CA2633540A1 - Procede de traitement d'une pulpe de cellulose-lignine - Google Patents

Procede de traitement d'une pulpe de cellulose-lignine Download PDF

Info

Publication number: CA2633540A1
Authority: CA; Canada
Prior art keywords: pulp; ozone; chelant; cellulose; stage
Prior art date: 2005-12-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002633540A

Other languages

English (en)

Inventor

Dwane Scott Hutto

Haixuan Zou

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

University of Maine System

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2005-12-14

Filing date

2006-12-12

Publication date

2007-06-21

2006-12-12 Application filed by Individual filed Critical Individual

2007-06-21 Publication of CA2633540A1 publication Critical patent/CA2633540A1/fr

Status Abandoned legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 74
230000008569 process Effects 0.000 title claims abstract description 73
229920005610 lignin Polymers 0.000 title claims abstract description 31
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 102
239000013522 chelant Substances 0.000 claims abstract description 32
239000007844 bleaching agent Substances 0.000 claims abstract description 19
150000002978 peroxides Chemical class 0.000 claims abstract description 9
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 46
238000004061 bleaching Methods 0.000 claims description 20
238000000354 decomposition reaction Methods 0.000 claims description 20
229920001131 Pulp (paper) Polymers 0.000 claims description 17
239000000463 material Substances 0.000 claims description 12
229910052751 metal Inorganic materials 0.000 claims description 12
239000002184 metal Substances 0.000 claims description 12
229920002678 cellulose Polymers 0.000 claims description 11
239000001913 cellulose Substances 0.000 claims description 11
150000002739 metals Chemical class 0.000 claims description 10
229910021654 trace metal Inorganic materials 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 8
239000000725 suspension Substances 0.000 claims description 6
230000015556 catabolic process Effects 0.000 claims description 5
238000006243 chemical reaction Methods 0.000 claims description 5
239000003795 chemical substances by application Substances 0.000 claims description 5
238000006731 degradation reaction Methods 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical group [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 4
150000001912 cyanamides Chemical class 0.000 claims description 3
230000006872 improvement Effects 0.000 claims description 3
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 2
230000004913 activation Effects 0.000 claims description 2
230000003213 activating effect Effects 0.000 claims 1
230000035484 reaction time Effects 0.000 claims 1
150000003254 radicals Chemical class 0.000 description 19
238000004537 pulping Methods 0.000 description 13
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
239000001301 oxygen Substances 0.000 description 12
229910052760 oxygen Inorganic materials 0.000 description 12
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
239000000460 chlorine Substances 0.000 description 10
229910052801 chlorine Inorganic materials 0.000 description 10
238000002474 experimental method Methods 0.000 description 10
239000000835 fiber Substances 0.000 description 6
239000000123 paper Substances 0.000 description 6
230000008859 change Effects 0.000 description 5
230000009920 chelation Effects 0.000 description 5
241000894007 species Species 0.000 description 5
241000196324 Embryophyta Species 0.000 description 4
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
239000006227 byproduct Substances 0.000 description 4
239000002655 kraft paper Substances 0.000 description 4
239000002023 wood Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000011121 hardwood Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical class OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
235000005018 Pinus echinata Nutrition 0.000 description 2
241001236219 Pinus echinata Species 0.000 description 2
235000017339 Pinus palustris Nutrition 0.000 description 2
229920002522 Wood fibre Polymers 0.000 description 2
239000002253 acid Substances 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
239000012190 activator Substances 0.000 description 2
230000008901 benefit Effects 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
238000011109 contamination Methods 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
230000001066 destructive effect Effects 0.000 description 2
230000029087 digestion Effects 0.000 description 2
229960001484 edetic acid Drugs 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
229960003330 pentetic acid Drugs 0.000 description 2
238000011084 recovery Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
238000005406 washing Methods 0.000 description 2
239000002025 wood fiber Substances 0.000 description 2
OGRXKBUCZFFSTL-UHFFFAOYSA-N 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol Chemical compound O=NN(C)CCCC(O)C1=CC=CN=C1 OGRXKBUCZFFSTL-UHFFFAOYSA-N 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
101100130497 Drosophila melanogaster Mical gene Proteins 0.000 description 1
101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
241000209504 Poaceae Species 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
241000209140 Triticum Species 0.000 description 1
235000021307 Triticum Nutrition 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
235000009120 camo Nutrition 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
235000005607 chanvre indien Nutrition 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000010276 construction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000011487 hemp Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000012978 lignocellulosic material Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000005457 optimization Methods 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000012286 potassium permanganate Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000009420 retrofitting Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
229910052979 sodium sulfide Inorganic materials 0.000 description 1
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
239000011122 softwood Substances 0.000 description 1
229910021655 trace metal ion Inorganic materials 0.000 description 1
230000003313 weakening effect Effects 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1042—Use of chelating agents

Landscapes

Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Wood Science & Technology (AREA)
Paper (AREA)

CA002633540A 2005-12-14 2006-12-12 Procede de traitement d'une pulpe de cellulose-lignine Abandoned CA2633540A1 (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US11/300,126 US20070131364A1 (en)	2005-12-14	2005-12-14	Process for treating a cellulose-lignin pulp
US11/300,126		2005-12-14
PCT/US2006/047416 WO2007070527A2 (fr)	2005-12-14	2006-12-12	Procede de traitement d’une pulpe de cellulose-lignine

Publications (1)

Publication Number	Publication Date
CA2633540A1 true CA2633540A1 (fr)	2007-06-21

Family

ID=38138100

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002633540A Abandoned CA2633540A1 (fr)	2005-12-14	2006-12-12	Procede de traitement d'une pulpe de cellulose-lignine

Country Status (10)

Country	Link
US (1)	US20070131364A1 (fr)
EP (1)	EP1979532A4 (fr)
JP (1)	JP2009520120A (fr)
CN (1)	CN101426975B (fr)
AU (1)	AU2006326561B8 (fr)
BR (1)	BRPI0619948A2 (fr)
CA (1)	CA2633540A1 (fr)
NO (1)	NO20082756L (fr)
WO (1)	WO2007070527A2 (fr)
ZA (1)	ZA200804881B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20080221132A1 (en) *	2006-09-11	2008-09-11	Xiong Cai	Multi-Functional Small Molecules as Anti-Proliferative Agents
PL2861799T3 (pl)	2012-06-13	2020-01-31	University Of Maine System Board Of Trustees	Wydajny energetycznie sposób wytwarzania włókien nanocelulozowych
CN106283794B (zh) *	2016-11-02	2017-11-21	江南大学	一种利用臭氧去除麻纤维木质素的方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4119486A (en) *	1975-08-14	1978-10-10	Westvaco Corporation	Process for bleaching wood pulp with ozone in the presence of a cationic surfactant
US4238282A (en) *	1979-07-23	1980-12-09	Nalco Chemical Company	Chemical treatments in bleaching stages which increase pulp brightness
DE3544398A1 (de) *	1985-12-16	1987-06-19	Sueddeutsche Kalkstickstoff	Verfahren zur bleiche und delignifizierung von zellstoffhaltigen produkten
US5188708A (en) *	1989-02-15	1993-02-23	Union Camp Patent Holding, Inc.	Process for high consistency oxygen delignification followed by ozone relignification
US5164043A (en) *	1990-05-17	1992-11-17	Union Camp Patent Holding, Inc.	Environmentally improved process for bleaching lignocellulosic materials with ozone
US5164044A (en) *	1990-05-17	1992-11-17	Union Camp Patent Holding, Inc.	Environmentally improved process for bleaching lignocellulosic materials with ozone
JP2002517173A (ja) *	1991-01-03	2002-06-11	ユニオンキャンプパテントホウルディングインコーポレイテッド	塩素を使用しないリグノセルロースパルプの漂白法
SE468355B (sv) *	1991-04-30	1992-12-21	Eka Nobel Ab	Blekning av kemisk massa genom behandling med komplexbildare och ozon
US5364503A (en) *	1992-02-20	1994-11-15	Macmillan Bloedel Limited	Nitric oxide treatment for ozone bleaching
BE1006057A3 (fr) *	1992-07-06	1994-05-03	Solvay Interox	Procede pour la delignification d'une pate a papier chimique.
ATE163206T1 (de) *	1992-10-23	1998-02-15	Mac Millan Bloedel Ltd	Verbessertes ozonbleichen
US5364506A (en) *	1993-04-28	1994-11-15	The Board Of Trustees Of The Leland Stanford Junior University	Method and apparatus for partial oxidation of methane and cogeneration of electrical energy
SE9301960L (sv) *	1993-06-08	1994-07-25	Kvaerner Pulping Tech	Blekning av kemisk massa med peroxid vid övertryck
SE502667C2 (sv) *	1993-07-12	1995-12-04	Kvaerner Pulping Tech	Behandling av fibermaterial med komplexbildare före kokning
US5662803A (en) *	1996-04-09	1997-09-02	Nalco Chemical Company	Stabilizers for additives in aqueous systems containing ozone
CA2189724A1 (fr) *	1996-07-08	1998-01-09	Suezone Chow	Methode de reduction en pate
PT925401E (pt) *	1996-09-11	2002-07-31	Solvay Interox Sa	Processo para o branqueamento de pasta de papel
AU3404099A (en) *	1998-04-17	1999-11-08	Alberta Research Council Inc.	Method of producing lignocellulosic pulp from non-woody species
SE514947C2 (sv) *	1998-09-09	2001-05-21	Valmet Fibertech Ab	Blekning av massa med ozon innefattande oxalsyratillsats
US6302997B1 (en) *	1999-08-30	2001-10-16	North Carolina State University	Process for producing a pulp suitable for papermaking from nonwood fibrous materials
US7396974B2 (en) *	2002-02-08	2008-07-08	University Of Maine	Oxidation using a non-enzymatic free radical system mediated by redox cycling chelators
DE10320618A1 (de) *	2003-05-08	2004-11-18	Papierfabrik Albbruck Gmbh & Co. Kg	Verfahren zum Bleichen von Faserstoffen

2005
- 2005-12-14 US US11/300,126 patent/US20070131364A1/en not_active Abandoned
2006
- 2006-12-12 CN CN2006800468212A patent/CN101426975B/zh not_active Expired - Fee Related
- 2006-12-12 CA CA002633540A patent/CA2633540A1/fr not_active Abandoned
- 2006-12-12 BR BRPI0619948-8A patent/BRPI0619948A2/pt not_active IP Right Cessation
- 2006-12-12 AU AU2006326561A patent/AU2006326561B8/en not_active Ceased
- 2006-12-12 EP EP06839344A patent/EP1979532A4/fr not_active Withdrawn
- 2006-12-12 WO PCT/US2006/047416 patent/WO2007070527A2/fr not_active Ceased
- 2006-12-12 JP JP2008545747A patent/JP2009520120A/ja active Pending
2008
- 2008-06-04 ZA ZA200804881A patent/ZA200804881B/xx unknown
- 2008-06-18 NO NO20082756A patent/NO20082756L/no not_active Application Discontinuation

Also Published As

Publication number	Publication date
NO20082756L (no)	2008-08-11
US20070131364A1 (en)	2007-06-14
WO2007070527A3 (fr)	2008-11-13
EP1979532A2 (fr)	2008-10-15
JP2009520120A (ja)	2009-05-21
CN101426975B (zh)	2011-09-21
CN101426975A (zh)	2009-05-06
EP1979532A4 (fr)	2011-09-28
AU2006326561B2 (en)	2011-03-17
AU2006326561A1 (en)	2007-06-21
WO2007070527A2 (fr)	2007-06-21
ZA200804881B (en)	2009-03-25
BRPI0619948A2 (pt)	2011-10-25
AU2006326561B8 (en)	2011-04-07

Legal Events

Date	Code	Title	Description
2011-10-26	EEER	Examination request
2014-02-06	FZDE	Discontinued	Effective date: 20131212

Publication	Publication Date	Title
JP2843892B2 (ja)	1999-01-06	リグノセルロース含有パルプの漂白方法
CA2067295C (fr)	1996-07-23	Procede de blanchiment de matiere contenant de la lignocellulose
DE19614587A1 (de)	1997-10-16	Verfahren und Bleichlösung zum Bleichen von cellulosischen Faserstoffen
US6702921B2 (en)	2004-03-09	Methods to enhance pulp bleaching and delignification using an organic sulfide chelating agent
US20150240423A1 (en)	2015-08-27	Effect of low dose xylanase on pulp in prebleach treatment process
EP0789798B1 (fr)	1998-06-24	Procede de delignification et de blanchiment de cellulose chimique
CA2669032C (fr)	2013-03-19	Procede de blanchiment ameliore avec au moins une etape d'extraction
AU2006326561B8 (en)	2011-04-07	Process for treating a cellulose-lignin pulp
US11384480B2 (en)	2022-07-12	Method for bleaching paper pulp
RU2479683C2 (ru)	2013-04-20	Способы и системы для отбеливания лигноцеллюлозных масс после варки с содой и антрахиноном
JP2009138293A (ja)	2009-06-25	漂白アルカリ化学パルプの製造方法
US20120031575A1 (en)	2012-02-09	Pulp Bleaching and Alkaline Extraction Method
US20100224336A1 (en)	2010-09-09	Process of bleaching a wood pulp
EP0652321B1 (fr)	1998-01-21	Blanchiment de pâte à papier chimique
JPH10121393A (ja)	1998-05-12	パルプ化方法
US5645688A (en)	1997-07-08	Bleaching compositions and processes employing sulfamates and polyaminocarboxylic acids
CA3049171C (fr)	2025-09-02	Procede de blanchiment d'une pate a papier
LT3269B (en)	1995-05-25	Process for bleaching of lignocellulose-containing pulps