CA2450917A1 - Methode et appareil de conversion d'un combustible a base d'hydrocarbures en hydrogene gazeux et en dioxyde de carbone - Google Patents

Methode et appareil de conversion d'un combustible a base d'hydrocarbures en hydrogene gazeux et en dioxyde de carbone Download PDF

Info

Publication number: CA2450917A1
Authority: CA; Canada
Prior art keywords: tube; reformer; fuel; vessel; zone
Prior art date: 1996-08-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002450917A

Other languages

English (en)

Inventor

Lawrence G. Clawson

William L. Mitchell

Jeffrey M. Bently

Johannes H.J. Thijssen

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Nuvera Fuel Cells LLC

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-08-26

Filing date

1997-08-25

Publication date

1998-03-05

1996-08-26 Priority claimed from US08/703,398 external-priority patent/US6126908A/en

1997-08-25 Application filed by Individual filed Critical Individual

1998-03-05 Publication of CA2450917A1 publication Critical patent/CA2450917A1/fr

Status Abandoned legal-status Critical Current

Links

239000000446 fuel Substances 0.000 title claims abstract description 149
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 62
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 62
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 57
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 44
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 32
238000000034 method Methods 0.000 title claims description 17
239000001569 carbon dioxide Substances 0.000 title claims description 16
229910002092 carbon dioxide Inorganic materials 0.000 title claims description 16
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 51
239000001301 oxygen Substances 0.000 claims abstract description 51
229910052760 oxygen Inorganic materials 0.000 claims abstract description 51
239000003054 catalyst Substances 0.000 claims description 81
239000007789 gas Substances 0.000 claims description 51
239000000203 mixture Substances 0.000 claims description 51
238000006243 chemical reaction Methods 0.000 claims description 44
238000002407 reforming Methods 0.000 claims description 37
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 30
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 28
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 28
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 28
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
-1 magnesium aluminate Chemical class 0.000 claims description 18
238000002156 mixing Methods 0.000 claims description 16
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
239000000377 silicon dioxide Substances 0.000 claims description 15
239000011777 magnesium Substances 0.000 claims description 14
229910052749 magnesium Inorganic materials 0.000 claims description 14
239000000395 magnesium oxide Substances 0.000 claims description 14
229910052763 palladium Inorganic materials 0.000 claims description 14
229910052697 platinum Inorganic materials 0.000 claims description 14
229910052759 nickel Inorganic materials 0.000 claims description 13
229910052703 rhodium Inorganic materials 0.000 claims description 11
239000010948 rhodium Substances 0.000 claims description 11
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 11
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 10
229910052741 iridium Inorganic materials 0.000 claims description 10
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 10
229910052700 potassium Inorganic materials 0.000 claims description 10
239000011591 potassium Substances 0.000 claims description 10
229910052707 ruthenium Inorganic materials 0.000 claims description 10
229910017052 cobalt Inorganic materials 0.000 claims description 9
239000010941 cobalt Substances 0.000 claims description 9
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
229910001868 water Inorganic materials 0.000 claims description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 6
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 5
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
229910052802 copper Inorganic materials 0.000 claims description 4
239000010949 copper Substances 0.000 claims description 4
229910000423 chromium oxide Inorganic materials 0.000 claims description 3
229910052742 iron Inorganic materials 0.000 claims description 3
229910021332 silicide Inorganic materials 0.000 claims description 3
FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 3
QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims 1
238000001833 catalytic reforming Methods 0.000 claims 1
238000000629 steam reforming Methods 0.000 abstract description 33
238000007254 oxidation reaction Methods 0.000 abstract description 32
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 31
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 21
230000003647 oxidation Effects 0.000 abstract description 21
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract description 12
229910001882 dioxygen Inorganic materials 0.000 abstract description 12
239000003502 gasoline Substances 0.000 abstract description 10
DDZNRTJLFZLBPE-FBZJSIJRSA-N 82863-50-1 Chemical compound CC1CCCCC1.C([C@@H]1C2)C[C@@H]2[C@@H]2[C@H]1CCC2.C12C3C4C5C4CC3C5C1C1CC2CC1 DDZNRTJLFZLBPE-FBZJSIJRSA-N 0.000 abstract description 8
239000004071 soot Substances 0.000 abstract description 4
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 31
229910002091 carbon monoxide Inorganic materials 0.000 description 31
238000001816 cooling Methods 0.000 description 18
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
229910052717 sulfur Inorganic materials 0.000 description 11
239000011593 sulfur Substances 0.000 description 11
239000003350 kerosene Substances 0.000 description 9
229910052739 hydrogen Inorganic materials 0.000 description 7
239000001257 hydrogen Substances 0.000 description 7
238000002485 combustion reaction Methods 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 5
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
150000001340 alkali metals Chemical class 0.000 description 4
229910000510 noble metal Inorganic materials 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
229910000314 transition metal oxide Inorganic materials 0.000 description 3
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
239000001294 propane Substances 0.000 description 2
239000011787 zinc oxide Substances 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
238000003763 carbonization Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000002826 coolant Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
229960004643 cupric oxide Drugs 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
238000010248 power generation Methods 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

