CA2306889C - Procede et dispositif de production de gaz de combustion, de gaz de synthese et de gaz de reduction a partir de combustibles solides - Google Patents
Procede et dispositif de production de gaz de combustion, de gaz de synthese et de gaz de reduction a partir de combustibles solides Download PDFInfo
- Publication number
- CA2306889C CA2306889C CA002306889A CA2306889A CA2306889C CA 2306889 C CA2306889 C CA 2306889C CA 002306889 A CA002306889 A CA 002306889A CA 2306889 A CA2306889 A CA 2306889A CA 2306889 C CA2306889 C CA 2306889C
- Authority
- CA
- Canada
- Prior art keywords
- gas
- combustion chamber
- fuel
- slag
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/50—Fuel charging devices
- C10J3/506—Fuel charging devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/485—Entrained flow gasifiers
- C10J3/487—Swirling or cyclonic gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/52—Ash-removing devices
- C10J3/526—Ash-removing devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/152—Nozzles or lances for introducing gas, liquids or suspensions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Gasification And Melting Of Waste (AREA)
- Treatment Of Sludge (AREA)
- Industrial Gases (AREA)
Abstract
L'invention concerne un procédé et un dispositif permettant de produire des gaz de combustion, de synthèse et de réduction à partir de combustibles fossiles renouvelables, d'autres biomasses, d'ordures ou de boues, ces derniers étant largement séparés, avant leur introduction dans le réacteur, en produits gazeux et en solides, p.ex. en gaz dégagé de distillation lente et en charbon de bois, puis cédés séparément au réacteur. Selon l'invention, le réacteur comprend un brûleur mixte, une chambre de combustion, un gazéificateur de flux de particules, un canal de compensation de température et un bain d'eau. Le brûleur mixte dispose de dispositifs permettant la combustion substoechiométrique des produits gazeux dégagés de distillation lente et de dispositifs de rotation qui lancent par centrifugation les particules fluides sur la paroi de la chambre de combustion. Les gouttelettes de scories fluides tombent dans un bain d'eau. La poussière combustible peut réagir par endothermie avec l'agent de gazéification provenant de la chambre de combustion pour produire un gaz de gazéification. Le coke résiduel est amené à tourbillonner de telle façon qu'il ramène la température de la paroi de la chambre de combustion en-deçà de la température de fusion des scories par absorption thermique par convection. Il se forme alors une couche de protection de scories solidifiées sur la paroi interne de la chambre de combustion.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19747324.5 | 1997-10-28 | ||
| DE19747324A DE19747324C2 (de) | 1997-10-28 | 1997-10-28 | Vorrichtung zur Erzeugung von Brenn-, Synthese- und Reduktionsgas aus nachwachsenden und fossilen Brennstoffen, Biomassen, Müll oder Schlämmen |
| PCT/EP1998/006342 WO1999021940A1 (fr) | 1997-10-28 | 1998-10-06 | Procede et dispositif de production de gaz de combustion, de gaz de synthese et de gaz de reduction a partir de combustibles solides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2306889A1 CA2306889A1 (fr) | 1999-05-06 |
| CA2306889C true CA2306889C (fr) | 2008-12-16 |
Family
ID=7846707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002306889A Expired - Fee Related CA2306889C (fr) | 1997-10-28 | 1998-10-06 | Procede et dispositif de production de gaz de combustion, de gaz de synthese et de gaz de reduction a partir de combustibles solides |
