CA2597808C - Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant - Google Patents

Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant Download PDF

Info

Publication number: CA2597808C
Authority: CA; Canada
Prior art keywords: catalyst; sorber; accordance; sulfur; sorption
Prior art date: 1998-07-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA2597808A

Other languages

English (en)

Other versions

CA2597808A1 (fr

Inventor

Larry E. Campbell

Gregory J. Wagner

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Miratech Knoxville LLC

Original Assignee

Goal Line Environmental Technologies LLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-07-10

Filing date

1999-06-16

Publication date

2010-09-21

1998-07-10 Priority claimed from US09/113,258 external-priority patent/US6037307A/en

1999-06-16 Application filed by Goal Line Environmental Technologies LLC filed Critical Goal Line Environmental Technologies LLC

2000-01-20 Publication of CA2597808A1 publication Critical patent/CA2597808A1/fr

2010-09-21 Application granted granted Critical

2010-09-21 Publication of CA2597808C publication Critical patent/CA2597808C/fr

2019-06-16 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 98
238000000034 method Methods 0.000 title claims abstract description 28
150000003464 sulfur compounds Chemical class 0.000 title description 15
239000000203 mixture Substances 0.000 claims abstract description 31
239000003607 modifier Substances 0.000 claims abstract description 31
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
229930195733 hydrocarbon Natural products 0.000 claims abstract description 6
230000003647 oxidation Effects 0.000 claims abstract description 6
238000007254 oxidation reaction Methods 0.000 claims abstract description 6
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
229910052697 platinum Inorganic materials 0.000 claims description 14
230000001590 oxidative effect Effects 0.000 claims description 11
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
239000000919 ceramic Substances 0.000 claims description 7
229910052760 oxygen Inorganic materials 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
-1 C12 hydrocarbons Chemical class 0.000 claims description 3
238000002485 combustion reaction Methods 0.000 claims description 3
229910052786 argon Inorganic materials 0.000 claims description 2
239000002131 composite material Substances 0.000 claims description 2
229910052734 helium Inorganic materials 0.000 claims description 2
239000001307 helium Substances 0.000 claims description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims 2
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract description 134
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 42
229910000037 hydrogen sulfide Inorganic materials 0.000 abstract description 42
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 39
229910052717 sulfur Inorganic materials 0.000 abstract description 39
239000011593 sulfur Substances 0.000 abstract description 39
239000007789 gas Substances 0.000 abstract description 26
229910052802 copper Inorganic materials 0.000 abstract description 15
229910052797 bismuth Inorganic materials 0.000 abstract description 12
229910052709 silver Inorganic materials 0.000 abstract description 12
229910000510 noble metal Inorganic materials 0.000 abstract description 9
229910052719 titanium Inorganic materials 0.000 abstract description 5
229910052726 zirconium Inorganic materials 0.000 abstract description 5
150000002430 hydrocarbons Chemical class 0.000 abstract description 4
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 3
229910052684 Cerium Inorganic materials 0.000 abstract description 3
229910052782 aluminium Inorganic materials 0.000 abstract description 3
229910052735 hafnium Inorganic materials 0.000 abstract description 3
239000011261 inert gas Substances 0.000 abstract description 2
229910052710 silicon Inorganic materials 0.000 abstract description 2
239000000356 contaminant Substances 0.000 abstract 5
229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 79
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 60
238000001179 sorption measurement Methods 0.000 description 42
230000008929 regeneration Effects 0.000 description 38
238000011069 regeneration method Methods 0.000 description 38
239000010949 copper Substances 0.000 description 36
238000011068 loading method Methods 0.000 description 16
238000003795 desorption Methods 0.000 description 11
230000000694 effects Effects 0.000 description 11
150000001875 compounds Chemical class 0.000 description 7
229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
230000002829 reductive effect Effects 0.000 description 7
229920006395 saturated elastomer Polymers 0.000 description 7
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
241000264877 Hippospongia communis Species 0.000 description 6
230000003750 conditioning effect Effects 0.000 description 6
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Inorganic materials [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 6
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
238000005516 engineering process Methods 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
230000003247 decreasing effect Effects 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
239000008188 pellet Substances 0.000 description 4
238000002336 sorption--desorption measurement Methods 0.000 description 4
238000012360 testing method Methods 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
230000001143 conditioned effect Effects 0.000 description 3
239000000463 material Substances 0.000 description 3
239000002243 precursor Substances 0.000 description 3
239000004332 silver Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000005083 Zinc sulfide Substances 0.000 description 2
229910052787 antimony Inorganic materials 0.000 description 2
229910052785 arsenic Inorganic materials 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
239000000969 carrier Substances 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
229910052878 cordierite Inorganic materials 0.000 description 2
230000001351 cycling effect Effects 0.000 description 2
JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
238000005203 dry scrubbing Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000003546 flue gas Substances 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
229910052738 indium Inorganic materials 0.000 description 2
229910052745 lead Inorganic materials 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000001172 regenerating effect Effects 0.000 description 2
229910052815 sulfur oxide Inorganic materials 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
238000005200 wet scrubbing Methods 0.000 description 2
229910052984 zinc sulfide Inorganic materials 0.000 description 2
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
239000010963 304 stainless steel Substances 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
241001507939 Cormus domestica Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
235000019738 Limestone Nutrition 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
235000010261 calcium sulphite Nutrition 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000009533 lab test Methods 0.000 description 1
239000006028 limestone Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910001960 metal nitrate Inorganic materials 0.000 description 1
229910052863 mullite Inorganic materials 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
239000010802 sludge Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000011343 solid material Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

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Catalysts (AREA)

CA2597808A 1998-07-10 1999-06-16 Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant Expired - Lifetime CA2597808C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US09/113,258		1998-07-10
US09/113,258 US6037307A (en)	1998-07-10	1998-07-10	Catalyst/sorber for treating sulfur compound containing effluent
CA002336855A CA2336855C (fr)	1998-07-10	1999-06-16	Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002336855A Division CA2336855C (fr)	1998-07-10	1999-06-16	Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant

Publications (2)

Publication Number	Publication Date
CA2597808A1 CA2597808A1 (fr)	2000-01-20
CA2597808C true CA2597808C (fr)	2010-09-21

Family

ID=38663541

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA2597808A Expired - Lifetime CA2597808C (fr)	1998-07-10	1999-06-16	Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant

Country Status (1)

Country	Link
CA (1)	CA2597808C (fr)

1999
- 1999-06-16 CA CA2597808A patent/CA2597808C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2597808A1 (fr)	2000-01-20

Legal Events

Date	Code	Title	Description
2007-08-31	EEER	Examination request
2019-08-19	MKEX	Expiry	Effective date: 20190617

Publication	Publication Date	Title
CA2336855C (fr)	2007-11-13	Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant
EP0947234B1 (fr)	2004-11-10	Procédé catalytique sec à une étape pour la séparation simultanée de dioxyde de soufre et d'oxydes d'azote de courant gazeux
Knoblauch et al.	1981	Application of active coke in processes of SO2-and NOx-removal from flue gases
US4001375A (en)	1977-01-04	Process for the desulfurization of flue gas
CA2397226C (fr)	2009-09-29	Procede, systeme catalyseur et appareil de traitement de compose de soufre contenant un effluent
US6610264B1 (en)	2003-08-26	Process and system for desulfurizing a gas stream
CA2193638C (fr)	2000-01-25	Systemes de traitement des gaz d'echappement
US7906085B2 (en)	2011-03-15	Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control
US5202101A (en)	1993-04-13	Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream
JPS5837008B2 (ja)	1983-08-13	ガス類からの窒素酸化物及び硫黄酸化物の除去
JPS6268527A (ja)	1987-03-28	硫化水素との反応によつて再生しうる吸収物質を用いる、ガスからの硫黄酸化物の除去方法
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WO2002022239A1 (fr)	2002-03-21	Elimination d'oxydes de soufre des gaz d'echappement provenant de processus de combustion
JPS594175B2 (ja)	1984-01-28	被覆触媒を使用する窒素酸化物除去
US6106791A (en)	2000-08-22	Exhaust gas treating systems
JPH119933A (ja)	1999-01-19	気体からの窒素酸化物除去方法
US6814948B1 (en)	2004-11-09	Exhaust gas treating systems
Li et al.	1997	Selective Adsorption of NO x from Hot Combustion Gases by Ce-Doped CuO/TiO2
CN112536031B (zh)	2022-10-11	用于处理工业废气的催化剂及其制备方法
CA2597808C (fr)	2010-09-21	Catalyseur/agent sorbant aux fins du traitement d'un effluent contenant un compose sulfure et procede correspondant
MXPA01000311A (es)	2002-02-26	Proceso y catalizador/sorbente para tratar un compuesto de azufre que contiene efluente
EP0504476B1 (fr)	1997-02-19	Procédé et dispositif régénérateur pour l'élimination simultanée de particules et d'oxydes de soufre et d'azote d'un courant gazeux
Bereketidou et al.	2012	Simultaneous removal of NO and SO2 from combustion flue gases using supported copper oxide catalysts
Eguchi et al.	2002	Catalytically Promoted NO x Sorption by ZrO2-Based Oxides
JPH07256052A (ja)	1995-10-09	排煙同時脱硫・脱硝方法