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Hydrogen, Water And Hydrids (AREA)

CA002450917A 1996-08-26 1997-08-25 Methode et appareil de conversion d'un combustible a base d'hydrocarbures en hydrogene gazeux et en dioxyde de carbone Abandoned CA2450917A1 (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US08/703,398 US6126908A (en)	1996-08-26	1996-08-26	Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide
US08/703,398		1996-08-26
CA002265468A CA2265468C (fr)	1996-08-26	1997-08-25	Procede et appareil pour transformer du carburant hydrocarbure en gaz hydrogene et en dioxyde de carbone

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002265468A Division CA2265468C (fr)	1996-08-26	1997-08-25	Procede et appareil pour transformer du carburant hydrocarbure en gaz hydrogene et en dioxyde de carbone

Publications (1)

Publication Number	Publication Date
CA2450917A1 true CA2450917A1 (fr)	1998-03-05

Family

ID=31716482

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002450917A Abandoned CA2450917A1 (fr)	1996-08-26	1997-08-25	Methode et appareil de conversion d'un combustible a base d'hydrocarbures en hydrogene gazeux et en dioxyde de carbone

Country Status (1)

Country	Link
CA (1)	CA2450917A1 (fr)

1997
- 1997-08-25 CA CA002450917A patent/CA2450917A1/fr not_active Abandoned

Legal Events

Date	Code	Title	Description
2003-12-23	EEER	Examination request
2009-08-25	FZDE	Dead

Publication	Publication Date	Title
US6207122B1 (en)	2001-03-27	Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide
US7226490B2 (en)	2007-06-05	Fuel processor for producing a hydrogen rich gas
CN101589275A (zh)	2009-11-25	用于蒸汽产生和气体预热的传热装置
AU2007333978A1 (en)	2008-06-26	Hybrid combustor for fuel processing applications
JP2010513189A (ja)	2010-04-30	燃料処理用途において触媒プレバーナーを使用するための方法
TW574137B (en)	2004-02-01	Process and apparatus for producing hydrogen
KR20020084266A (ko)	2002-11-04	연료 셀과 병용하는 연료 처리 장치의 다단계 연소 방법
CA2580647A1 (fr)	2006-03-30	Procede d'oxydation partielle catalytique de combustible hydrocarbone liquide
US20060168887A1 (en)	2006-08-03	Method for producing a fuel gas containing hydrogen for electrochemical cells and associated device
CA2450917A1 (fr)	1998-03-05	Methode et appareil de conversion d'un combustible a base d'hydrocarbures en hydrogene gazeux et en dioxyde de carbone
Clawson et al.	2000	Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide
AU2013206509A1 (en)	2013-07-18	Heat transfer unit for steam generation and gas preheating
HK1135455A (en)	2010-06-04	Hybrid combustor for fuel processing applications
JP2000264603A (ja)	2000-09-26	水素発生装置
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AU2008200186A1 (en)	2008-02-07	Dual stack compact fuel processor for producing a hydrogen rich gas