CA2356221A1 - Methode de fabrication de pieces moulees par rotation comprenant des nanoparticules de renforcement - Google Patents
Methode de fabrication de pieces moulees par rotation comprenant des nanoparticules de renforcement Download PDFInfo
- Publication number
- CA2356221A1 CA2356221A1 CA002356221A CA2356221A CA2356221A1 CA 2356221 A1 CA2356221 A1 CA 2356221A1 CA 002356221 A CA002356221 A CA 002356221A CA 2356221 A CA2356221 A CA 2356221A CA 2356221 A1 CA2356221 A1 CA 2356221A1
- Authority
- CA
- Canada
- Prior art keywords
- reinforcing particles
- particles
- thermoplastic
- molten material
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 230000002787 reinforcement Effects 0.000 title description 25
- 239000002105 nanoparticle Substances 0.000 title description 22
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000002245 particle Substances 0.000 claims abstract description 67
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 22
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 22
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 22
- 239000012768 molten material Substances 0.000 claims abstract description 21
- 239000006185 dispersion Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 239000008188 pellet Substances 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 16
- 229920005989 resin Polymers 0.000 description 16
- 239000011347 resin Substances 0.000 description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 description 13
- 239000011707 mineral Substances 0.000 description 13
- 239000003365 glass fiber Substances 0.000 description 9
- 229920000098 polyolefin Polymers 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- -1 polyethylenes Polymers 0.000 description 7
- 238000001175 rotational moulding Methods 0.000 description 7
- 239000000945 filler Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 229920002397 thermoplastic olefin Polymers 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000002952 polymeric resin Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229920003247 engineering thermoplastic Polymers 0.000 description 2
- 238000004299 exfoliation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 229920006380 polyphenylene oxide Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 229910000275 saponite Inorganic materials 0.000 description 2
- 229910052604 silicate mineral Inorganic materials 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920007019 PC/ABS Polymers 0.000 description 1
- 229920001944 Plastisol Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000009725 powder blending Methods 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
- B29C41/042—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould by rotating a mould around its axis of symmetry
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
L'invention concerne un procédé de production d'articles renforcés, qui consiste à: a) préparer une composition en poudre d'au moins un matériau thermoplastique et d'environ 2 à 15 % en volume de particules de renforcement. Ces particules de renforcement sont dispersées de manière sensiblement uniforme dans le matériau thermoplastique. Au moins 50 % des particules de renforcement ont une épaisseur inférieure à environ 20 couches, et les couches de particules de renforcement présentent une épaisseur des unités comprise entre environ 0,7 et 1,2 nm; b) chauffer la poudre pour la transformer en une matière fondue; c) imprimer des rotations à la matière fondue dans une cavité du moule pour amener cette dernière à épouser les forme des surfaces de la cavité du moule, la matière fondue ayant une uniformité de dispersion sensiblement identique à celle des particules de renforcement qu'elle renferme, par comparaison avec l'uniformité de dispersion des particules de renforcement renfermées dans la poudre thermoplastique; et d) refroidir la matière fondue pour former un article renforcé.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11313298P | 1998-12-21 | 1998-12-21 | |
| US60/113,132 | 1998-12-21 | ||
| PCT/US1999/029986 WO2000037241A1 (fr) | 1998-12-21 | 1999-12-17 | Procede de production de pieces moulees par rotation comprenant des nanoparticules de renforcement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2356221A1 true CA2356221A1 (fr) | 2000-06-29 |
Family
ID=22347731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002356221A Abandoned CA2356221A1 (fr) | 1998-12-21 | 1999-12-17 | Methode de fabrication de pieces moulees par rotation comprenant des nanoparticules de renforcement |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU2365600A (fr) |
| CA (1) | CA2356221A1 (fr) |
| WO (1) | WO2000037241A1 (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6668457B1 (en) | 1999-12-10 | 2003-12-30 | L&L Products, Inc. | Heat-activated structural foam reinforced hydroform |
| US6482486B1 (en) | 2000-03-14 | 2002-11-19 | L&L Products | Heat activated reinforcing sleeve |
| US6729425B2 (en) | 2001-09-05 | 2004-05-04 | L&L Products, Inc. | Adjustable reinforced structural assembly and method of use therefor |
| US7169344B2 (en) | 2002-04-26 | 2007-01-30 | L&L Products, Inc. | Method of reinforcing at least a portion of a structure |
| US7144441B2 (en) * | 2003-07-03 | 2006-12-05 | General Electric Company | Process for producing materials reinforced with nanoparticles and articles formed thereby |
| US7700670B2 (en) | 2005-05-13 | 2010-04-20 | Beach Brian A | Low-density molding compound |
| CN105295325B (zh) | 2014-06-27 | 2019-12-27 | 康廷南拓结构塑料有限公司 | 包括表面改性的微球体的低密度模塑料 |
| ES2629409T3 (es) * | 2015-06-09 | 2017-08-09 | Hobas Engineering Gmbh | Procedimiento para la fabricación de un tubo multicapa que contiene microfibras, así como dicho tubo |
| CN114986768B (zh) * | 2022-05-20 | 2024-08-27 | 厦门迈勒滚塑有限公司 | 一种高刚性滚塑船体的成型工艺 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3510625C2 (de) * | 1985-03-23 | 1987-02-19 | Dow Chemical GmbH, 2160 Stade | Schleudergußverfahren zum Herstellen von faserverstärkten Kunststoffrohren und faserverstärktes Kunststoffrohr |
| NZ215525A (en) * | 1985-03-23 | 1988-07-28 | Dow Chemical Gmbh | Making fibre reinforced plastics pipes by centrifugal casting |
| US4739007A (en) * | 1985-09-30 | 1988-04-19 | Kabushiki Kaisha Toyota Chou Kenkyusho | Composite material and process for manufacturing same |
| JP2674720B2 (ja) * | 1991-08-12 | 1997-11-12 | アライド−シグナル・インコーポレーテッド | 剥離層状物質の高分子ナノ複合体の溶融加工形成法 |
| CA2332877C (fr) * | 1998-05-22 | 2009-01-06 | Magna International Of America, Inc. | Elements de garniture interieure pour vehicule a moteur |
| WO1999061281A1 (fr) * | 1998-05-22 | 1999-12-02 | Magna International Of America, Inc. | Panneaux exterieurs destines a des vehicules a moteur |
| CA2332870C (fr) * | 1998-05-22 | 2008-12-02 | Magna International Of America, Inc. | Vitre pour vehicule a moteur |
| EP1077837A4 (fr) * | 1998-05-22 | 2004-07-07 | Magna Int America Inc | Carenage frontal a faible epaisseur de paroi destine a un vehicule motorise |
-
1999
- 1999-12-17 AU AU23656/00A patent/AU2365600A/en not_active Abandoned
- 1999-12-17 CA CA002356221A patent/CA2356221A1/fr not_active Abandoned
- 1999-12-17 WO PCT/US1999/029986 patent/WO2000037241A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000037241A9 (fr) | 2000-12-07 |
| WO2000037241A1 (fr) | 2000-06-29 |
| AU2365600A (en) | 2000-07-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |