CA2368258C - Substrats de diffusion gazeuse - Google Patents
Substrats de diffusion gazeuse Download PDFInfo
- Publication number
- CA2368258C CA2368258C CA002368258A CA2368258A CA2368258C CA 2368258 C CA2368258 C CA 2368258C CA 002368258 A CA002368258 A CA 002368258A CA 2368258 A CA2368258 A CA 2368258A CA 2368258 C CA2368258 C CA 2368258C
- Authority
- CA
- Canada
- Prior art keywords
- gas diffusion
- electrode
- diffusion substrate
- membrane
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000009792 diffusion process Methods 0.000 title claims abstract description 84
- 239000000758 substrate Substances 0.000 title claims abstract description 74
- 239000000463 material Substances 0.000 claims abstract description 95
- 239000000945 filler Substances 0.000 claims abstract description 35
- 239000000446 fuel Substances 0.000 claims abstract description 20
- 239000003607 modifier Substances 0.000 claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 49
- 229910052799 carbon Inorganic materials 0.000 claims description 41
- 239000012528 membrane Substances 0.000 claims description 38
- 239000000835 fiber Substances 0.000 claims description 31
- 239000010411 electrocatalyst Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- 229920005597 polymer membrane Polymers 0.000 claims description 10
- 239000004005 microsphere Substances 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000003658 microfiber Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 210000002268 wool Anatomy 0.000 claims description 4
- 239000012494 Quartz wool Substances 0.000 claims description 3
- 229910021485 fumed silica Inorganic materials 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 239000002657 fibrous material Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 239000010970 precious metal Substances 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 64
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 27
- 239000004810 polytetrafluoroethylene Substances 0.000 description 27
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 26
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 13
- 239000003792 electrolyte Substances 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 229910052697 platinum Inorganic materials 0.000 description 12
- 229920000557 Nafion® Polymers 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 238000011068 loading method Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000011236 particulate material Substances 0.000 description 11
- 239000000376 reactant Substances 0.000 description 11
- -1 polytetrafluoroethylene Polymers 0.000 description 10
- 239000006229 carbon black Substances 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229920006358 Fluon Polymers 0.000 description 6
- 239000006230 acetylene black Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000002322 conducting polymer Substances 0.000 description 4
- 229920001940 conductive polymer Polymers 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920009441 perflouroethylene propylene Polymers 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012078 proton-conducting electrolyte Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inert Electrodes (AREA)
- Inorganic Insulating Materials (AREA)
- Photoreceptors In Electrophotography (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fuel Cell (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
L'invention concerne un nouveau substrat de diffusion gazeuse qui comprend une structure poreuse et une matière de charge, caractérisé en ce que la matière de charge comporte une matière de charge de base qui est conductrice en électricité et carbonée ainsi qu'au moins une matière de modification de nature hydrophile par rapport à la matière de charge de base. L'invention concerne également une électrode de diffusion gazeuse comprenant ledit substrat et l'utilisation de ce substrat ou de cette électrode dans une pile à combustible.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9905950.3 | 1999-03-16 | ||
