CA2578233A1 - Systeme de desulfuration et procede pour desulfurer un flux de combustible - Google Patents

Systeme de desulfuration et procede pour desulfurer un flux de combustible Download PDF

Info

Publication number: CA2578233A1
Authority: CA; Canada
Prior art keywords: sulfur; adsorbent; calcium; selective; zeolite
Prior art date: 2004-09-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002578233A

Other languages

English (en)

Inventor

Eric J. Weston

R. Steve Spivey

Kerry C. Weston

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sued Chemie Inc

Zeochem LLC

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2004-09-01

Filing date

2005-08-19

Publication date

2006-03-16

2005-08-18 Priority claimed from US11/207,154 external-priority patent/US20060043001A1/en

2005-08-19 Application filed by Individual filed Critical Individual

2006-03-16 Publication of CA2578233A1 publication Critical patent/CA2578233A1/fr

Status Abandoned legal-status Critical Current

Links

239000000446 fuel Substances 0.000 title claims abstract description 140
238000006477 desulfuration reaction Methods 0.000 title claims description 38
230000023556 desulfurization Effects 0.000 title claims description 38
238000000034 method Methods 0.000 title claims description 38
230000003009 desulfurizing effect Effects 0.000 title description 4
239000003463 adsorbent Substances 0.000 claims abstract description 350
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 293
239000011593 sulfur Substances 0.000 claims abstract description 293
229910052717 sulfur Inorganic materials 0.000 claims abstract description 293
239000010457 zeolite Substances 0.000 claims abstract description 135
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 133
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 133
229910052791 calcium Inorganic materials 0.000 claims abstract description 67
239000011575 calcium Substances 0.000 claims abstract description 67
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 64
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 59
229930195733 hydrocarbon Natural products 0.000 claims abstract description 59
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 59
150000003464 sulfur compounds Chemical class 0.000 claims description 86
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 56
150000002697 manganese compounds Chemical class 0.000 claims description 49
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 48
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 45
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 41
239000005751 Copper oxide Substances 0.000 claims description 37
229910000431 copper oxide Inorganic materials 0.000 claims description 37
239000000203 mixture Substances 0.000 claims description 32
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 28
QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 claims description 27
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 claims description 26
239000011787 zinc oxide Substances 0.000 claims description 24
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 21
150000002500 ions Chemical group 0.000 claims description 18
RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 claims description 18
229910021645 metal ion Inorganic materials 0.000 claims description 15
229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 14
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 11
239000011230 binding agent Substances 0.000 claims description 11
229910001424 calcium ion Inorganic materials 0.000 claims description 11
239000011572 manganese Substances 0.000 claims description 10
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 10
229910052799 carbon Inorganic materials 0.000 claims description 8
239000002250 absorbent Substances 0.000 claims description 7
230000002745 absorbent Effects 0.000 claims description 7
-1 calcium cations Chemical class 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 7
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
GEYXPJBPASPPLI-UHFFFAOYSA-N manganese(III) oxide Inorganic materials O=[Mn]O[Mn]=O GEYXPJBPASPPLI-UHFFFAOYSA-N 0.000 claims description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
150000001768 cations Chemical class 0.000 claims description 4
229910052748 manganese Inorganic materials 0.000 claims description 4
150000002898 organic sulfur compounds Chemical class 0.000 claims description 4
150000003568 thioethers Chemical class 0.000 claims description 4
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
229910052802 copper Inorganic materials 0.000 claims description 3
239000010949 copper Substances 0.000 claims description 3
150000002019 disulfides Chemical class 0.000 claims description 3
229910052709 silver Inorganic materials 0.000 claims description 3
239000004332 silver Substances 0.000 claims description 3
150000003462 sulfoxides Chemical class 0.000 claims description 3
229930192474 thiophene Natural products 0.000 claims description 3
150000003577 thiophenes Chemical class 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
229910052793 cadmium Inorganic materials 0.000 claims description 2
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
229910017052 cobalt Inorganic materials 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
229910052737 gold Inorganic materials 0.000 claims description 2
239000010931 gold Substances 0.000 claims description 2
