CA2420004A1 - Nanofibres de graphite cristallin et procede de production correspondant - Google Patents
Nanofibres de graphite cristallin et procede de production correspondant Download PDFInfo
- Publication number
- CA2420004A1 CA2420004A1 CA002420004A CA2420004A CA2420004A1 CA 2420004 A1 CA2420004 A1 CA 2420004A1 CA 002420004 A CA002420004 A CA 002420004A CA 2420004 A CA2420004 A CA 2420004A CA 2420004 A1 CA2420004 A1 CA 2420004A1
- Authority
- CA
- Canada
- Prior art keywords
- carbon
- nanofibers
- nanofiber
- catalyst
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1278—Carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
- C01P2004/16—Nanowires or nanorods, i.e. solid nanofibres with two nearly equal dimensions between 1-100 nanometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Inorganic Fibers (AREA)
Abstract
L'invention concerne un procédé de production de nanofibres de carbone graphitique sensiblement cristallin constituées de feuilles de graphite. Les feuilles de graphite sont sensiblement parallèles ou sensiblement perpendiculaires à l'axe longitudinal de la nanofibre de carbone. Lorsque les feuilles de graphite doivent être sensiblement parallèles, ces nanofibres de carbones sont produites par mise en contact de catalyseur en masse à base de fer ou bimétallique à base de fer:cuivre, ou de fer:nickel, avec un mélange de monoxyde carbone et d'hydrogène à des températures comprises entre 670 ·C environ et 725 ·C environ pendant une durée effective. Lorsque les feuillets de graphite doivent être sensiblement perpendiculaires, les nanofibres sont produites par l'utilisation d'un catalyseur en masse bimétallique fer:cuivre à des températures comprises entre 550 ·C environ et 670 ·C environ.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/659,441 US6537515B1 (en) | 2000-09-08 | 2000-09-08 | Crystalline graphite nanofibers and a process for producing same |
| US09/659,441 | 2000-09-08 | ||
| US09/902,113 | 2001-07-10 | ||
| US09/902,113 US20020054849A1 (en) | 2000-09-08 | 2001-07-10 | Crystalline graphite nanofibers and a process for producing same |
| PCT/US2001/028199 WO2002020401A1 (fr) | 2000-09-08 | 2001-09-07 | Nanofibres de graphite cristallin et procede de production correspondant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2420004A1 true CA2420004A1 (fr) | 2002-03-14 |
Family
ID=27097820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002420004A Abandoned CA2420004A1 (fr) | 2000-09-08 | 2001-09-07 | Nanofibres de graphite cristallin et procede de production correspondant |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US20020054849A1 (fr) |
| EP (1) | EP1349808A4 (fr) |
| CA (1) | CA2420004A1 (fr) |
| WO (1) | WO2002020401A1 (fr) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6991363B2 (en) * | 2000-04-28 | 2006-01-31 | Premark Feg L.L.C. | Mixer with pivotable bowl |
| US6849245B2 (en) * | 2001-12-11 | 2005-02-01 | Catalytic Materials Llc | Catalysts for producing narrow carbon nanostructures |
| US6927250B2 (en) | 2002-08-15 | 2005-08-09 | Advanced Energy Technology Inc. | Graphite composites and methods of making such composites |
| WO2004035883A2 (fr) * | 2002-10-17 | 2004-04-29 | Nexen Nano Tech Co., Ltd | Nano-carbone fibreux et procede d'elaboration |
| AU2003273074A1 (en) * | 2002-10-17 | 2004-05-04 | Nexen Nano Tech Co., Ltd | Ultra-fine fibrous carbon and preparation method thereof |
| US20050077503A1 (en) * | 2003-07-23 | 2005-04-14 | Takuya Gotou | Dispersion comprising thin particles having a skeleton consisting of carbons, electroconductive coating film, electroconductive composite material, and a process for producing them |
| US20050025695A1 (en) * | 2003-07-28 | 2005-02-03 | Bhabendra Pradhan | Catalyst and process to produce nanocarbon materials in high yield and at high selectivity at reduced reaction temperatures |
| US8541054B2 (en) * | 2003-09-08 | 2013-09-24 | Honda Motor Co., Ltd | Methods for preparation of one-dimensional carbon nanostructures |
| JP2007504086A (ja) * | 2003-09-03 | 2007-03-01 | 本田技研工業株式会社 | 一次元炭素ナノ構造体の製造方法 |
| US20050112050A1 (en) * | 2003-11-21 | 2005-05-26 | Pradhan Bhabendra K. | Process to reduce the pre-reduction step for catalysts for nanocarbon synthesis |
| US8048940B2 (en) * | 2004-07-09 | 2011-11-01 | Vanderbilt University | Reactive graphitic carbon nanofiber reinforced polymeric composites showing enhanced flexural strength |
| US7351360B2 (en) * | 2004-11-12 | 2008-04-01 | International Business Machines Corporation | Self orienting micro plates of thermally conducting material as component in thermal paste or adhesive |
| WO2006093989A2 (fr) * | 2005-03-01 | 2006-09-08 | The Regents Of The University Of California | Preparation d'articles graphitiques |
| JP4197729B2 (ja) * | 2006-12-21 | 2008-12-17 | 昭和電工株式会社 | 炭素繊維および炭素繊維製造用触媒 |
| KR101443222B1 (ko) * | 2007-09-18 | 2014-09-19 | 삼성전자주식회사 | 그라펜 패턴 및 그의 형성방법 |
| US20090226361A1 (en) * | 2008-03-05 | 2009-09-10 | Jessica Campos-Delgado | Cvd-grown graphite nanoribbons |
| MY160277A (en) | 2009-04-17 | 2017-02-28 | Seerstone Llc | Method of producing solid carbon by reducing carbon oxides |
| US9096784B2 (en) * | 2010-07-23 | 2015-08-04 | International Business Machines Corporation | Method and system for allignment of graphite nanofibers for enhanced thermal interface material performance |
| US20120189530A1 (en) * | 2011-01-20 | 2012-07-26 | Eden Energy Ltd. | System And Process For Producing Hydrogen And A Carbon Nanotube Product |
| CN102335628B (zh) * | 2011-07-21 | 2013-04-10 | 南京大学 | 一种负载型纳米双金属复合催化剂及其制备方法 |
| US9257359B2 (en) | 2011-07-22 | 2016-02-09 | International Business Machines Corporation | System and method to process horizontally aligned graphite nanofibers in a thermal interface material used in 3D chip stacks |
| JP6212050B2 (ja) * | 2011-12-22 | 2017-10-11 | スリーエム イノベイティブ プロパティズ カンパニー | 高い光透過を備えた導電性物品 |
| KR20130108816A (ko) * | 2012-03-26 | 2013-10-07 | 삼성에스디아이 주식회사 | 이차 전지 |
| WO2013158158A1 (fr) | 2012-04-16 | 2013-10-24 | Seerstone Llc | Procédé de traitement d'un dégagement gazeux contenant des oxydes de carbone |
| NO2749379T3 (fr) | 2012-04-16 | 2018-07-28 | ||
| EP2838837A4 (fr) | 2012-04-16 | 2015-12-23 | Seerstone Llc | Procédés et structures de réduction d'oxydes de carbone avec des catalyseurs non ferreux |
| US9221685B2 (en) | 2012-04-16 | 2015-12-29 | Seerstone Llc | Methods of capturing and sequestering carbon |
| EP2838839B1 (fr) | 2012-04-16 | 2020-08-12 | Seerstone LLC | Procédé de production de carbone solide par réduction du dioxyde de carbone |
| US9896341B2 (en) | 2012-04-23 | 2018-02-20 | Seerstone Llc | Methods of forming carbon nanotubes having a bimodal size distribution |
| US10815124B2 (en) | 2012-07-12 | 2020-10-27 | Seerstone Llc | Solid carbon products comprising carbon nanotubes and methods of forming same |
| JP6284934B2 (ja) | 2012-07-12 | 2018-02-28 | シーアストーン リミテッド ライアビリティ カンパニー | カーボンナノチューブを含む固体炭素生成物およびそれを形成する方法 |
| JP6025979B2 (ja) | 2012-07-13 | 2016-11-16 | シーアストーン リミテッド ライアビリティ カンパニー | アンモニアおよび固体炭素生成物を形成するための方法およびシステム |
| US9779845B2 (en) | 2012-07-18 | 2017-10-03 | Seerstone Llc | Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same |
| JP2014114205A (ja) * | 2012-11-14 | 2014-06-26 | Toshiba Corp | 炭素材料とその製造方法およびそれを用いた電気化学セルと減酸素装置と冷蔵庫 |
