CA2312378A1 - Electrode en fibres de carbone pour batterie secondaire - Google Patents
Electrode en fibres de carbone pour batterie secondaire Download PDFInfo
- Publication number
- CA2312378A1 CA2312378A1 CA002312378A CA2312378A CA2312378A1 CA 2312378 A1 CA2312378 A1 CA 2312378A1 CA 002312378 A CA002312378 A CA 002312378A CA 2312378 A CA2312378 A CA 2312378A CA 2312378 A1 CA2312378 A1 CA 2312378A1
- Authority
- CA
- Canada
- Prior art keywords
- carbon
- precursor
- range
- electrode
- heat treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 32
- 239000000835 fiber Substances 0.000 title claims description 15
- 239000002243 precursor Substances 0.000 claims abstract description 39
- 229920000297 Rayon Polymers 0.000 claims abstract description 18
- 239000002964 rayon Substances 0.000 claims abstract description 15
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 12
- 239000003792 electrolyte Substances 0.000 claims abstract description 11
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 39
- 239000004917 carbon fiber Substances 0.000 claims description 39
- 239000004744 fabric Substances 0.000 claims description 28
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 229920002678 cellulose Polymers 0.000 claims description 9
- 239000001913 cellulose Substances 0.000 claims description 9
- 239000007833 carbon precursor Substances 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 7
- 230000001131 transforming effect Effects 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 150000002642 lithium compounds Chemical class 0.000 claims 1
- 150000002902 organometallic compounds Chemical class 0.000 claims 1
- 150000003961 organosilicon compounds Chemical group 0.000 claims 1
- 238000009941 weaving Methods 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052744 lithium Inorganic materials 0.000 abstract description 10
- 210000004027 cell Anatomy 0.000 description 18
- 238000003780 insertion Methods 0.000 description 14
- -1 LiCo02 Chemical class 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 9
- 230000037431 insertion Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 206010040844 Skin exfoliation Diseases 0.000 description 3
- 238000004299 exfoliation Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 229910032387 LiCoO2 Inorganic materials 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000005087 graphitization Methods 0.000 description 2
- 150000002484 inorganic compounds Chemical group 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000000235 small-angle X-ray scattering Methods 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910014549 LiMn204 Inorganic materials 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 238000009656 pre-carbonization Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
Le carbone des fibres présente une distance inter-réticulaire moyenne (d¿002?) au moins égale à 0,36 nm, de préférence 0,38 nm, a une taille de cristallite telle que la hauteur moyenne (L¿c?) est comprise entre 0,7 nm et 3 nm et la dimension latérale moyenne (L¿a?) est comprise entre 2 nm et 6 nm, et présente une porosité totale comprise entre 10 % et 30 %. L'électrode est de préférence en tissu de carbone à précurseur rayonne et constitue une anode (10) d'une batterie secondaire ayant une cathode (20) qui comprend du lithium, permettant l'insertion et la désinsertion d'ions lithium, et un électrolyte (30).
