CA2435113C - Procede de traitement d'emulsions d'huiles lourdes au moyen d'un melange de naphtha et d'hydrocarbure aliphatique leger - Google Patents
Procede de traitement d'emulsions d'huiles lourdes au moyen d'un melange de naphtha et d'hydrocarbure aliphatique leger Download PDFInfo
- Publication number
- CA2435113C CA2435113C CA002435113A CA2435113A CA2435113C CA 2435113 C CA2435113 C CA 2435113C CA 002435113 A CA002435113 A CA 002435113A CA 2435113 A CA2435113 A CA 2435113A CA 2435113 C CA2435113 C CA 2435113C
- Authority
- CA
- Canada
- Prior art keywords
- naphtha
- bitumen
- aliphatic hydrocarbon
- degrees celsius
- oil phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 73
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 239000000839 emulsion Substances 0.000 title claims abstract description 23
- 239000000295 fuel oil Substances 0.000 title abstract description 3
- 125000001931 aliphatic group Chemical group 0.000 title description 3
- 239000010426 asphalt Substances 0.000 claims abstract description 109
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 31
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 31
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000001273 butane Substances 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 238000009835 boiling Methods 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims description 75
- 238000011084 recovery Methods 0.000 claims description 8
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 239000001282 iso-butane Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 16
- 239000011707 mineral Substances 0.000 abstract description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 150000002739 metals Chemical class 0.000 abstract description 5
- 229910052759 nickel Inorganic materials 0.000 abstract description 3
- 229910052720 vanadium Inorganic materials 0.000 abstract description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract description 3
- 238000001556 precipitation Methods 0.000 abstract description 2
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 1
- 238000004939 coking Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 33
- 239000003921 oil Substances 0.000 description 29
- 239000012071 phase Substances 0.000 description 28
- 235000010755 mineral Nutrition 0.000 description 15
- 238000000605 extraction Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 239000003027 oil sand Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000011877 solvent mixture Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- -1 vanadium and nickel Chemical class 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical group CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 241001290534 Lachnocaulon Species 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000004155 tailings processing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
- B01D17/047—Breaking emulsions with separation aids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Une émulsion bitume-eau est traitée avec un mélange contenant du naphta et un hydrocarbure aliphatique léger tel que le butane. Le traitement déstabilise l'émulsion, ce qui permet d'en retirer en grande partie l'eau et la substance minérale. Le traitement entraîne également la précipitation de certains des asphaltènes présents dans le bitume. Le degré de désasphaltage est facilement maîtrisé afin d'obtenie une teneur précise en asphaltènes. Comme, pour les pétroles lourds tels que le bitume de l'Athabasca, les métaux tels que le nickel et le vanadium, sont concentrés dans les fractions dont le point d'ébullition est élevé et sont associés aux asphaltènes, l'élimination des asphaltènes réduit la teneur en métaux du produit. Selon la concentration en métaux et en asphaltènes choisie, le produit traité peut être valorisé davantage grâce à une série de procédés de conversion, notamment dans des unités de cokéfaction et d'hydrocraquage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002435113A CA2435113C (fr) | 2003-07-11 | 2003-07-11 | Procede de traitement d'emulsions d'huiles lourdes au moyen d'un melange de naphtha et d'hydrocarbure aliphatique leger |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002435113A CA2435113C (fr) | 2003-07-11 | 2003-07-11 | Procede de traitement d'emulsions d'huiles lourdes au moyen d'un melange de naphtha et d'hydrocarbure aliphatique leger |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2435113A1 CA2435113A1 (fr) | 2005-01-11 |