| GBGB9905950.3A GB9905950D0 (en) | 1999-03-16 | 1999-03-16 | Substrates |
| PCT/GB2000/000382 WO2000055933A1 (fr) | 1999-03-16 | 2000-02-09 | Substrats de diffusion gazeuse |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2368258A1 CA2368258A1 (fr) | 2000-09-21 |
| CA2368258C true CA2368258C (fr) | 2009-12-22 |
Family
ID=10849662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002368258A Expired - Fee Related CA2368258C (fr) | 1999-03-16 | 2000-02-09 | Substrats de diffusion gazeuse |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6531240B1 (fr) |
| EP (1) | EP1169743B1 (fr) |
| JP (1) | JP2002539596A (fr) |
| AT (1) | ATE306124T1 (fr) |
| CA (1) | CA2368258C (fr) |
| DE (1) | DE60022993T2 (fr) |
| ES (1) | ES2249245T3 (fr) |
| GB (1) | GB9905950D0 (fr) |
| WO (1) | WO2000055933A1 (fr) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6350539B1 (en) * | 1999-10-25 | 2002-02-26 | General Motors Corporation | Composite gas distribution structure for fuel cell |
| US6649299B2 (en) * | 2000-02-11 | 2003-11-18 | The Texas A&M University System | Gas diffusion electrode with nanosized pores and method for making same |
| AU2001250491A1 (en) | 2000-04-17 | 2001-10-30 | Johnson Matthey Pulic Limited Company | Gas diffusion substrate |
| GB0022895D0 (en) * | 2000-09-19 | 2000-11-01 | Johnson Matthey Plc | Anode structure |
| GB0027119D0 (en) | 2000-11-07 | 2000-12-20 | Johnson Matthey Plc | Gas diffusion substrate |
| US20030091891A1 (en) * | 2001-01-16 | 2003-05-15 | Tomoaki Yoshida | Catalyst composition for cell, gas diffusion layer, and fuel cell comprising the same |
| US7189472B2 (en) * | 2001-03-28 | 2007-03-13 | Kabushiki Kaisha Toshiba | Fuel cell, electrode for fuel cell and a method of manufacturing the same |
| KR100504965B1 (ko) * | 2001-04-27 | 2005-07-29 | 마쯔시다덴기산교 가부시키가이샤 | 연료전지용 전극 및 그 제조방법 |
| GB0112021D0 (en) | 2001-05-17 | 2001-07-11 | Johnson Matthey Plc | Substrate |
| US7144476B2 (en) * | 2002-04-12 | 2006-12-05 | Sgl Carbon Ag | Carbon fiber electrode substrate for electrochemical cells |
| TW558833B (en) * | 2002-09-09 | 2003-10-21 | Ind Tech Res Inst | Gas diffusion electrode and the method for making the same |
| WO2004102722A2 (fr) * | 2003-05-09 | 2004-11-25 | Foamex L.P. | Couche de diffusion gazeuse contenant un melange de particules de carbone |
| JP4293831B2 (ja) * | 2003-05-16 | 2009-07-08 | 三洋電機株式会社 | 燃料電池 |
| DE10340834B4 (de) | 2003-09-04 | 2018-12-06 | Daimler Ag | Membran-Elektroden-Anordnung für eine Brennstoffzelle |
| KR100696462B1 (ko) | 2003-09-26 | 2007-03-19 | 삼성에스디아이 주식회사 | 연료전지용 전극 확산층 |
| DE10345261A1 (de) * | 2003-09-29 | 2005-04-21 | Ballard Power Systems | Polymerelektrolytmembran-Brennstoffzelle mit stabiler Leistung |
| DE10345030A1 (de) * | 2003-09-29 | 2005-04-14 | Daimlerchrysler Ag | Membran-Elektroden-Anordnung für eine Polymerelektrolytmembran-Brennstoffzelle |
| US7550221B2 (en) * | 2003-10-29 | 2009-06-23 | Rolls-Royce Fuel Cell Systems Limited | Gas delivery substrate |
| US20050233202A1 (en) * | 2004-04-20 | 2005-10-20 | Fay Matthew M | Thermoplastic-imbibed diffusion media to help eliminate MEA edge failure |
| GB0413324D0 (en) * | 2004-06-15 | 2004-07-21 | Johnson Matthey Plc | Gas diffusion substrate |
| JP2006219694A (ja) * | 2005-02-08 | 2006-08-24 | Permelec Electrode Ltd | ガス拡散電極 |
| US20070128472A1 (en) * | 2005-10-27 | 2007-06-07 | Tierney T K | Cell Assembly and Casing Assembly for a Power Storage Device |
| US7851557B2 (en) | 2006-06-20 | 2010-12-14 | Lg Chem, Ltd. | Organic/inorganic composite electrolyte membranes using zeolite and fuel cell comprising the same |