| CN103811773A (zh) * | 2012-11-14 | 2014-05-21 | 株式会社东芝 | 碳材料及其制造方法、电化学电池、减氧装置和冰箱 |
| MX382104B (es) | 2012-11-29 | 2025-03-13 | Seerstone Llc | Reactores y métodos para producir materiales de carbono sólido. |
| US9245813B2 (en) | 2013-01-30 | 2016-01-26 | International Business Machines Corporation | Horizontally aligned graphite nanofibers in etched silicon wafer troughs for enhanced thermal performance |
| US9090004B2 (en) | 2013-02-06 | 2015-07-28 | International Business Machines Corporation | Composites comprised of aligned carbon fibers in chain-aligned polymer binder |
| EP3129321B1 (fr) | 2013-03-15 | 2021-09-29 | Seerstone LLC | Electrodes comprenant du carbone en nanostructure |
| US9586823B2 (en) | 2013-03-15 | 2017-03-07 | Seerstone Llc | Systems for producing solid carbon by reducing carbon oxides |
| US9783421B2 (en) | 2013-03-15 | 2017-10-10 | Seerstone Llc | Carbon oxide reduction with intermetallic and carbide catalysts |
| EP3129135A4 (fr) | 2013-03-15 | 2017-10-25 | Seerstone LLC | Réacteurs, systèmes et procédés de formation de produits solides |
| US9783416B2 (en) | 2013-03-15 | 2017-10-10 | Seerstone Llc | Methods of producing hydrogen and solid carbon |
| US9082744B2 (en) | 2013-07-08 | 2015-07-14 | International Business Machines Corporation | Method for aligning carbon nanotubes containing magnetic nanoparticles in a thermosetting polymer using a magnetic field |
| CN104638275A (zh) * | 2013-11-08 | 2015-05-20 | 株式会社东芝 | 碳材料及其制法、使用其的电化学电池和减氧装置及冰箱 |
| WO2018022999A1 (fr) | 2016-07-28 | 2018-02-01 | Seerstone Llc. | Produits solides en carbone comprenant des nanotubes de carbone comprimés dans un récipient et procédés pour leur formation |
| CN110922742A (zh) * | 2019-10-31 | 2020-03-27 | 深圳市超导新材料有限公司 | 一种新型透明导电膜及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4900483A (en) * | 1987-10-29 | 1990-02-13 | Exxon Research And Engineering Company | Method of producing isotropically reinforced net-shape microcomposites |
| US5413866A (en) * | 1990-10-23 | 1995-05-09 | Baker; R. Terry K. | High performance carbon filament structures |
| US5618875A (en) * | 1990-10-23 | 1997-04-08 | Catalytic Materials Limited | High performance carbon filament structures |
| US5149584A (en) * | 1990-10-23 | 1992-09-22 | Baker R Terry K | Carbon fiber structures having improved interlaminar properties |
| US5458784A (en) * | 1990-10-23 | 1995-10-17 | Catalytic Materials Limited | Removal of contaminants from aqueous and gaseous streams using graphic filaments |
| JP2687794B2 (ja) * | 1991-10-31 | 1997-12-08 | 日本電気株式会社 | 円筒状構造をもつ黒鉛繊維 |
| US6479028B1 (en) * | 2000-04-03 | 2002-11-12 | The Regents Of The University Of California | Rapid synthesis of carbon nanotubes and carbon encapsulated metal nanoparticles by a displacement reaction |
| US6537515B1 (en) * | 2000-09-08 | 2003-03-25 | Catalytic Materials Llc | Crystalline graphite nanofibers and a process for producing same |
-
2001
- 2001-07-10 US US09/902,113 patent/US20020054849A1/en not_active Abandoned
- 2001-09-07 EP EP01968718A patent/EP1349808A4/fr active Pending
- 2001-09-07 CA CA002420004A patent/CA2420004A1/fr not_active Abandoned
- 2001-09-07 WO PCT/US2001/028199 patent/WO2002020401A1/fr not_active Ceased
-
2003
- 2003-07-22 US US10/625,069 patent/US20040071625A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1349808A4 (fr) | 2006-02-01 |
| US20020054849A1 (en) | 2002-05-09 |
| WO2002020401A1 (fr) | 2002-03-14 |
| US20040071625A1 (en) | 2004-04-15 |
| EP1349808A1 (fr) | 2003-10-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued | ||
| FZDE | Discontinued |
Effective date: 20090908 |