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR97/15142 | 1997-12-02 | ||
| FR9715142A FR2771856B1 (fr) | 1997-12-02 | 1997-12-02 | Electrode en fibres de carbone pour batterie secondaire |
| PCT/FR1998/002580 WO1999028983A1 (fr) | 1997-12-02 | 1998-12-01 | Electrode en fibres de carbone pour batterie secondaire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2312378A1 true CA2312378A1 (fr) | 1999-06-10 |
Family
ID=9514044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002312378A Abandoned CA2312378A1 (fr) | 1997-12-02 | 1998-12-01 | Electrode en fibres de carbone pour batterie secondaire |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6361900B1 (fr) |
| EP (1) | EP1036420B1 (fr) |
| JP (1) | JP2001525595A (fr) |
| CA (1) | CA2312378A1 (fr) |
| DE (1) | DE69804247D1 (fr) |
| FR (1) | FR2771856B1 (fr) |
| WO (1) | WO1999028983A1 (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1652247A4 (fr) * | 2003-07-28 | 2009-08-19 | Showa Denko Kk | Electrode haute densite et batterie utilisant ladite electrode |
| US20070077496A1 (en) * | 2005-10-05 | 2007-04-05 | Medtronic, Inc. | Lithium-ion battery |
| US8017273B2 (en) | 2008-04-28 | 2011-09-13 | Ut-Battelle Llc | Lightweight, durable lead-acid batteries |
| CN109888168B (zh) * | 2019-01-12 | 2022-07-12 | 欣旺达电动汽车电池有限公司 | 一种正极及其制备方法和具有该正极的电池 |
| US11686011B2 (en) | 2019-11-19 | 2023-06-27 | University Of Central Florida Research Foundation, Inc. | Vertically-aligned graphene-carbon fiber hybrid electrodes and methods for making same |
| US12094654B2 (en) | 2020-11-04 | 2024-09-17 | University Of Central Florida Research Foundation, Inc. | Storing energy in carbon fiber-based electric vehicle body panels |
| WO2023022785A1 (fr) * | 2021-08-16 | 2023-02-23 | University Of Central Florida Research Foundation, Inc. | Composite à base de fibres de carbone à double fonction formant supercondensateur de stockage d'énergie pour panneaux de carrosserie d'un véhicule |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62154461A (ja) * | 1985-12-26 | 1987-07-09 | Toho Rayon Co Ltd | 電極材用活性炭素繊維 |
| US4861690A (en) | 1988-06-06 | 1989-08-29 | Ope Henry F | Lightweight battery construction |
| CA2043472A1 (fr) * | 1990-06-04 | 1991-12-05 | Mitsutaka Miyabayashi | Electrode pour batterie secondaire |
| EP0552731B1 (fr) * | 1992-01-20 | 1996-09-18 | Unitika Ltd. | Matériau carboné et cellule le contenant |
| JP3653105B2 (ja) * | 1993-02-25 | 2005-05-25 | 呉羽化学工業株式会社 | 二次電池電極用炭素質材料 |
| CA2122770C (fr) * | 1994-05-03 | 2000-10-03 | Moli Energy (1990) Limited | Substances carbonees hotes et leur utilisation comme anodes dans les piles rechargeables |
| US5518836A (en) | 1995-01-13 | 1996-05-21 | Mccullough; Francis P. | Flexible carbon fiber, carbon fiber electrode and secondary energy storage devices |
| DE69602405T2 (de) * | 1995-10-03 | 1999-12-16 | Kureha Kagaku Kogyo K.K., Tokio/Tokyo | Elektrodenmaterial aus Kohlenstoff für Sekundärbatterie und Verfahren zu seiner Herstellung |
-
1997
- 1997-12-02 FR FR9715142A patent/FR2771856B1/fr not_active Expired - Fee Related
-
1998
- 1998-12-01 US US09/555,499 patent/US6361900B1/en not_active Expired - Fee Related
- 1998-12-01 WO PCT/FR1998/002580 patent/WO1999028983A1/fr not_active Ceased
- 1998-12-01 JP JP2000523718A patent/JP2001525595A/ja not_active Withdrawn
- 1998-12-01 DE DE69804247T patent/DE69804247D1/de not_active Expired - Lifetime
- 1998-12-01 EP EP98958289A patent/EP1036420B1/fr not_active Expired - Lifetime
- 1998-12-01 CA CA002312378A patent/CA2312378A1/fr not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1036420A1 (fr) | 2000-09-20 |
| EP1036420B1 (fr) | 2002-03-13 |
| US6361900B1 (en) | 2002-03-26 |
| JP2001525595A (ja) | 2001-12-11 |
| WO1999028983A1 (fr) | 1999-06-10 |
| DE69804247D1 (de) | 2002-04-18 |
| FR2771856A1 (fr) | 1999-06-04 |
| FR2771856B1 (fr) | 2000-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |