CA2563528A1 - Fluides de fracturation contenant des esters boriques comme agents de reticulation et methode d'utilisation desdits fluides - Google Patents

Fluides de fracturation contenant des esters boriques comme agents de reticulation et methode d'utilisation desdits fluides Download PDF

Info

Publication number: CA2563528A1
Authority: CA; Canada
Prior art keywords: treating fluid; formation treating; formation; fluid; borate
Prior art date: 2002-06-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002563528A

Other languages

English (en)

Inventor

D. V. Satyanarayana Gupta

Ron Pierce

Nicole Deanne Litt

Anita Colleen Jerat

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BJ Services Co Canada

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-06-25

Filing date

2003-06-09

Publication date

2003-12-25

2002-06-25 Priority claimed from US10/178,410 external-priority patent/US7007757B2/en

2003-06-09 Application filed by Individual filed Critical Individual

2003-12-25 Publication of CA2563528A1 publication Critical patent/CA2563528A1/fr

Status Abandoned legal-status Critical Current

Links

239000012530 fluid Substances 0.000 title claims abstract description 143
150000001642 boronic acid derivatives Chemical class 0.000 title abstract description 11
239000003431 cross linking reagent Substances 0.000 title description 21
238000000034 method Methods 0.000 title 1
230000015572 biosynthetic process Effects 0.000 claims abstract description 81
229920000642 polymer Polymers 0.000 claims abstract description 56
239000007788 liquid Substances 0.000 claims abstract description 36
-1 borate ester Chemical class 0.000 claims description 58
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
239000003795 chemical substances by application Substances 0.000 claims description 16
238000010979 pH adjustment Methods 0.000 claims description 13
239000000203 mixture Substances 0.000 claims description 9
239000003513 alkali Substances 0.000 claims description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 7
150000001447 alkali salts Chemical group 0.000 claims description 7
159000000011 group IA salts Chemical class 0.000 claims description 7
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 6
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
239000003960 organic solvent Substances 0.000 claims description 6
230000007062 hydrolysis Effects 0.000 claims description 5
238000006460 hydrolysis reaction Methods 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 5
150000005691 triesters Chemical class 0.000 claims description 5
125000004122 cyclic group Chemical group 0.000 claims description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 42
238000005755 formation reaction Methods 0.000 description 32
244000303965 Cyamopsis psoralioides Species 0.000 description 19
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 15
239000004327 boric acid Substances 0.000 description 15
235000010338 boric acid Nutrition 0.000 description 15
229960002645 boric acid Drugs 0.000 description 15
AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 15
239000000499 gel Substances 0.000 description 14
239000000243 solution Substances 0.000 description 13
ZFMOJHVRFMOIGF-UHFFFAOYSA-N 2,4,6-trimethoxy-1,3,5,2,4,6-trioxatriborinane Chemical compound COB1OB(OC)OB(OC)O1 ZFMOJHVRFMOIGF-UHFFFAOYSA-N 0.000 description 10
WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 description 10
239000004971 Cross linker Substances 0.000 description 9
238000004132 cross linking Methods 0.000 description 9
238000011068 loading method Methods 0.000 description 9
238000007792 addition Methods 0.000 description 8
238000005086 pumping Methods 0.000 description 7
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
230000003111 delayed effect Effects 0.000 description 5
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
238000009472 formulation Methods 0.000 description 4
230000036571 hydration Effects 0.000 description 4
238000006703 hydration reaction Methods 0.000 description 4
239000002562 thickening agent Substances 0.000 description 4
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
229910052796 boron Inorganic materials 0.000 description 3
229920006037 cross link polymer Polymers 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
150000003839 salts Chemical group 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
NHDIQVFFNDKAQU-UHFFFAOYSA-N tripropan-2-yl borate Chemical compound CC(C)OB(OC(C)C)OC(C)C NHDIQVFFNDKAQU-UHFFFAOYSA-N 0.000 description 3
239000004372 Polyvinyl alcohol Substances 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
230000008901 benefit Effects 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000001530 fumaric acid Substances 0.000 description 2
239000007789 gas Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000012856 packing Methods 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
229920002907 Guar gum Polymers 0.000 description 1
229920000161 Locust bean gum Polymers 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
101100074807 Mus musculus Lhx3 gene Proteins 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
235000012538 ammonium bicarbonate Nutrition 0.000 description 1
239000001099 ammonium carbonate Substances 0.000 description 1
235000012501 ammonium carbonate Nutrition 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
235000006708 antioxidants Nutrition 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000002585 base Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000003139 biocide Substances 0.000 description 1
HGHPQUIZVKPZEU-UHFFFAOYSA-N boranylidynezirconium Chemical compound [B].[Zr] HGHPQUIZVKPZEU-UHFFFAOYSA-N 0.000 description 1
229940063013 borate ion Drugs 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000013522 chelant Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000013505 freshwater Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
239000000665 guar gum Substances 0.000 description 1
235000010417 guar gum Nutrition 0.000 description 1
230000000887 hydrating effect Effects 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000000711 locust bean gum Substances 0.000 description 1
235000010420 locust bean gum Nutrition 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
235000019422 polyvinyl alcohol Nutrition 0.000 description 1
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
230000002028 premature Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
239000004576 sand Substances 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000011734 sodium Substances 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
235000019351 sodium silicates Nutrition 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1