Country Status (20)
| Country | Link |
|---|---|
| EP (1) | EP1027407B1 (fr) |
| JP (1) | JP4112173B2 (fr) |
| CN (1) | CN1136299C (fr) |
| AR (1) | AR010952A1 (fr) |
| AT (1) | ATE200791T1 (fr) |
| AU (1) | AU754147B2 (fr) |
| BR (1) | BR9813292B1 (fr) |
| CA (1) | CA2306889C (fr) |
| DE (2) | DE19747324C2 (fr) |
| DK (1) | DK1027407T3 (fr) |
| ES (1) | ES2157673T3 (fr) |
| GR (1) | GR3036233T3 (fr) |
| ID (1) | ID21135A (fr) |
| MY (1) | MY127842A (fr) |
| NO (1) | NO328487B1 (fr) |
| PL (1) | PL190794B1 (fr) |
| PT (1) | PT1027407E (fr) |
| TW (1) | TW518363B (fr) |
| WO (1) | WO1999021940A1 (fr) |
| ZA (1) | ZA989759B (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2010328844B2 (en) * | 2009-12-10 | 2014-04-24 | Sk Innovation Co., Ltd. | Top-feeding double-swirl type gasifier |
| US9234148B2 (en) | 2009-03-04 | 2016-01-12 | Thyssenkrupp Industrial Solution Ag | Process and apparatus for the utilization of the enthalpy of a syngas by additional and post-gasification of renewable fuels |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19906891C2 (de) * | 1999-02-19 | 2002-07-18 | Schwarze Pumpe Energiewerke Ag | Verfahren zur Verwertung von staubförmigen und schlammartigen kohlenstoffhaltigen Stoffen in der Festbettvergasung |
| US6911058B2 (en) * | 2001-07-09 | 2005-06-28 | Calderon Syngas Company | Method for producing clean energy from coal |
| DE102005006305B4 (de) * | 2005-02-11 | 2015-11-26 | Consulting & Management Friess Gbr (Vertretungsberechtigte Gesellschafter: Dietmar J. Friess 14532 Kleinmachnow, Jessica Friess 14532 Kleinmachnow) | Verfahren zur Erzeugung von Brenn- und Synthesegasen mit Hochdruckdampferzeugung |
| US7819070B2 (en) | 2005-07-15 | 2010-10-26 | Jc Enviro Enterprises Corp. | Method and apparatus for generating combustible synthesis gas |
| DE102005035988B4 (de) * | 2005-07-28 | 2009-01-02 | Wolf, Bodo Max, Dr.-Ing. | Verfahren zur Erzeugung von flüssigen Kohlenwasserstoffen aus Gas |
| DE102005035921B4 (de) * | 2005-07-28 | 2008-07-10 | Choren Industries Gmbh | Verfahren zur endothermen Vergasung von Kohlenstoff |
| US20070225382A1 (en) * | 2005-10-14 | 2007-09-27 | Van Den Berg Robert E | Method for producing synthesis gas or a hydrocarbon product |
| CA2632915C (fr) * | 2005-12-14 | 2014-09-30 | Shell Internationale Research Maatschappij B.V. | Procede de fabrication d'un gaz de synthese |
| CN1935951B (zh) * | 2006-09-21 | 2010-12-08 | 武汉凯迪工程技术研究总院有限公司 | 一种固体含碳原料的高温气化装置 |
| DE102007012452B4 (de) | 2007-03-15 | 2014-01-16 | SynCraft Enegineering GmbH | Vergaser |
| FI122860B (fi) * | 2007-05-25 | 2012-08-15 | Gasek Oy | Menetelmä kiinteän polttoaineen kaasuttamiseksi ja myötävirtakaasutin |
| EP2238223B1 (fr) | 2008-01-28 | 2015-08-26 | Shell Internationale Research Maatschappij B.V. | Procédé pour le démarrage d'un réacteur de gazéification du charbon |
| DE102008027336B4 (de) * | 2008-06-07 | 2010-07-08 | Karlsruher Institut für Technologie | Vorrichtung und Verfahren zur Bestimmung einer Partikelumwandlungsintensität |
| DE102008033096A1 (de) * | 2008-07-15 | 2010-02-11 | Uhde Gmbh | Verfahren und Vorrichtung zum Zünden und zum Betrieb von Brennern bei der Vergasung kohlenstoffhaltiger Brennstoffe |
| DE102008035295B4 (de) * | 2008-07-29 | 2013-10-17 | Siemens Aktiengesellschaft | Kohlenmonoxid-Konvertierung mittels gestufter Quenchung |
| DE102008049716A1 (de) * | 2008-09-30 | 2010-04-08 | Siemens Aktiengesellschaft | Nutzung der fühlbaren Wärme des Rohgases bei der Flugstromvergasung |
| US8357215B2 (en) | 2009-03-04 | 2013-01-22 | General Electric Company | Method and apparatus of particulate removal from gasifier components |
| DE102009011174A1 (de) | 2009-03-04 | 2010-09-09 | Uhde Gmbh | Verfahren und Vorrichtung zur Nutzung der Enthalpie eines Synthesegases zur Zusatzvergasung von nachwachsenden Brennstoffen |
| DE102010008384A1 (de) | 2010-02-17 | 2011-08-18 | Uhde GmbH, 44141 | Verfahren und Vorrichtung zur Nutzung der Enthalpie eines Synthesegases durch Zugabe von nachwachsenden Brennstoffen in den Abkühlraum einer Flugstromvergasung |
| JP4486699B1 (ja) * | 2009-11-06 | 2010-06-23 | 株式会社リ・サイエンスシステム研究所 | 水素ガスの発生を伴う有機性廃棄物の改質方法および有機性廃棄物改質用装置 |
| DE102010033646B4 (de) * | 2010-02-05 | 2012-05-24 | Pyrox Gmbh | Verfahren und Schachtvergaser zur Erzeugung von Brenngas aus einem festen Brennstoff |
| US8480769B2 (en) * | 2010-07-29 | 2013-07-09 | Air Products And Chemicals, Inc. | Method for gasification and a gasifier |
| DE102011008187B4 (de) * | 2011-01-10 | 2015-08-27 | Suncoal Industries Gmbh | Verfahren zur Erzeugung von Brenn- und Syntheserohgas |
| DE102011107726B4 (de) | 2011-07-14 | 2016-06-30 | Thyssenkrupp Industrial Solutions Ag | Vorrichtung und Verfahren zum Einleiten von nachwachsenden Brennstoffen in den Bereich der Strahlungskesselwand von Vergasungsreaktoren |
| CN102399590B (zh) * | 2011-10-08 | 2014-02-19 | 湖北双环科技股份有限公司 | 一种富氧气化的生产方法 |
| US20130330236A1 (en) * | 2012-06-12 | 2013-12-12 | General Electric Company | System for initiating a gasification reaction in a gasifier |
| CN103589460A (zh) * | 2012-08-16 | 2014-02-19 | 王庆 | 设置点火炉头的废锅流程水冷壁水煤浆气化炉 |
| DE102014219455B4 (de) | 2013-09-25 | 2019-08-14 | Technische Universität Bergakademie Freiberg | Verfahren und Vorrichtung zur Teilkonvertierung von Rohgasen der Flugstromvergasung |
| CN104019460B (zh) * | 2014-06-20 | 2016-08-24 | 航天长征化学工程股份有限公司 | 一种水冷壁气化炉挂渣方法及设备 |
| CN104403694B (zh) * | 2014-10-16 | 2017-02-15 | 煤炭科学技术研究院有限公司 | 一种固定床气化炉的液态连续排渣器及排渣方法 |
| CN105482852B (zh) * | 2015-11-20 | 2018-03-30 | 新奥科技发展有限公司 | 一种气化炉及煤加氢气化方法 |
| CN108473896B (zh) * | 2015-12-16 | 2021-10-15 | 气体产品与化学公司 | 气化系统及工艺 |
| DE102017005627A1 (de) | 2016-10-07 | 2018-04-12 | Lennart Feldmann | Verfahren und System zur Verbesserung der Treibhausgas-Emissionsminderungsleistung biogener Kraft-, Heiz- und Brennstoffe und/oder zur Anreicherung landwirtschaftlich genutzter Flächen mit Humus-C |
| JP6847702B2 (ja) * | 2017-02-17 | 2021-03-24 | 三菱パワー株式会社 | フィルタ付ノズル、ガス化複合発電装置、フィルタ付ノズルにおけるフィルタの取り外し方法 |
| CN107129833B (zh) * | 2017-06-23 | 2024-03-29 | 航天长征化学工程股份有限公司 | 一种环形粉煤腔 |
| CN107674712B (zh) * | 2017-11-13 | 2019-09-06 | 煤炭科学技术研究院有限公司 | 一种固定床熔渣气化炉 |
| CN107892952B (zh) * | 2017-11-13 | 2019-09-06 | 煤炭科学技术研究院有限公司 | 一种两段式熔渣气化炉 |
| RO134445B1 (ro) * | 2020-05-18 | 2021-06-30 | Bogdan-Sabin Frâncu | Procedeu şi instalaţie de gazeificare a amestecurilor eterogene de substanţe şi compuşi organici |
| WO2022040389A1 (fr) * | 2020-08-19 | 2022-02-24 | The Regents Of The University Of California | Réaction chimique et conversion dans des réacteurs chimiques thermiquement hétérogènes et à l'état non stable |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3840354A (en) * | 1972-03-23 | 1974-10-08 | Us Interior | Three-stage gasification of coal |
| US4272255A (en) * | 1979-07-19 | 1981-06-09 | Mountain Fuel Resources, Inc. | Apparatus for gasification of carbonaceous solids |
| FR2530796A1 (fr) * | 1982-07-21 | 1984-01-27 | Creusot Loire | Dispositif de conversion et de recuperation thermique |
| JPS59176391A (ja) * | 1983-03-28 | 1984-10-05 | Hitachi Ltd | 石炭ガス化炉 |