229910052742 iron Inorganic materials 0.000 claims description 2
229910052744 lithium Inorganic materials 0.000 claims description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
229910052706 scandium Inorganic materials 0.000 claims description 2
SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 2
150000002506 iron compounds Chemical class 0.000 claims 1
229910052751 metal Inorganic materials 0.000 claims 1
239000002184 metal Substances 0.000 claims 1
238000004519 manufacturing process Methods 0.000 abstract description 10
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 41
238000001179 sorption measurement Methods 0.000 description 32
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 26
DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 24
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 19
239000001257 hydrogen Substances 0.000 description 19
229910052739 hydrogen Inorganic materials 0.000 description 19
239000003345 natural gas Substances 0.000 description 15
239000003915 liquefied petroleum gas Substances 0.000 description 13
239000001294 propane Substances 0.000 description 13
WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
239000000463 material Substances 0.000 description 7
238000005342 ion exchange Methods 0.000 description 6
239000000126 substance Substances 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 5
239000011734 sodium Substances 0.000 description 5
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 4
230000005611 electricity Effects 0.000 description 4
239000007789 gas Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 3
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
239000000292 calcium oxide Substances 0.000 description 3
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
229910001414 potassium ion Inorganic materials 0.000 description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
229910001415 sodium ion Inorganic materials 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000003513 alkali Substances 0.000 description 2
239000000440 bentonite Substances 0.000 description 2
229910000278 bentonite Inorganic materials 0.000 description 2
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
229910001423 beryllium ion Inorganic materials 0.000 description 2
229910002090 carbon oxide Inorganic materials 0.000 description 2
238000000975 co-precipitation Methods 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
238000003795 desorption Methods 0.000 description 2
238000001514 detection method Methods 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000011591 potassium Substances 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
239000004113 Sepiolite Substances 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
229960000892 attapulgite Drugs 0.000 description 1
239000011324 bead Substances 0.000 description 1
239000001273 butane Substances 0.000 description 1
WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical group CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
150000001869 cobalt compounds Chemical class 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
229910052900 illite Inorganic materials 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
239000012528 membrane Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
238000000465 moulding Methods 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
229910052625 palygorskite Inorganic materials 0.000 description 1
239000008188 pellet Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
239000012071 phase Substances 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
238000002459 porosimetry Methods 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052624 sepiolite Inorganic materials 0.000 description 1
235000019355 sepiolite Nutrition 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0222—Compounds of Mn, Re
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0233—Compounds of Cu, Ag, Au
- B01J20/0237—Compounds of Cu
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28052—Several layers of identical or different sorbents stacked in a housing, e.g. in a column
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
- C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
- C10G25/05—Removal of non-hydrocarbon compounds, e.g. sulfur compounds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Analytical Chemistry (AREA)
Inorganic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
General Chemical & Material Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Combustion & Propulsion (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Fuel Cell (AREA)

CA002578233A 2004-09-01 2005-08-19 Systeme de desulfuration et procede pour desulfurer un flux de combustible Abandoned CA2578233A1 (fr)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US93217704A	2004-09-01	2004-09-01
US10/932,177		2004-09-01
US11/207,154		2005-08-18
US11/207,154 US20060043001A1 (en)	2004-09-01	2005-08-18	Desulfurization system and method for desulfurizing afuel stream
PCT/US2005/029715 WO2006028686A1 (fr)	2004-09-01	2005-08-19	Systeme de desulfuration et procede pour desulfurer un flux de combustible

Publications (1)

Publication Number	Publication Date
CA2578233A1 true CA2578233A1 (fr)	2006-03-16

Family

ID=35501806

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002578233A Abandoned CA2578233A1 (fr)	2004-09-01	2005-08-19	Systeme de desulfuration et procede pour desulfurer un flux de combustible

Country Status (5)

Country	Link
EP (1)	EP1802392A1 (fr)
JP (1)	JP2008511725A (fr)
KR (1)	KR20070056129A (fr)
CA (1)	CA2578233A1 (fr)
WO (1)	WO2006028686A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2783539C1 (ru) *	2019-01-15	2022-11-14	Ханивелл Интернэшнл Инк.	Интегрированные способы извлечения меркаптанов и/или обессеривания, объединенные с термическим окислением и обработкой дымовых газов

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US7780846B2 (en)	2004-09-01	2010-08-24	Sud-Chemie Inc.	Sulfur adsorbent, desulfurization system and method for desulfurizing
US20060283780A1 (en) *	2004-09-01	2006-12-21	Sud-Chemie Inc.,	Desulfurization system and method for desulfurizing a fuel stream
US8323603B2 (en) *	2004-09-01	2012-12-04	Sud-Chemie Inc.	Desulfurization system and method for desulfurizing a fuel stream
JP5275771B2 (ja) *	2008-12-10	2013-08-28	Ｊｘ日鉱日石エネルギー株式会社	脱硫器、並びにそれを備えた燃料電池コージェネレーションシステム及び脱硫システム
CN101664689B (zh) *	2009-09-16	2012-04-18	长春惠工净化工业有限公司	活性炭脱硫剂及其制备方法
DE102010014890A1 (de)	2010-04-14	2011-10-20	Süd-Chemie AG	Vorrichtung zur Adsorptionsbehandlung eines Fluids oder Fluidstroms, Verfahren zum Regenerieren und/oder Entsorgen, Befüllen und/oder Installieren einer Vorrichtung zur Adsorptionsbehandlung eines Fluids oder Fluidstroms und Verfahren zur Adsorptionsbehandlung eines Fluids oder Fluidstroms
DE202010016522U1 (de)	2010-04-14	2011-02-17	Süd-Chemie AG	Vorrichtung zur Adsorptionsbehandlung eines Fluids oder Fluidstroms
KR101613575B1 (ko)	2010-04-14	2016-04-19	클라리안트 프로두크테 (도이칠란트) 게엠베하	유체 또는 유체 스트림의 흡착 처리용 장치
KR20120085079A (ko) *	2011-01-21	2012-07-31	삼성전자주식회사	복합금속 산화물 촉매, 상기 촉매를 구비한 필터 모듈 및 이를 구비한 공기청정기
KR101956106B1 (ko) *	2016-08-23	2019-03-12	에이치앤파워(주)	다단 탈황 시스템의 운전방법
WO2019189550A1 (fr) *	2018-03-29	2019-10-03	日揮触媒化成株式会社	Adsorbant

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NL258555A (fr) *	1959-11-30
US4358297A (en) *	1980-01-02	1982-11-09	Exxon Research And Engineering Company	Removal of sulfur from process streams
JPH0333191A (ja) *	1989-03-17	1991-02-13	Fuji Electric Co Ltd	脱硫反応器
US5106484A (en) *	1990-12-19	1992-04-21	Exxon Chemical Patents Inc.	Purifying feed for reforming over zeolite catalysts
JPH06287575A (ja) *	1993-04-05	1994-10-11	Ishikawajima Harima Heavy Ind Co Ltd	脱硫方法及び装置
JP2001278602A (ja) *	2000-03-31	2001-10-10	Idemitsu Kosan Co Ltd	脱硫剤、脱硫方法及び燃料電池用水素の製造方法
JP4749589B2 (ja) *	2001-04-18	2011-08-17	出光興産株式会社	有機硫黄化合物含有燃料油用脱硫剤及び燃料電池用水素の製造方法
JP3895134B2 (ja) *	2001-07-05	2007-03-22	東京瓦斯株式会社	燃料ガスの脱硫装置及び脱硫方法
JP4676690B2 (ja) *	2002-11-05	2011-04-27	出光興産株式会社	金属イオン交換ゼオライト及びその製造方法、並びに該金属イオン交換ゼオライトを含む硫黄化合物除去用吸着剤
AU2003292768A1 (en) *	2002-12-26	2004-07-22	Idemitsu Kosan Co., Ltd.	Method for removing sulfur compound in hydrocarbon-containing gas