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Lubricants (AREA)

CA002563528A 2002-06-25 2003-06-09 Fluides de fracturation contenant des esters boriques comme agents de reticulation et methode d'utilisation desdits fluides Abandoned CA2563528A1 (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US10/178,410		2002-06-25
US10/178,410 US7007757B2 (en)	2002-06-25	2002-06-25	Fracturing fluids containing borate esters as crosslinking agents and method of using same
CA002431528A CA2431528C (fr)	2002-06-25	2003-06-09	Fluides de fracturation contenant des esters boriques comme agents de reticulation et methode d'utilisation desdits fluides

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002431528A Division CA2431528C (fr)	2002-06-25	2003-06-09	Fluides de fracturation contenant des esters boriques comme agents de reticulation et methode d'utilisation desdits fluides

Publications (1)

Publication Number	Publication Date
CA2563528A1 true CA2563528A1 (fr)	2003-12-25

Family

ID=39343626

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002563528A Abandoned CA2563528A1 (fr)	2002-06-25	2003-06-09	Fluides de fracturation contenant des esters boriques comme agents de reticulation et methode d'utilisation desdits fluides

Country Status (1)

Country	Link
CA (1)	CA2563528A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112111263A (zh) *	2020-09-23	2020-12-22	中国石油大学(华东)	一种抗高温清洁压裂液的制备方法
CN114437360A (zh) *	2020-10-30	2022-05-06	中国石油化工股份有限公司	聚醚-聚胺多硼酸骨架交联剂的制备方法与应用
CN116751577A (zh) *	2023-08-16	2023-09-15	山东德坤工贸有限公司	一种压裂液用延迟交联型交联剂

2003
- 2003-06-09 CA CA002563528A patent/CA2563528A1/fr not_active Abandoned

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112111263A (zh) *	2020-09-23	2020-12-22	中国石油大学(华东)	一种抗高温清洁压裂液的制备方法
CN114437360A (zh) *	2020-10-30	2022-05-06	中国石油化工股份有限公司	聚醚-聚胺多硼酸骨架交联剂的制备方法与应用
CN114437360B (zh) *	2020-10-30	2023-07-11	中国石油化工股份有限公司	聚醚-聚胺多硼酸骨架交联剂的制备方法与应用
CN116751577A (zh) *	2023-08-16	2023-09-15	山东德坤工贸有限公司	一种压裂液用延迟交联型交联剂
CN116751577B (zh) *	2023-08-16	2023-10-31	山东德坤工贸有限公司	一种压裂液用延迟交联型交联剂

Legal Events

Date	Code	Title	Description
2006-10-31	EEER	Examination request
2009-03-05	FZDE	Dead

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US7683011B2 (en)	2010-03-23	Process to prepare borozirconate solution and use as cross-linker in hydraulic fracturing fluids
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