| US4647294A (en) * | 1984-03-30 | 1987-03-03 | Texaco Development Corp. | Partial oxidation apparatus |
| JPS62236891A (ja) * | 1986-04-09 | 1987-10-16 | Hitachi Ltd | 石炭ガス化炉の石炭ガス化方法 |
| EP0545241B1 (fr) * | 1991-11-29 | 1996-02-28 | Noell Energie- und Entsorgungstechnik GmbH | Procédé pour la valorisation thermique de déchets |
| DE4404673C2 (de) * | 1994-02-15 | 1995-11-23 | Entec Recycling Und Industriea | Verfahren zur Erzeugung von Brenngas |
-
1997
- 1997-10-28 DE DE19747324A patent/DE19747324C2/de not_active Expired - Fee Related
-
1998
- 1998-10-06 AT AT98949009T patent/ATE200791T1/de active
- 1998-10-06 DK DK98949009T patent/DK1027407T3/da active
- 1998-10-06 CA CA002306889A patent/CA2306889C/fr not_active Expired - Fee Related
- 1998-10-06 EP EP98949009A patent/EP1027407B1/fr not_active Expired - Lifetime
- 1998-10-06 ES ES98949009T patent/ES2157673T3/es not_active Expired - Lifetime
- 1998-10-06 CN CNB988106574A patent/CN1136299C/zh not_active Expired - Fee Related
- 1998-10-06 PT PT80401413T patent/PT1027407E/pt unknown
- 1998-10-06 BR BRPI9813292-0A patent/BR9813292B1/pt not_active IP Right Cessation
- 1998-10-06 JP JP2000518034A patent/JP4112173B2/ja not_active Expired - Fee Related
- 1998-10-06 PL PL340217A patent/PL190794B1/pl unknown
- 1998-10-06 AU AU95427/98A patent/AU754147B2/en not_active Ceased
- 1998-10-06 WO PCT/EP1998/006342 patent/WO1999021940A1/fr not_active Ceased
- 1998-10-06 DE DE59800654T patent/DE59800654D1/de not_active Expired - Lifetime
- 1998-10-16 MY MYPI98004746A patent/MY127842A/en unknown
- 1998-10-23 ID IDP981403A patent/ID21135A/id unknown
- 1998-10-27 ZA ZA989759A patent/ZA989759B/xx unknown
- 1998-10-28 TW TW087117842A patent/TW518363B/zh active
- 1998-10-28 AR ARP980105392A patent/AR010952A1/es unknown
-
2000
- 2000-04-17 NO NO20001993A patent/NO328487B1/no not_active IP Right Cessation
-
2001
- 2001-07-18 GR GR20010401085T patent/GR3036233T3/el not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9234148B2 (en) | 2009-03-04 | 2016-01-12 | Thyssenkrupp Industrial Solution Ag | Process and apparatus for the utilization of the enthalpy of a syngas by additional and post-gasification of renewable fuels |
| AU2010328844B2 (en) * | 2009-12-10 | 2014-04-24 | Sk Innovation Co., Ltd. | Top-feeding double-swirl type gasifier |
| AU2010328844A8 (en) * | 2009-12-10 | 2014-05-22 | Sk Innovation Co., Ltd. | Top-feeding double-swirl type gasifier |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1027407B1 (fr) | 2001-04-25 |
| DE59800654D1 (de) | 2001-05-31 |
| NO20001993L (no) | 2000-06-15 |
| AU9542798A (en) | 1999-05-17 |
| PT1027407E (pt) | 2001-10-30 |
| AR010952A1 (es) | 2000-07-12 |
| DK1027407T3 (da) | 2001-08-13 |
| TW518363B (en) | 2003-01-21 |
| EP1027407A1 (fr) | 2000-08-16 |
| DE19747324C2 (de) | 1999-11-04 |
| CN1278292A (zh) | 2000-12-27 |
| PL190794B1 (pl) | 2006-01-31 |
| BR9813292A (pt) | 2000-08-22 |
| CN1136299C (zh) | 2004-01-28 |
| JP4112173B2 (ja) | 2008-07-02 |
| JP2001521056A (ja) | 2001-11-06 |
| PL340217A1 (en) | 2001-01-15 |
| DE19747324A1 (de) | 1999-04-29 |
| NO20001993D0 (no) | 2000-04-17 |
| ATE200791T1 (de) | 2001-05-15 |
| ID21135A (id) | 1999-04-29 |
| BR9813292B1 (pt) | 2009-12-01 |
| CA2306889A1 (fr) | 1999-05-06 |
| ZA989759B (en) | 1999-05-03 |
| GR3036233T3 (en) | 2001-10-31 |
| NO328487B1 (no) | 2010-03-01 |
| MY127842A (en) | 2006-12-29 |
| ES2157673T3 (es) | 2001-08-16 |
| AU754147B2 (en) | 2002-11-07 |
| WO1999021940A1 (fr) | 1999-05-06 |
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