CA2600876A1 - Adsorbants eliminant le mercure des fumees industrielles - Google Patents
Adsorbants eliminant le mercure des fumees industrielles Download PDFInfo
- Publication number
- CA2600876A1 CA2600876A1 CA002600876A CA2600876A CA2600876A1 CA 2600876 A1 CA2600876 A1 CA 2600876A1 CA 002600876 A CA002600876 A CA 002600876A CA 2600876 A CA2600876 A CA 2600876A CA 2600876 A1 CA2600876 A1 CA 2600876A1
- Authority
- CA
- Canada
- Prior art keywords
- halide salt
- group
- cation
- reaction chamber
- carbonaceous feedstock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003463 adsorbent Substances 0.000 title claims abstract 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract 7
- 239000003546 flue gas Substances 0.000 title claims abstract 7
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims 9
- 229910052753 mercury Inorganic materials 0.000 title claims 9
- 238000000034 method Methods 0.000 claims abstract 45
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 26
- -1 halide salt Chemical class 0.000 claims abstract 23
- 230000003197 catalytic effect Effects 0.000 claims abstract 10
- 238000004519 manufacturing process Methods 0.000 claims abstract 5
- 238000001179 sorption measurement Methods 0.000 claims abstract 5
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims 20
- 239000000203 mixture Substances 0.000 claims 19
- 239000007789 gas Substances 0.000 claims 17
- 150000001768 cations Chemical class 0.000 claims 16
- 150000001450 anions Chemical class 0.000 claims 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 10
- 239000003245 coal Substances 0.000 claims 10
- QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 claims 10
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims 8
- 230000003213 activating effect Effects 0.000 claims 8
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 5
- 229910021590 Copper(II) bromide Inorganic materials 0.000 claims 5
- 229910021592 Copper(II) chloride Inorganic materials 0.000 claims 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims 5
- 229910052791 calcium Inorganic materials 0.000 claims 5
- 229910001622 calcium bromide Inorganic materials 0.000 claims 5
- 239000001110 calcium chloride Substances 0.000 claims 5
- 235000011148 calcium chloride Nutrition 0.000 claims 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims 5
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims 5
- 229910052802 copper Inorganic materials 0.000 claims 5
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims 5
- 229910001623 magnesium bromide Inorganic materials 0.000 claims 5
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims 5
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- 229910052700 potassium Inorganic materials 0.000 claims 5
- 229910052708 sodium Inorganic materials 0.000 claims 5
- 239000011780 sodium chloride Substances 0.000 claims 5
- 229910052723 transition metal Inorganic materials 0.000 claims 5
- 150000003624 transition metals Chemical class 0.000 claims 5
- 229910052749 magnesium Inorganic materials 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- 239000001103 potassium chloride Substances 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 230000001590 oxidative effect Effects 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 239000000843 powder Substances 0.000 claims 3
- 239000007864 aqueous solution Substances 0.000 claims 2
- 239000002802 bituminous coal Substances 0.000 claims 2
- 239000002019 doping agent Substances 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 239000011261 inert gas Substances 0.000 claims 2
- 239000003077 lignite Substances 0.000 claims 2
- 230000009257 reactivity Effects 0.000 claims 2
- 239000003476 subbituminous coal Substances 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 1
