CA2466084C - Compositions nettoyantes pour surfaces de ceramique et de porcelaine et procedes correspondants - Google Patents

Compositions nettoyantes pour surfaces de ceramique et de porcelaine et procedes correspondants Download PDF

Info

Publication number: CA2466084C
Authority: CA; Canada
Prior art keywords: composition; weight percent; acid; cleaning; sodium
Prior art date: 1997-12-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002466084A

Other languages

English (en)

Other versions

CA2466084A1 (fr

Inventor

Wayne M. Rees

Phillip J. Neumiller

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

SC Johnson and Son Inc

Original Assignee

SC Johnson and Son Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-12-22

Filing date

1998-12-17

Publication date

2006-09-12

1997-12-22 Priority claimed from US08/995,326 external-priority patent/US5895781A/en

1998-12-17 Application filed by SC Johnson and Son Inc filed Critical SC Johnson and Son Inc

1999-07-01 Publication of CA2466084A1 publication Critical patent/CA2466084A1/fr

2006-09-12 Application granted granted Critical

2006-09-12 Publication of CA2466084C publication Critical patent/CA2466084C/fr

2018-12-17 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 236
238000004140 cleaning Methods 0.000 title claims abstract description 89
239000000919 ceramic Substances 0.000 title abstract description 24
229910052573 porcelain Inorganic materials 0.000 title abstract description 17
238000000034 method Methods 0.000 title description 12
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 66
CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 claims abstract description 41
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 39
235000010350 erythorbic acid Nutrition 0.000 claims abstract description 37
229910052751 metal Inorganic materials 0.000 claims abstract description 37
239000002184 metal Substances 0.000 claims abstract description 37
229940026239 isoascorbic acid Drugs 0.000 claims abstract description 35
150000004696 coordination complex Chemical class 0.000 claims abstract description 32
239000004094 surface-active agent Substances 0.000 claims abstract description 19
230000000536 complexating effect Effects 0.000 claims abstract description 12
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims abstract description 10
229910000342 sodium bisulfate Inorganic materials 0.000 claims abstract description 10
230000002452 interceptive effect Effects 0.000 claims abstract description 6
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 15
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 13
235000019333 sodium laurylsulphate Nutrition 0.000 claims description 13
235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 7
YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 claims description 7
125000003368 amide group Chemical group 0.000 claims description 4
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 claims description 4
239000002253 acid Substances 0.000 abstract description 23
239000000344 soap Substances 0.000 abstract description 16
235000008733 Citrus aurantifolia Nutrition 0.000 abstract description 15
235000011941 Tilia x europaea Nutrition 0.000 abstract description 15
239000004571 lime Substances 0.000 abstract description 15
FRTNIYVUDIHXPG-UHFFFAOYSA-N acetic acid;ethane-1,2-diamine Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN FRTNIYVUDIHXPG-UHFFFAOYSA-N 0.000 abstract description 9
239000002689 soil Substances 0.000 abstract description 9
239000011521 glass Substances 0.000 abstract description 8
239000004519 grease Substances 0.000 abstract description 8
230000003647 oxidation Effects 0.000 abstract description 8
238000007254 oxidation reaction Methods 0.000 abstract description 8
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 51
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 42
230000000052 comparative effect Effects 0.000 description 33
238000009472 formulation Methods 0.000 description 27
239000003826 tablet Substances 0.000 description 25
238000012360 testing method Methods 0.000 description 24
239000011572 manganese Substances 0.000 description 23
239000003638 chemical reducing agent Substances 0.000 description 22
229910052742 iron Inorganic materials 0.000 description 21
229910052748 manganese Inorganic materials 0.000 description 20
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 19
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 18
235000006408 oxalic acid Nutrition 0.000 description 17
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 16
-1 iron oxides Chemical class 0.000 description 14
239000000843 powder Substances 0.000 description 12
239000000975 dye Substances 0.000 description 11
239000003205 fragrance Substances 0.000 description 11
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
239000003086 colorant Substances 0.000 description 10
229910052708 sodium Inorganic materials 0.000 description 10
239000011734 sodium Substances 0.000 description 10
239000000654 additive Substances 0.000 description 9
229910052783 alkali metal Inorganic materials 0.000 description 9
235000015497 potassium bicarbonate Nutrition 0.000 description 9
229910000028 potassium bicarbonate Inorganic materials 0.000 description 9
239000011736 potassium bicarbonate Substances 0.000 description 9
239000001103 potassium chloride Substances 0.000 description 9
235000011164 potassium chloride Nutrition 0.000 description 9
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 9
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
235000017557 sodium bicarbonate Nutrition 0.000 description 8
229910000030 sodium bicarbonate Inorganic materials 0.000 description 8
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 7
150000007513 acids Chemical class 0.000 description 7
239000010410 layer Substances 0.000 description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
230000000996 additive effect Effects 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
239000008139 complexing agent Substances 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
239000008367 deionised water Substances 0.000 description 6
229910021641 deionized water Inorganic materials 0.000 description 6
239000000463 material Substances 0.000 description 6
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 6
239000008119 colloidal silica Substances 0.000 description 5
229910002027 silica gel Inorganic materials 0.000 description 5
239000000126 substance Substances 0.000 description 5
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
238000005299 abrasion Methods 0.000 description 4
239000003463 adsorbent Substances 0.000 description 4
239000012736 aqueous medium Substances 0.000 description 4
150000002443 hydroxylamines Chemical class 0.000 description 4
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 4
235000021317 phosphate Nutrition 0.000 description 4
229940075560 sodium lauryl sulfoacetate Drugs 0.000 description 4
UAJTZZNRJCKXJN-UHFFFAOYSA-M sodium;2-dodecoxy-2-oxoethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCOC(=O)CS([O-])(=O)=O UAJTZZNRJCKXJN-UHFFFAOYSA-M 0.000 description 4
239000008399 tap water Substances 0.000 description 4
235000020679 tap water Nutrition 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
239000004318 erythorbic acid Substances 0.000 description 3
229910001448 ferrous ion Inorganic materials 0.000 description 3
235000013980 iron oxide Nutrition 0.000 description 3
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
150000004706 metal oxides Chemical class 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
239000011780 sodium chloride Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000007916 tablet composition Substances 0.000 description 3
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 2
RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 2
YIAKRURWWXGSLG-UHFFFAOYSA-N CCO.CCCCCCCCCCCC(N)=O Chemical compound CCO.CCCCCCCCCCCC(N)=O YIAKRURWWXGSLG-UHFFFAOYSA-N 0.000 description 2
101100241173 Caenorhabditis elegans dat-1 gene Proteins 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 description 2
235000019393 L-cystine Nutrition 0.000 description 2
239000004158 L-cystine Substances 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
HLCFGWHYROZGBI-JJKGCWMISA-M Potassium gluconate Chemical compound [K+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O HLCFGWHYROZGBI-JJKGCWMISA-M 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
239000003082 abrasive agent Substances 0.000 description 2
230000009471 action Effects 0.000 description 2
235000011037 adipic acid Nutrition 0.000 description 2
150000001279 adipic acids Chemical class 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
235000010323 ascorbic acid Nutrition 0.000 description 2
239000011668 ascorbic acid Substances 0.000 description 2
229960005070 ascorbic acid Drugs 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
229960003067 cystine Drugs 0.000 description 2
UBAXRAHSPKWNCX-UHFFFAOYSA-N diallyl trisulfide Chemical compound C=CCSSSCC=C UBAXRAHSPKWNCX-UHFFFAOYSA-N 0.000 description 2
GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000007789 gas Substances 0.000 description 2
239000000499 gel Substances 0.000 description 2
229960003681 gluconolactone Drugs 0.000 description 2
150000002311 glutaric acids Chemical class 0.000 description 2
229940075529 glyceryl stearate Drugs 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
230000002401 inhibitory effect Effects 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
239000007942 layered tablet Substances 0.000 description 2
239000003446 ligand Substances 0.000 description 2
235000010755 mineral Nutrition 0.000 description 2
239000011707 mineral Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
229960003975 potassium Drugs 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
239000004224 potassium gluconate Substances 0.000 description 2
235000013926 potassium gluconate Nutrition 0.000 description 2
229960003189 potassium gluconate Drugs 0.000 description 2
238000006722 reduction reaction Methods 0.000 description 2
229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
239000000176 sodium gluconate Substances 0.000 description 2
235000012207 sodium gluconate Nutrition 0.000 description 2
229940005574 sodium gluconate Drugs 0.000 description 2
235000009518 sodium iodide Nutrition 0.000 description 2
UELAIMNOXLAYRW-UHFFFAOYSA-M sodium;1,4-dicyclohexyloxy-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].C1CCCCC1OC(=O)C(S(=O)(=O)[O-])CC(=O)OC1CCCCC1 UELAIMNOXLAYRW-UHFFFAOYSA-M 0.000 description 2
FGDMJJQHQDFUCP-UHFFFAOYSA-M sodium;2-propan-2-ylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(C(C)C)=CC=C21 FGDMJJQHQDFUCP-UHFFFAOYSA-M 0.000 description 2
238000005507 spraying Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
235000011044 succinic acid Nutrition 0.000 description 2
150000003444 succinic acids Chemical class 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
DINKXUCRJBUQAZ-UHFFFAOYSA-N tert-butyl 5-bromopyridine-3-carboxylate Chemical compound CC(C)(C)OC(=O)C1=CN=CC(Br)=C1 DINKXUCRJBUQAZ-UHFFFAOYSA-N 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
102100027825 Complexin-4 Human genes 0.000 description 1
101710137428 Complexin-4 Proteins 0.000 description 1
ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
241001251094 Formica Species 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012538 ammonium bicarbonate Nutrition 0.000 description 1
239000001099 ammonium carbonate Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
235000006708 antioxidants Nutrition 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
229960003237 betaine Drugs 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
ZZZCUOFIHGPKAK-UWTATZPHSA-N dehydro-D-arabinono-1,4-lactone Chemical compound OC[C@H]1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UWTATZPHSA-N 0.000 description 1
RMKCQUWJDRTEHE-UHFFFAOYSA-N diallyl tetrasulfane Natural products C=CCSSSSCC=C RMKCQUWJDRTEHE-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000003628 erosive effect Effects 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
229960002089 ferrous chloride Drugs 0.000 description 1
235000003891 ferrous sulphate Nutrition 0.000 description 1
239000011790 ferrous sulphate Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000003517 fume Substances 0.000 description 1
ZXUMPYVMVQXNNH-UHFFFAOYSA-N hydroxylamine oxalic acid hydrochloride Chemical compound Cl.NO.OC(=O)C(O)=O ZXUMPYVMVQXNNH-UHFFFAOYSA-N 0.000 description 1
NILJXUMQIIUAFY-UHFFFAOYSA-N hydroxylamine;nitric acid Chemical compound ON.O[N+]([O-])=O NILJXUMQIIUAFY-UHFFFAOYSA-N 0.000 description 1
HYYHQASRTSDPOD-UHFFFAOYSA-N hydroxylamine;phosphoric acid Chemical compound ON.OP(O)(O)=O HYYHQASRTSDPOD-UHFFFAOYSA-N 0.000 description 1
229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000010525 oxidative degradation reaction Methods 0.000 description 1
239000003973 paint Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000003223 protective agent Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000005060 rubber Substances 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1

Landscapes

Detergent Compositions (AREA)

CA002466084A 1997-12-22 1998-12-17 Compositions nettoyantes pour surfaces de ceramique et de porcelaine et procedes correspondants Expired - Fee Related CA2466084C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US08/995,326 US5895781A (en)	1997-12-22	1997-12-22	Cleaning compositions for ceramic and porcelain surfaces and related methods
US08/995,326		1997-12-22
CA002316334A CA2316334C (fr)	1997-12-22	1998-12-17	Compositions nettoyantes pour surfaces de ceramique et de porcelaine et procedes correspondants

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002316334A Division CA2316334C (fr)	1997-12-22	1998-12-17	Compositions nettoyantes pour surfaces de ceramique et de porcelaine et procedes correspondants

Publications (2)

Publication Number	Publication Date
CA2466084A1 CA2466084A1 (fr)	1999-07-01
CA2466084C true CA2466084C (fr)	2006-09-12

Family

ID=32683220

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002466084A Expired - Fee Related CA2466084C (fr)	1997-12-22	1998-12-17	Compositions nettoyantes pour surfaces de ceramique et de porcelaine et procedes correspondants

Country Status (1)

Country	Link
CA (1)	CA2466084C (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2386729C2 (ru) *	2008-06-30	2010-04-20	Федеральное государственное образовательное учреждение высшего профессионального образования "Московский государственный университет природообустройства" (МГУП)	Способ удаления окалины
CN112853364B (zh) *	2021-01-14	2022-08-26	西安热工研究院有限公司	一种凝汽器锰垢化学清洗剂

1998
- 1998-12-17 CA CA002466084A patent/CA2466084C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2466084A1 (fr)	1999-07-01

Legal Events

Date	Code	Title	Description
2004-04-22	EEER	Examination request
2007-12-17	MKLA	Lapsed

Publication	Publication Date	Title
US5910475A (en)	1999-06-08	Cleaning compositions for ceramic and porcelain surfaces and related methods
JP4838350B2 (ja)	2011-12-14	金属表面用酸性洗浄剤
US7517844B2 (en)	2009-04-14	Acidic cleaning compositions comprising an acid mixture and ternary solvent mixture
AU716149B2 (en)	2000-02-17	Cleaning and disinfecting compositions with electrolytic disinfecting booster
GB2149419A (en)	1985-06-12	Acid liquid detergent composition for cleaning ceramic tiles without eroding grout
JPH10508901A (ja)	1998-09-02	残留物の少ないヒドロトロープを含む硬質表面洗浄剤
US6420329B1 (en)	2002-07-16	Cleaning compositions
PL174150B1 (pl)	1998-06-30	Wodna kompozycja czyszcząca
CA1148058A (fr)	1983-06-14	Methode et composition pour prevenir la formation de taches de manganese a la surface d'articles vitrifies
US5607911A (en)	1997-03-04	Aqueous compositions with detergent for rust and stain removal
CA2466084C (fr)	2006-09-12	Compositions nettoyantes pour surfaces de ceramique et de porcelaine et procedes correspondants
JPS5993799A (ja)	1984-05-30	液体洗浄剤
US5525252A (en)	1996-06-11	Aqueous, non-corrosive, composition with detergent for rust and stain removal
JP2002212595A (ja)	2002-07-31	液体漂白剤組成物
JP3299039B2 (ja)	2002-07-08	硬質表面洗浄剤組成物
JPS6257494A (ja)	1987-03-13	黴汚れ用洗浄剤組成物
JPH11236594A (ja)	1999-08-31	硬質体用漂白剤組成物
WO2008046449A1 (fr)	2008-04-24	Nettoyant sanitaire à base d'une nouvelle combinaison d'acides
JPH02170898A (ja)	1990-07-02	液体洗浄漂白剤組成物
JP3372108B2 (ja)	2003-01-27	硬質表面洗浄剤組成物
JPH09235590A (ja)	1997-09-09	液体洗浄剤組成物
JPH06128770A (ja)	1994-05-10	パチンコ遊戯機用洗浄剤組成物
JPH08151595A (ja)	1996-06-11	洗浄剤組成物
JP2004035816A (ja)	2004-02-05	洗浄剤組成物
JPH03277700A (ja)	1991-12-09	液体洗浄剤