CA2499850C - Procede et dispositif de production de nanotubes de carbone a paroi simple - Google Patents

Procede et dispositif de production de nanotubes de carbone a paroi simple Download PDF

Info

Publication number
CA2499850C
CA2499850C CA002499850A CA2499850A CA2499850C CA 2499850 C CA2499850 C CA 2499850C CA 002499850 A CA002499850 A CA 002499850A CA 2499850 A CA2499850 A CA 2499850A CA 2499850 C CA2499850 C CA 2499850C
Authority
CA
Canada
Prior art keywords
carbon
plasma
metal catalyst
containing substance
atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002499850A
Other languages
English (en)
Other versions
CA2499850A1 (fr
Inventor
Olivier Smiljanic
Barry L. Stansfield
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institut National de La Recherche Scientifique INRS
Original Assignee
Institut National de La Recherche Scientifique INRS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34620944&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2499850(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from CA002385802A external-priority patent/CA2385802C/fr
Application filed by Institut National de La Recherche Scientifique INRS filed Critical Institut National de La Recherche Scientifique INRS
Priority to CA002499850A priority Critical patent/CA2499850C/fr
Publication of CA2499850A1 publication Critical patent/CA2499850A1/fr
Application granted granted Critical
Publication of CA2499850C publication Critical patent/CA2499850C/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1271—Alkanes or cycloalkanes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1273—Alkenes, alkynes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1276—Aromatics, e.g. toluene
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/133—Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0869—Feeding or evacuating the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0871—Heating or cooling of the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0875—Gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0892—Materials to be treated involving catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894—Processes carried out in the presence of a plasma
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé de production de nanotubes de carbone à paroi simple. Le procédé de l'invention consiste (a) à utiliser un chalumeau à plasma comprenant un tube à plasma pourvu d'une extrémité d'évacuation de plasma, (b) à acheminer un gaz inerte à travers le tube à plasma en vue de former un plasma principal, (c) à mettre une substance contenant du carbone et un catalyseur métallique en contact avec ce plasma principal au niveau de l'extrémité d'évacuation de plasma du tube à plasma de manière à former un plasma secondaire contenant des atomes ou des molécules de carbone ainsi que des atomes du catalyseur métallique, et (d) à condenser les atomes ou les molécules de carbone et les atomes du catalyseur métallique de sorte à former des nanotubes de carbone à paroi simple. Dans un autre mode de réalisation, les opérations (b) et (c) peuvent être réalisées par acheminement d'un gaz inerte et d'un catalyseur métallique inorganique à travers le tube à plasma en vue de former un plasma principal contenant des atomes du catalyseur métallique inorganique, et par mise en contact d'une substance contenant du carbone avec le plasma principal au niveau de l'extrémité d'évacuation de plasma du tube à plasma de façon à former un plasma secondaire contenant des atomes ou des molécules de carbone et les atomes de catalyseur métallique. L'invention concerne également un dispositif destiné à la mise en oeuvre du procédé susmentionné.
CA002499850A 2002-05-09 2003-05-09 Procede et dispositif de production de nanotubes de carbone a paroi simple Expired - Lifetime CA2499850C (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA002499850A CA2499850C (fr) 2002-05-09 2003-05-09 Procede et dispositif de production de nanotubes de carbone a paroi simple

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CA2,385,802 2002-05-09
CA002385802A CA2385802C (fr) 2002-05-09 2002-05-09 Methode et appareil de production de nanotubes de carbone a paroi simple
CA002499850A CA2499850C (fr) 2002-05-09 2003-05-09 Procede et dispositif de production de nanotubes de carbone a paroi simple
PCT/CA2003/000694 WO2003095362A2 (fr) 2002-05-09 2003-05-09 Procede et dispositif de production de nanotubes de carbone a paroi simple

Publications (2)

Publication Number Publication Date
CA2499850A1 CA2499850A1 (fr) 2003-11-20
CA2499850C true CA2499850C (fr) 2006-01-10

Family

ID=34620944

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002499850A Expired - Lifetime CA2499850C (fr) 2002-05-09 2003-05-09 Procede et dispositif de production de nanotubes de carbone a paroi simple

Country Status (1)

Country Link
CA (1) CA2499850C (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2003287801A1 (en) 2002-11-15 2004-06-15 Mgill University Method for producing carbon nanotubes using a dc non-transferred thermal plasma torch
CN112121843B (zh) * 2020-10-15 2022-04-22 哈尔滨工业大学 一种丝瓜络遗态支撑的氮掺杂碳纳米管包覆铁纳米颗粒类芬顿催化剂的制备方法和应用
CN113860287B (zh) * 2021-09-22 2022-12-27 江西铜业技术研究院有限公司 一种等离子体电弧法制备单壁碳纳米管的系统和方法
CN114518453B (zh) * 2022-01-26 2023-05-16 东北农业大学 一种多壁碳纳米管复合物及其制备方法和应用

Also Published As

Publication number Publication date
CA2499850A1 (fr) 2003-11-20

Similar Documents

Publication Publication Date Title
US8071906B2 (en) Apparatus for producing single-wall carbon nanotubes
US7824649B2 (en) Apparatus and method for synthesizing a single-wall carbon nanotube array
Smiljanic et al. Gas-phase synthesis of SWNT by an atmospheric pressure plasma jet
US7846414B2 (en) Method for producing carbon nanotubes using a DC non-transferred thermal plasma torch
EP3391715B1 (fr) Appareil et procédé de synthèse par plasma de nanotubes de carbone
US20050118090A1 (en) Plasma synthesis of hollow nanostructures
JP3463091B2 (ja) カーボンナノチューブの製造方法
KR100376202B1 (ko) 탄소나노튜브 또는 탄소나노섬유 합성용 기상합성 장치 및이를 사용한 합성방법
CA2748064A1 (fr) Procede et appareil de recuperation de structures filamenteuses de carbone
CA2499850C (fr) Procede et dispositif de production de nanotubes de carbone a paroi simple
KR20160135382A (ko) 탄소나노튜브 합성 장치 및 그 방법
Takikawa et al. Amorphous carbon fibrilliform nanomaterials prepared by chemical vapor deposition
Govindaraj et al. Synthesis, growth mechanism and processing of carbon nanotubes
US8506921B2 (en) Production of vertical arrays of small diameter single-walled carbon nanotubes
Ma et al. Low-temperature growth of carbon nanofiber using a vapor–facet–solid process
KR20040050409A (ko) 플라즈마 발생기를 이용한 탄소나노튜브 또는 탄소나노섬유 기상합성장치와 그 합성법
Shavelkina et al. Effect of the precursor aggregate state on the synthesis of CNTs in a DC plasma jet
Le Normand et al. Gas phase and surface kinetics in plasma and hot filament-enhanced catalytic chemical vapor deposition of carbon nanostructures
EP2743231A1 (fr) Procédé de production de nanotubes de carbone en l'absence de catalyseurs métalliques
Harbec Producing carbon nanotubes using the technology of DC thermal plasma torch
KR20240172608A (ko) 탄소나노튜브 제조방법 및 제조장치
Yamatani et al. Continuous production of carbon nanostructures using plasma jet
Ren et al. Chemical Vapor Deposition of Carbon Nanotubes
JPH08301699A (ja) 気相成長炭素繊維の連続製造装置および気相成長炭素繊維の連続製造方法

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20230509