| US7669719B2 (en) | 2006-07-05 | 2010-03-02 | General Electric Company | Membrane structure and method of making |
| US20090035657A1 (en) * | 2006-10-23 | 2009-02-05 | Buiel Edward R | Electrode for Hybrid Energy Storage Device and Method of Making Same |
| ES2500167T3 (es) * | 2006-10-23 | 2014-09-30 | Axion Power International, Inc. | Dispositivo de almacenamiento de energía híbrida y método de fabricación del mismo |
| US8202653B2 (en) * | 2006-10-23 | 2012-06-19 | Axion Power International, Inc. | Electrode with reduced resistance grid and hybrid energy storage device having same |
| US20090103242A1 (en) * | 2007-10-19 | 2009-04-23 | Axion Power International, Inc. | Electrode with Reduced Resistance Grid and Hybrid Energy Storage Device Having Same |
| JP5430513B2 (ja) * | 2010-07-08 | 2014-03-05 | 三菱レイヨン株式会社 | 多孔質電極基材及びその製造方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4175165A (en) * | 1977-07-20 | 1979-11-20 | Engelhard Minerals & Chemicals Corporation | Fuel cell system utilizing ion exchange membranes and bipolar plates |
| FR2589787B1 (fr) | 1985-09-27 | 1988-05-20 | Rhone Poulenc Chim Base | Materiau microporeux, procede pour son obtention, et applications notamment a la realisation d'elements cathodiques |
| JPH0626125B2 (ja) * | 1986-04-01 | 1994-04-06 | 田中貴金属工業株式会社 | ガス拡散電極の製造方法 |
| JPH0633480B2 (ja) * | 1986-09-30 | 1994-05-02 | 田中貴金属工業株式会社 | 反応膜・ガス拡散膜の製造方法 |
| JP2588538B2 (ja) * | 1987-08-07 | 1997-03-05 | 田中貴金属工業株式会社 | ガス拡散電極の製造方法 |
| JPH07326361A (ja) * | 1994-05-31 | 1995-12-12 | Toyota Motor Corp | 電極とその製造方法および燃料電池 |
| GB9504713D0 (en) | 1995-03-09 | 1995-04-26 | Johnson Matthey Plc | Improved electrocatalytic material |
| US5863673A (en) * | 1995-12-18 | 1999-01-26 | Ballard Power Systems Inc. | Porous electrode substrate for an electrochemical fuel cell |
| DE69709784T2 (de) * | 1996-02-28 | 2002-08-08 | Johnson Matthey Plc, London | Verwendung von katalytisch aktiven Gasdiffusionselektroden mit Faservliessubstrat in einer Direkt-Methanol-Brennstoffzelle |
| DE19611510A1 (de) | 1996-03-23 | 1997-09-25 | Degussa | Gasdiffusionselektrode für Membranbrennstoffzellen und Verfahren zu ihrer Herstellung |
| JP3773325B2 (ja) * | 1997-03-17 | 2006-05-10 | ジャパンゴアテックス株式会社 | 高分子固体電解質燃料電池用ガス拡散層材料及びその接合体 |
| JP3583897B2 (ja) | 1997-04-11 | 2004-11-04 | 三洋電機株式会社 | 燃料電池 |
| GB9708365D0 (en) | 1997-04-25 | 1997-06-18 | Johnson Matthey Plc | Proton conducting membranes |
| US6103077A (en) * | 1998-01-02 | 2000-08-15 | De Nora S.P.A. | Structures and methods of manufacture for gas diffusion electrodes and electrode components |
-
1999
- 1999-03-16 GB GBGB9905950.3A patent/GB9905950D0/en not_active Ceased
-
2000
- 2000-02-09 AT AT00902732T patent/ATE306124T1/de not_active IP Right Cessation
- 2000-02-09 WO PCT/GB2000/000382 patent/WO2000055933A1/fr not_active Ceased
- 2000-02-09 ES ES00902732T patent/ES2249245T3/es not_active Expired - Lifetime
- 2000-02-09 EP EP00902732A patent/EP1169743B1/fr not_active Expired - Lifetime
- 2000-02-09 JP JP2000605279A patent/JP2002539596A/ja active Pending
- 2000-02-09 US US09/936,547 patent/US6531240B1/en not_active Expired - Lifetime
- 2000-02-09 CA CA002368258A patent/CA2368258C/fr not_active Expired - Fee Related
- 2000-02-09 DE DE60022993T patent/DE60022993T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2249245T3 (es) | 2006-04-01 |
| EP1169743A1 (fr) | 2002-01-09 |
| WO2000055933A1 (fr) | 2000-09-21 |
| DE60022993T2 (de) | 2006-06-22 |
| JP2002539596A (ja) | 2002-11-19 |
| GB9905950D0 (en) | 1999-05-05 |
| EP1169743B1 (fr) | 2005-10-05 |
| US6531240B1 (en) | 2003-03-11 |
| ATE306124T1 (de) | 2005-10-15 |
| DE60022993D1 (de) | 2006-02-16 |
| CA2368258A1 (fr) | 2000-09-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |