622A1 (es)	2002-09-04
AU4402000A (en)	2000-11-17
DE19919445A1 (de)	2000-11-02

Legal Events

Date	Code	Title	Description
2002-07-30	FZDE	Dead

Publication	Publication Date	Title
US6329335B1 (en)	2001-12-11	Detergent tablets
US7205266B2 (en)	2007-04-17	Laundry or dishwasher detergent tablet having at least one cavity
CA2307429A1 (fr)	2000-11-03	Pastilles de detergent enduites
CA2315298A1 (fr)	2000-10-29	Article solide de lavage et de nettoyage renfermant un agent de blanchiment
CA2315253A1 (fr)	2000-10-28	Corps forme polyphase avec division optimale de la phase
CA2303638A1 (fr)	2000-09-30	Pastilles de detersif a une ou plusieurs phases renfermant des activateurs de blanchiment particuliers
CA2324070A1 (fr)	2001-04-21	Pastilles de detergent ayant une meilleure resistance a l'abrasion
CA2297443A1 (fr)	2000-07-28	Pastilles de detergent multiphases
CA2304316A1 (fr)	2000-09-30	Pastilles de detersif renfermant des activateurs de blanchiment particuliers
CA2302141A1 (fr)	2000-09-25	Pastille contenant un adjuvant
CA2315303A1 (fr)	2000-10-29	Articles detergents solides ayant des proprietes ameliorees
CA2335039A1 (fr)	2000-12-14	Corps moules detergents et nettoyants a plusieurs phases, contenant un parfum
WO2000014196A1 (fr)	2000-03-16	Pastilles de detergent renfermant des liants
CA2299445A1 (fr)	2000-08-25	Pastilles de detergent anti-abrasives renfermant des additifs solides
CA2300616A1 (fr)	2000-09-11	Pastilles de detergent contenant une combinaison de surfactant, d'agent de blanchiment et d'agent renforcateur
CA2306724A1 (fr)	2000-10-29	Pastilles de detergent renfermant des liants solides
CA2306722A1 (fr)	2000-10-29	Pastilles de detergent renfermant un liant
CN1284125A (zh)	2001-02-14	多相洗涤剂片剂
CA2300017A1 (fr)	2000-08-25	Procede de production de tablettes de detergent a desagregation rapide
CA2298966A1 (fr)	2000-08-20	Tablettes de detergent presentant une stabilite de la couleur
CA2300604A1 (fr)	2000-09-11	Pastilles de detergent renfermant une combinaison de surfactant et d'agent renforcateur
CA2304409A1 (fr)	2000-10-03	Pastilles de detergent contenant des granules particuliers de surfactant
CA2306381A1 (fr)	2000-10-24	Pastilles de detergent contenant des agents de blanchiment
CA2300016A1 (fr)	2000-08-25	Pastille de detergent entreposable
CA2297458A1 (fr)	2000-07-28	Pastilles de detergent anti-abrasives avec une haute teneur en surfactant non ionique