CA2658841C - Activation, refining, and use of oil shale - Google Patents
Activation, refining, and use of oil shale Download PDFInfo
- Publication number
- CA2658841C CA2658841C CA2658841A CA2658841A CA2658841C CA 2658841 C CA2658841 C CA 2658841C CA 2658841 A CA2658841 A CA 2658841A CA 2658841 A CA2658841 A CA 2658841A CA 2658841 C CA2658841 C CA 2658841C
- Authority
- CA
- Canada
- Prior art keywords
- oil shale
- activated
- activation
- shale
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004058 oil shale Substances 0.000 title claims abstract description 204
- 230000004913 activation Effects 0.000 title abstract description 44
- 238000007670 refining Methods 0.000 title abstract description 8
- 238000001994 activation Methods 0.000 claims abstract description 72
- 230000006641 stabilisation Effects 0.000 claims abstract description 19
- 238000000605 extraction Methods 0.000 claims abstract description 18
- 239000000356 contaminant Substances 0.000 claims abstract description 14
- 238000011105 stabilization Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims description 71
- 230000008569 process Effects 0.000 claims description 56
- 239000000126 substance Substances 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000002904 solvent Substances 0.000 claims description 20
- 239000005416 organic matter Substances 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 16
- 239000011707 mineral Substances 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 10
- 239000007791 liquid phase Substances 0.000 claims description 9
- -1 inorganic base compound Chemical class 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 229910052785 arsenic Inorganic materials 0.000 claims description 6
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052793 cadmium Inorganic materials 0.000 claims description 5
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- 239000011651 chromium Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
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- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 2
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- 239000003079 shale oil Substances 0.000 claims description 2
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- 235000013311 vegetables Nutrition 0.000 abstract description 2
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- 238000001179 sorption measurement Methods 0.000 description 41
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 33
- 239000000047 product Substances 0.000 description 29
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- 235000019198 oils Nutrition 0.000 description 15
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- 238000007725 thermal activation Methods 0.000 description 10
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 9
- 229960000907 methylthioninium chloride Drugs 0.000 description 9
- 244000166071 Shorea robusta Species 0.000 description 8
- 235000015076 Shorea robusta Nutrition 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 239000011133 lead Substances 0.000 description 8
- 239000010880 spent shale Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
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- 239000011777 magnesium Substances 0.000 description 3
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- 239000002366 mineral element Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229910052776 Thorium Inorganic materials 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
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- 239000008367 deionised water Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
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- 239000000446 fuel Substances 0.000 description 2
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- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000019640 taste Nutrition 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 101100298225 Caenorhabditis elegans pot-2 gene Proteins 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 208000019693 Lung disease Diseases 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 241000206607 Porphyra umbilicalis Species 0.000 description 1
- 241000923606 Schistes Species 0.000 description 1
- 238000000944 Soxhlet extraction Methods 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- VTXYFVHXMBFNNN-UHFFFAOYSA-N [As].[Cd].[Pb] Chemical compound [As].[Cd].[Pb] VTXYFVHXMBFNNN-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
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- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
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- 239000011521 glass Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
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- 229910001425 magnesium ion Inorganic materials 0.000 description 1
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- 238000009832 plasma treatment Methods 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
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- 238000002211 ultraviolet spectrum Methods 0.000 description 1
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- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