2005
- 2005-08-19 WO PCT/US2005/029715 patent/WO2006028686A1/fr not_active Ceased
- 2005-08-19 CA CA002578233A patent/CA2578233A1/fr not_active Abandoned
- 2005-08-19 KR KR1020077007091A patent/KR20070056129A/ko not_active Withdrawn
- 2005-08-19 JP JP2007530001A patent/JP2008511725A/ja active Pending
- 2005-08-19 EP EP05808760A patent/EP1802392A1/fr not_active Withdrawn

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2783539C1 (ru) *	2019-01-15	2022-11-14	Ханивелл Интернэшнл Инк.	Интегрированные способы извлечения меркаптанов и/или обессеривания, объединенные с термическим окислением и обработкой дымовых газов

Also Published As

Publication number	Publication date
JP2008511725A (ja)	2008-04-17
KR20070056129A (ko)	2007-05-31
WO2006028686A1 (fr)	2006-03-16
EP1802392A1 (fr)	2007-07-04

Legal Events

Date	Code	Title	Description
2011-08-19	FZDE	Discontinued

Publication	Publication Date	Title
US20060283780A1 (en)	2006-12-21	Desulfurization system and method for desulfurizing a fuel stream
US8658321B2 (en)	2014-02-25	Desulfurization system and method for desulfurizing a fuel stream
US20060043001A1 (en)	2006-03-02	Desulfurization system and method for desulfurizing afuel stream
WO2008082849A2 (fr)	2008-07-10	Adsorbant de soufre, système de désulfuration et procédé de désulfuration
CN102170953B (zh)	2015-02-04	吸附剂材料和含烃气体脱硫的方法
Vellingiri et al.	2016	Metal–organic frameworks as a potential platform for selective treatment of gaseous sulfur compounds
US20020009404A1 (en)	2002-01-24	Molecular sieve adsorbent-catalyst for sulfur compound contaminated gas and liquid streams and process for its use
CA2511998C (fr)	2011-11-22	Procede permettant d'oter un compose de soufre dans un gaz contenant un hydrocarbure
Ratnasamy et al.	2012	Removal of sulfur compounds from natural gas for fuel cell applications using a sequential bed system
AU2008349418B2 (en)	2013-05-02	Contaminant removal from a gas stream
US20050121365A1 (en)	2005-06-09	Process for removal of sulfur compounds from a fuel cell feed stream
WO2006028686A1 (fr)	2006-03-16	Systeme de desulfuration et procede pour desulfurer un flux de combustible
WO2004060840A2 (fr)	2004-07-22	Lit de sorption a composants multiples destine la desulfuration d'hydrocarbures
CA2619231A1 (fr)	2007-02-22	Agent de desulfurisation pour eliminer les composes organiques soufres, methode de preparation de cet agent et methode pour eliminer ces composes a l'aide de cet agent
CA2694776A1 (fr)	2009-02-12	Catalyseur et procede de desulfuration de gaz contenant des hydrocarbures
CA2854463A1 (fr)	2013-05-10	Procede pour eliminer des composes soufres d'un melange gazeux contenant des hydrocarbures
JP2010037480A (ja)	2010-02-18	燃料ガス中の付臭剤除去装置

CA2578233A1 - Systeme de desulfuration et procede pour desulfurer un flux de combustible - Google Patents

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Applications Claiming Priority (5)

Publications (1)

Family

ID=35501806

Family Applications (1)

Country Status (5)

Cited By (1)

Families Citing this family (11)

Family Cites Families (10)

Cited By (1)

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