| CA2435113C true CA2435113C (fr) | 2008-06-17 |
Family
ID=33569535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002435113A Expired - Lifetime CA2435113C (fr) | 2003-07-11 | 2003-07-11 | Procede de traitement d'emulsions d'huiles lourdes au moyen d'un melange de naphtha et d'hydrocarbure aliphatique leger |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2435113C (fr) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7438807B2 (en) | 2002-09-19 | 2008-10-21 | Suncor Energy, Inc. | Bituminous froth inclined plate separator and hydrocarbon cyclone treatment process |
| US7556715B2 (en) | 2004-01-09 | 2009-07-07 | Suncor Energy, Inc. | Bituminous froth inline steam injection processing |
| US7736501B2 (en) | 2002-09-19 | 2010-06-15 | Suncor Energy Inc. | System and process for concentrating hydrocarbons in a bitumen feed |
| FR2947281A1 (fr) * | 2009-06-26 | 2010-12-31 | Total Sa | Procede de traitement d'hydrocarbures |
| US8025341B2 (en) | 2005-11-09 | 2011-09-27 | Suncor Energy Inc. | Mobile oil sands mining system |
| US8168071B2 (en) | 2005-11-09 | 2012-05-01 | Suncor Energy Inc. | Process and apparatus for treating a heavy hydrocarbon feedstock |
| US8357291B2 (en) | 2008-02-11 | 2013-01-22 | Exxonmobil Upstream Research Company | Upgrading bitumen in a paraffinic froth treatment process |
| US8684079B2 (en) | 2010-03-16 | 2014-04-01 | Exxonmobile Upstream Research Company | Use of a solvent and emulsion for in situ oil recovery |
| US8752623B2 (en) | 2010-02-17 | 2014-06-17 | Exxonmobil Upstream Research Company | Solvent separation in a solvent-dominated recovery process |
| US8899321B2 (en) | 2010-05-26 | 2014-12-02 | Exxonmobil Upstream Research Company | Method of distributing a viscosity reducing solvent to a set of wells |
| US8968580B2 (en) | 2009-12-23 | 2015-03-03 | Suncor Energy Inc. | Apparatus and method for regulating flow through a pumpbox |
| US9016799B2 (en) | 2005-11-09 | 2015-04-28 | Suncor Energy, Inc. | Mobile oil sands mining system |
| US9321967B2 (en) | 2009-08-17 | 2016-04-26 | Brack Capital Energy Technologies Limited | Oil sands extraction |
| US11001762B2 (en) | 2017-04-06 | 2021-05-11 | Suncor Energy Inc. | Partial upgrading of bitumen with thermal treatment and solvent deasphalting |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7631671B2 (en) | 2001-02-09 | 2009-12-15 | Mce Blending, Llc | Versatile systems for continuous in-line blending of butane and petroleum |
| CA2595336C (fr) | 2007-07-31 | 2009-09-15 | Imperial Oil Resources Limited | Reduction de l'entrainement ou de l'etablissement de salissures dans le traitement de l'ecume paraffinique |
| CA2716809C (fr) | 2008-03-20 | 2014-04-08 | Exxonmobil Upstream Research Company | Amplification de la stabilite d'une emulsion |
| US8252170B2 (en) | 2008-06-27 | 2012-08-28 | Exxonmobil Upstream Research Company | Optimizing feed mixer performance in a paraffinic froth treatment process |
| CA2650750C (fr) | 2009-01-23 | 2013-08-27 | Imperial Oil Resources Limited | Methode et systeme pour determiner la distribution granulometrique et les solides pouvant etre filtres dans un fluide contenant du bitume |
| CA2672004C (fr) | 2009-07-14 | 2012-03-27 | Imperial Oil Resources Limited | Materiel d'alimentation pour recipient de separation solides- liquides |
| US9222929B2 (en) | 2009-12-07 | 2015-12-29 | Exxonmobil Upstream Research Company | Solvent surveillance in solvent-based heavy oil recovery processes |
| CA2714842C (fr) | 2010-09-22 | 2012-05-29 | Imperial Oil Resources Limited | Methode de surveillance de la qualite du bitume durant son extraction au moyen d'un solvant |
| CA2734811C (fr) | 2011-03-29 | 2012-11-20 | Imperial Oil Resources Limited | Puits d'alimentation pour recipient de separation |
| CA2738560C (fr) | 2011-05-03 | 2014-07-08 | Imperial Oil Resources Limited | Amelioration du captage de fines particules dans le procede de traitement par moussage paraffinique |
| CA2783819C (fr) | 2011-11-08 | 2014-04-29 | Imperial Oil Resources Limited | Deshydratation des residus de sables bitumineux |
| US9321977B2 (en) | 2012-01-24 | 2016-04-26 | Sunoco Partners Marketing & Terminals L.P. | Methods for making and distributing batches of butane-enriched gasoline |
| US11421158B2 (en) | 2012-05-10 | 2022-08-23 | Texon Lp | Methods for expanding and enriching hydrocarbon diluent pools |
| US12291677B2 (en) | 2012-05-10 | 2025-05-06 | Texon Midstream, Llc | Methods for expanding and enriching hydrocarbon diluent pools |
| EP2847298A2 (fr) | 2012-05-10 | 2015-03-18 | Texon LP | Procédés pour la dilatation et l'enrichissement de mélanges de diluants d'hydrocarbures |
| US8748677B2 (en) | 2012-11-12 | 2014-06-10 | Sunoco Partners Marketing & Terminals L.P. | Expansion of fuel streams using mixed hydrocarbons |
| CA2936755C (fr) | 2016-07-19 | 2019-01-29 | Texon Lp | Methodes de reduction de la production de transmelange dans les pipelines de produits petroliers |
| WO2020185837A1 (fr) | 2019-03-12 | 2020-09-17 | Texon Lp | Mélange régulé de fractions de contaminats dans des flux d'hydrocarbures définis |
-
2003
- 2003-07-11 CA CA002435113A patent/CA2435113C/fr not_active Expired - Lifetime
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7726491B2 (en) | 2002-09-19 | 2010-06-01 | Suncor Energy Inc. | Bituminous froth hydrocarbon cyclone |
| US7736501B2 (en) | 2002-09-19 | 2010-06-15 | Suncor Energy Inc. | System and process for concentrating hydrocarbons in a bitumen feed |
| US7438807B2 (en) | 2002-09-19 | 2008-10-21 | Suncor Energy, Inc. | Bituminous froth inclined plate separator and hydrocarbon cyclone treatment process |
| US7914670B2 (en) | 2004-01-09 | 2011-03-29 | Suncor Energy Inc. | Bituminous froth inline steam injection processing |
| US7556715B2 (en) | 2004-01-09 | 2009-07-07 | Suncor Energy, Inc. | Bituminous froth inline steam injection processing |
| US8685210B2 (en) | 2004-01-09 | 2014-04-01 | Suncor Energy Inc. | Bituminous froth inline steam injection processing |
| US8800784B2 (en) | 2005-11-09 | 2014-08-12 | Suncor Energy Inc. | System, apparatus and process for extraction of bitumen from oil sands |
| US8480908B2 (en) | 2005-11-09 | 2013-07-09 | Suncor Energy Inc. | Process, apparatus and system for treating a hydrocarbon feedstock |
| US8096425B2 (en) | 2005-11-09 | 2012-01-17 | Suncor Energy Inc. | System, apparatus and process for extraction of bitumen from oil sands |
| US8968579B2 (en) | 2005-11-09 | 2015-03-03 | Suncor Energy Inc. | System, apparatus and process for extraction of bitumen from oil sands |
| US8168071B2 (en) | 2005-11-09 | 2012-05-01 | Suncor Energy Inc. | Process and apparatus for treating a heavy hydrocarbon feedstock |
| US8225944B2 (en) | 2005-11-09 | 2012-07-24 | Suncor Energy Inc. | System, apparatus and process for extraction of bitumen from oil sands |
| US8025341B2 (en) | 2005-11-09 | 2011-09-27 | Suncor Energy Inc. | Mobile oil sands mining system |
| US9016799B2 (en) | 2005-11-09 | 2015-04-28 | Suncor Energy, Inc. | Mobile oil sands mining system |
| US8357291B2 (en) | 2008-02-11 | 2013-01-22 | Exxonmobil Upstream Research Company | Upgrading bitumen in a paraffinic froth treatment process |
| GB2483039B (en) * | 2009-06-26 | 2013-07-10 | Total Sa | Method for treating hydrocarbons |
| WO2010150234A3 (fr) * | 2009-06-26 | 2011-03-17 | Total S.A. | Procede de traitement d'hydrocarbures |
| FR2947281A1 (fr) * | 2009-06-26 | 2010-12-31 | Total Sa | Procede de traitement d'hydrocarbures |
| GB2483039A (en) * | 2009-06-26 | 2012-02-22 | Total Sa | Method for treating hydrocarbons |
| US9321967B2 (en) | 2009-08-17 | 2016-04-26 | Brack Capital Energy Technologies Limited | Oil sands extraction |
| US8968580B2 (en) | 2009-12-23 | 2015-03-03 | Suncor Energy Inc. | Apparatus and method for regulating flow through a pumpbox |
| US8752623B2 (en) | 2010-02-17 | 2014-06-17 | Exxonmobil Upstream Research Company | Solvent separation in a solvent-dominated recovery process |
| US8684079B2 (en) | 2010-03-16 | 2014-04-01 | Exxonmobile Upstream Research Company | Use of a solvent and emulsion for in situ oil recovery |
| US8899321B2 (en) | 2010-05-26 | 2014-12-02 | Exxonmobil Upstream Research Company | Method of distributing a viscosity reducing solvent to a set of wells |
| US11001762B2 (en) | 2017-04-06 | 2021-05-11 | Suncor Energy Inc. | Partial upgrading of bitumen with thermal treatment and solvent deasphalting |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2435113A1 (fr) | 2005-01-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20230711 |