- C10G1/047—Hot water or cold water extraction processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Fats And Perfumes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA200606169 | 2006-07-26 | ||
| ZA2006/06169 | 2006-07-26 | ||
| PCT/ZA2007/000043 WO2008014526A2 (en) | 2006-07-26 | 2007-07-19 | Activation, refining, and use of oil shale |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2658841A1 CA2658841A1 (en) | 2008-01-31 |
| CA2658841C true CA2658841C (en) | 2015-11-24 |
Family
ID=38890218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2658841A Expired - Fee Related CA2658841C (en) | 2006-07-26 | 2007-07-19 | Activation, refining, and use of oil shale |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20090308793A1 (de) |
| EP (1) | EP2046494A2 (de) |
| CN (1) | CN101516495B (de) |
| AU (1) | AU2007278836B2 (de) |
| CA (1) | CA2658841C (de) |
| IL (1) | IL196597A (de) |
| MA (1) | MA30646B1 (de) |
| RU (1) | RU2443468C2 (de) |
| WO (1) | WO2008014526A2 (de) |
| ZA (1) | ZA200900587B (de) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7931784B2 (en) | 2008-04-30 | 2011-04-26 | Xyleco, Inc. | Processing biomass and petroleum containing materials |
| AU2009260197B2 (en) * | 2008-06-18 | 2014-03-27 | Xyleco, Inc. | Processing materials with ion beams |
| US9387454B2 (en) | 2008-06-18 | 2016-07-12 | Xyleco, Inc. | Processing material with ion beams |
| NZ711066A (en) | 2008-10-28 | 2017-02-24 | Xyleco Inc | Processing hydrocarbon-containing materials by irradiation |
| WO2010083574A1 (en) * | 2010-01-17 | 2010-07-29 | Botanical Water Holdings Pty Ltd | Recovering water |
| NZ601756A (en) | 2010-01-17 | 2014-09-26 | Ambrosios Kambouris | Recovering water |
| AU2010100800B9 (en) * | 2010-01-17 | 2011-04-07 | Botanical Water Holdings Pty Ltd | Recovering water |
| CN105478076B (zh) * | 2016-01-18 | 2017-09-22 | 宁波大红鹰学院 | 一种膨润土基多孔功能材料的制备方法 |
| CN110961073B (zh) * | 2019-12-05 | 2022-01-28 | 中国石油大学(北京) | 一种页岩吸附材料在油水分离中的应用方法 |
| CN111157517A (zh) * | 2020-01-03 | 2020-05-15 | 吉林烟草工业有限责任公司 | 一种卷烟主流烟气中六价铬的检测方法 |
| US11584889B2 (en) * | 2021-01-04 | 2023-02-21 | Saudi Arabian Oil Company | Synthetic source rock with tea |
| CN113466397B (zh) * | 2021-05-21 | 2022-05-03 | 中国地质大学(武汉) | 一种定量评价有机孔对页岩吸附气贡献的方法 |
| CN116335610B (zh) * | 2021-12-24 | 2026-01-02 | 中国石油天然气股份有限公司 | 一种基于地下核辐射模式的页岩油原位改质的方法及装置 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1676151A (en) * | 1924-09-16 | 1928-07-03 | Ralph H Mckee | Filtering material and process of filtering |
| US4032305A (en) * | 1974-10-07 | 1977-06-28 | Squires Arthur M | Treating carbonaceous matter with hot steam |
| US4308146A (en) * | 1977-05-02 | 1981-12-29 | Phillips Petroleum Company | Crushed raw oil shale as oil spill adsorbent |
| US4508743A (en) * | 1980-05-28 | 1985-04-02 | Societe D'assistance Technique Pour Produits Nestle S.A. | Caffeine adsorption |
| US4408999A (en) * | 1981-05-11 | 1983-10-11 | Exxon Research And Engineering Co. | Coal and oil shale beneficiation process |
| US5041210A (en) * | 1989-06-30 | 1991-08-20 | Marathon Oil Company | Oil shale retorting with steam and produced gas |
| US6030698A (en) * | 1994-12-19 | 2000-02-29 | Lockheed Martin Energy Research Corporation | Activated carbon fiber composite material and method of making |
| US6576145B2 (en) * | 1997-02-27 | 2003-06-10 | Continuum Environmental, Llc | Method of separating hydrocarbons from mineral substrates |
| US20060229476A1 (en) * | 2005-04-08 | 2006-10-12 | Mitchell Robert L Sr | Activated carbon monolith catalyst, methods for making same, and uses thereof |
-
2007
- 2007-07-19 CA CA2658841A patent/CA2658841C/en not_active Expired - Fee Related
- 2007-07-19 US US12/375,156 patent/US20090308793A1/en not_active Abandoned
- 2007-07-19 WO PCT/ZA2007/000043 patent/WO2008014526A2/en not_active Ceased
- 2007-07-19 EP EP07815028A patent/EP2046494A2/de not_active Ceased
- 2007-07-19 RU RU2009103556/05A patent/RU2443468C2/ru not_active IP Right Cessation
- 2007-07-19 AU AU2007278836A patent/AU2007278836B2/en not_active Ceased
- 2007-07-19 CN CN2007800354131A patent/CN101516495B/zh not_active Expired - Fee Related
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2009
- 2009-01-19 IL IL196597A patent/IL196597A/en not_active IP Right Cessation
- 2009-01-26 ZA ZA2009/00587A patent/ZA200900587B/en unknown
- 2009-02-13 MA MA31639A patent/MA30646B1/fr unknown
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2014
- 2014-03-20 US US14/220,649 patent/US20140202930A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008014526A3 (en) | 2008-06-19 |
| MA30646B1 (fr) | 2009-08-03 |
| CA2658841A1 (en) | 2008-01-31 |
| RU2443468C2 (ru) | 2012-02-27 |
| EP2046494A2 (de) | 2009-04-15 |
| AU2007278836B2 (en) | 2012-04-05 |
| CN101516495B (zh) | 2013-04-10 |
| US20140202930A1 (en) | 2014-07-24 |
| ZA200900587B (en) | 2010-02-24 |
| IL196597A0 (en) | 2009-11-18 |
| RU2009103556A (ru) | 2010-09-10 |
| CN101516495A (zh) | 2009-08-26 |
| AU2007278836A1 (en) | 2008-01-31 |
| IL196597A (en) | 2013-11-28 |
| US20090308793A1 (en) | 2009-12-17 |
| WO2008014526A2 (en) | 2008-01-31 |
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