- 238000007580 dry-mixing Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3021—Milling, crushing or grinding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/078,509 US20060205592A1 (en) | 2005-03-14 | 2005-03-14 | Catalytic adsorbents for mercury removal from flue gas and methods of manufacture therefor |
| US11/078,509 | 2005-03-14 | ||
| US11/224,149 US8017550B2 (en) | 2005-03-14 | 2005-09-12 | Catalytic adsorbents for mercury removal from flue gas and methods of manufacture therefor |
| US11/224,149 | 2005-09-12 | ||
| PCT/US2006/008895 WO2006099291A2 (fr) | 2005-03-14 | 2006-03-13 | Adsorbants eliminant le mercure des fumees industrielles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2600876A1 true CA2600876A1 (fr) | 2006-09-21 |
| CA2600876C CA2600876C (fr) | 2011-10-11 |
Family
ID=36992336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2600876A Expired - Fee Related CA2600876C (fr) | 2005-03-14 | 2006-03-13 | Adsorbants eliminant le mercure des fumees industrielles |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1866245A4 (fr) |
| KR (1) | KR20070113287A (fr) |
| CA (1) | CA2600876C (fr) |
| WO (1) | WO2006099291A2 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8198208B2 (en) | 2008-10-03 | 2012-06-12 | EPCOR Power Generation Services, Inc. | Bromination process |
| CN118831557A (zh) * | 2024-06-25 | 2024-10-25 | 青岛科技大学 | 一种碳包裹的CoSe2纳米颗粒吸附剂在吸附有色冶炼烟气Hg0的应用 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080127631A1 (en) * | 2006-11-30 | 2008-06-05 | General Electric Company | Method for removal of mercury from the emissions stream of a power plant and an apparatus for achieving the same |
| US7767007B2 (en) * | 2006-12-08 | 2010-08-03 | Praxair Technology, Inc. | Mercury adsorbents compatible as cement additives |
| US20120134903A1 (en) * | 2009-07-13 | 2012-05-31 | Alain Brasseur | Solid Inorganic Composition, Method for Preparing Same, and Use Thereof for Reducing Dioxins and Heavy Metals in Flue Gas |
| US9468904B2 (en) | 2013-12-31 | 2016-10-18 | Ada Carbon Solutions, Llc | Sorbent compositions having pneumatic conveyance capabilities |
| US10035126B2 (en) | 2013-12-31 | 2018-07-31 | Ada Carbon Solutions, Llc | Sorbent compositions having pneumatic conveyance capabilities |
| US9314767B2 (en) | 2014-03-07 | 2016-04-19 | Ada Carbon Solutions, Llc | Sorbent compositions having pneumatic conveyance capabilities |
| CN114130357B (zh) * | 2021-12-03 | 2024-11-12 | 海西州盐化工产品质量检验检测中心 | 一种盐湖老卤改性生物炭的制备方法及其应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2633484B2 (ja) * | 1993-12-22 | 1997-07-23 | 三井石油化学工業株式会社 | 液体炭化水素分中の水銀の除去方法 |
| US5556447A (en) * | 1995-01-23 | 1996-09-17 | Physical Sciences, Inc. | Process for treating metal-contaminated materials |
| DE69817942T2 (de) * | 1997-07-28 | 2004-07-29 | Corning Inc. | Katalysator zum Entfernen von Quecksilber und Verfahren zu dessen Herstellung und Verwendung |
| JP4493824B2 (ja) * | 2000-09-28 | 2010-06-30 | 日本パイオニクス株式会社 | 有害ガスの浄化方法及び浄化剤 |
-
2006
- 2006-03-13 WO PCT/US2006/008895 patent/WO2006099291A2/fr not_active Ceased
- 2006-03-13 CA CA2600876A patent/CA2600876C/fr not_active Expired - Fee Related
- 2006-03-13 KR KR1020077023456A patent/KR20070113287A/ko not_active Ceased
- 2006-03-13 EP EP06738007A patent/EP1866245A4/fr not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8198208B2 (en) | 2008-10-03 | 2012-06-12 | EPCOR Power Generation Services, Inc. | Bromination process |
| CN118831557A (zh) * | 2024-06-25 | 2024-10-25 | 青岛科技大学 | 一种碳包裹的CoSe2纳米颗粒吸附剂在吸附有色冶炼烟气Hg0的应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006099291A2 (fr) | 2006-09-21 |
| WO2006099291A8 (fr) | 2007-12-21 |
| WO2006099291A3 (fr) | 2006-11-30 |
| CA2600876C (fr) | 2011-10-11 |
| EP1866245A2 (fr) | 2007-12-19 |
| EP1866245A4 (fr) | 2012-12-05 |
| KR20070113287A (ko) | 2007-11-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20210315 |